390 research outputs found
Recommended from our members
Determination of the response of pentaerythritol tetranitrate to static high pressure up to 4.2 GPa by neutron diffraction
Neutron powder diffraction experiments were performed on pentaerythritol tetranitrate explosive up to 4.28 GPa. For deuterated samples the changes in lattice parameters, intramolecular torsional angles and molecular rotation were measured. The lattice parameter changes were different from those observed in protonated samples. However, there is no evidence of a phase transition or change in molecular symmetry
A comparative study of experimental configurations in synchrotron pair distribution function
The identification and quantification of amorphous components and nanocrystalline phases
with very small crystal sizes, smaller than ~3 nm, within samples containing crystalline phases is
very challenging. However, this is important as there are several types of systems that contain these
matrices: building materials, glass-ceramics, some alloys, etc. The total scattering synchrotron pair
distribution function (PDF) can be used to characterize the local atomic order of the nanocrystalline
components and to carry out quantitative analyses in complex mixtures. Although the resolution in
momentum transfer space has been widely discussed, the resolution in the interatomic distance space
has not been discussed to the best of our knowledge. Here, we report synchrotron PDF data collected at
three beamlines in different experimental configurations and X-ray detectors. We not only discuss the
effect of the resolution in Q-space, Qmax ins of the recorded data and Qmax of the processed data, but we
also discuss the resolution in the interatomic distance (real) space. A thorough study of single-phase
crystalline nickel used as standard was carried out. Then, selected cement-related samples including
anhydrous tricalcium and dicalcium silicates, and pastes derived from the hydration of tricalcium
silicate and ye’elimite with bassanite were analyzed.This work is part of the PhD of Mr. Jesus D. Zea-Garcia. This work was supported by Spanish MINECO and FEDER [BIA2017-82391-R research project and I3 [IEDI-2016-0079] program]
Determination and mitigation of the uncertainty of neutron diffraction measurements of residual strain in large-grained polycrystalline material
For large-grained samples it is advantageous to perform pairs of neutron diffraction measurements at the same spatial location but rotated 180° around the geometric centre of the gauge volume as a means of minimizing the scatter coming from the random positioning of grains within the gauge volume
Non-monotonic size dependence of the elastic modulus of nanocrystalline ZnO embedded in a nanocrystalline silver matrix
We present the first high pressure Raman study on nanocrystalline ZnO films
with different average crystallite sizes. The problem of low Raman signals from
nano sized particles was overcome by forming a nanocomposite of Ag and ZnO
nanoparticles. The presence of the nanodispersed Ag particles leads to a
substantial surface enhancement of the Raman signal from ZnO. We find that the
elastic modulus of nanocrystalline ZnO shows a non-monotonic dependence on the
crystallite size. We suggest that the non-monotonicity arises from an interplay
between the elastic properties of the individual grains and the intergranular
region.Comment: 10 pages, 6 figure
Poly[[μ-(1-ammonioethane-1,1-diyl)bis(hydrogenphosphonato)]diaquachloridodisodium]: a powder X-ray diffraction study
The title compound, [Na2(C2H8NO6P2)Cl(H2O)2]n, has a polymeric two-dimensional structure extending parallel to (001). The asymmetric unit contains two Na+ cations located on a centre of symmetry and on a mirror plane, respectively, one half of a bis-phosphonate anion (the entire anion is completed by mirror symmetry), one chloride anion on a mirror plane and one water molecule in general positions. The two Na+ cations exhibit distorted octahedral NaCl2O4 coordination polyhedra, each consisting of two deprotonated O atoms of the bis-phosphonate anion, of two water molecules and of two chloride anions. Strong O—H⋯O hydrogen bonds between the –OH group and one of the free O atoms of the bis-phosphonate anion connect adjacent layers along [100], supported by N—H⋯Cl interactions. Intralayer O—H⋯O and N—H⋯O hydrogen bonds are also observed
Visible-light photocatalytic intramolecular cyclopropane ring expansion
Described herein is a new visible-light photocatalytic strategy for the synthesis of enantioenriched dihydrofurans and cyclopentenes by an intramolecular nitro cyclopropane ring expansion reaction. Mechanistic studies and DFT calculations are used to elucidate the key factors in this new ring expansion reaction, and the need for the nitro group on the cyclopropaneThe Spanish Government (CTQ2015-64561-R, CTQ2014-59544-P) and the European Research Council (ERC-CG,contract number:647550) are acknowledge
Experimental evidence for an intermediate phase in the multiferroic YMnO3
We have studied YMnO by high-temperature synchrotron X-ray powder
diffraction, and have carried out differential thermal analysis and dilatometry
on a single crystal sample. These experiments show two phase transitions at
about 1100K and 1350K, respectively. This demonstrates the existence of an
intermediate phase between the room temperature ferroelectric and the high
temperature centrosymmetric phase. This study identifies for the first time the
different high-temperature phase transitions in YMnO.Comment: 10 pages 5 figures. New version, Additional data, Journal of Physics:
Condensed Matter, in Pres
- …