Surface collective excitations in ultrafast pump-probe spectroscopy of metal nanoparticles

The role of surface collective excitations in the electron relaxation in small metal particles is studied. It is shown that the dynamically screened electron-electron interaction in a nanoparticle contains a size-dependent correction induced by the surface. This leads to new channels of quasiparticle scattering accompanied by the emission of surface collective excitations. In noble-metal particles, the dipole collective excitations (surface plasmons) mediate a resonant scattering of d-holes to the conduction band. The role of this effect in the ultrafast optical dynamics of small nanoparticles is studied. With decreasing nanoparticle size, it leads to a strong change in the differential absorption lineshape and a strong frequency dependence of the relaxation near the surface plasmon resonance. The experimental implications of these results in ultrafast pump-probe spectroscopy are addressed. The size-dependence of conduction electron scattering rates is also discussed.Comment: 26 pages including 10 figures. Invited paper for Special Issue of Chemical Physics on "Electron Dynamics in Metals

Impurity-enhanced Aharonov-Bohm effect in neutral quantum-ring magnetoexcitons

We study the role of impurity scattering on the photoluminescence (PL) emission of polarized magnetoexcitons. We consider systems where both the electron and hole are confined on a ring structure (quantum rings) as well as on a type-II quantum dot. Despite their neutral character, excitons exhibit strong modulation of energy and oscillator strength in the presence of magnetic fields. Scattering impurities enhance the PL intensity on otherwise "dark" magnetic field windows and non-zero PL emission appears for a wide magnetic field range even at zero temperature. For higher temperatures, impurity-induced anticrossings on the excitonic spectrum lead to unexpected peaks and valleys on the PL intensity as function of magnetic field. Such behavior is absent on ideal systems and can account for prominent features in recent experimental results.Comment: 7 pages, 7 figures, RevTe

Spectroscopy of vibrational modes in metal nanoshells

We study the spectrum of vibrational modes in metal nanoparticles with a dielectric core. Vibrational modes are excited by the rapid heating of the particle lattice that takes place after laser excitation, and can be monitored by means of pump-probe spectroscopy as coherent oscillations of transient optical spectra. In nanoshells, the presence of two metal surfaces results in a substantially different energy spectrum of acoustic vibrations than for solid particles. We calculated the energy spectrum as well as the damping of nanoshell vibrational modes. The oscillator strength of fundamental breathing mode is larger than that in solid nanoparticles. At the same time, in very thin nanoshells, the fundamental mode is overdamped due to instantaneous energy transfer to the surrounding medium

Size-dependent Correlation Effects in Ultrafast Optical Dynamics of Metal Nanoparticles

We study the role of collective surface excitations in the electron relaxation in small metal particles. We show that the dynamically screened electron-electron interaction in a nanoparticle contains a size-dependent correction induced by the surface. This leads to new channels of quasiparticle scattering accompanied by the emission of surface collective excitations. We calculate the energy and temperature dependence of the corresponding rates, which depend strongly on the nanoparticle size. We show that the surface-plasmon-mediated scattering rate of a conduction electron increases with energy, in contrast to that mediated by a bulk plasmon. In noble-metal particles, we find that the dipole collective excitations (surface plasmons) mediate a resonant scattering of d-holes to the conduction band. We study the role of the latter effect in the ultrafast optical dynamics of small nanoparticles and show that, with decreasing nanoparticle size, it leads to a drastic change in the differential absorption lineshape and a strong frequency dependence of the relaxation near the surface plasmon resonance. The experimental implications of our results in ultrafast pump-probe spectroscopy are also discussed.Comment: 29 pages including 6 figure

Resonance scattering and singularities of the scattering function

Recent studies of transport phenomena with complex potentials are explained by generic square root singularities of spectrum and eigenfunctions of non-Hermitian Hamiltonians. Using a two channel problem we demonstrate that such singularities produce a significant effect upon the pole behaviour of the scattering matrix, and more significantly upon the associated residues. This mechanism explains why by proper choice of the system parameters the resonance cross section is increased drastically in one channel and suppressed in the other channel.Comment: 4 pages, 3 figure

Nondissipative Drag Conductance as a Topological Quantum Number

We show in this paper that the boundary condition averaged nondissipative drag conductance of two coupled mesoscopic rings with no tunneling, evaluated in a particular many-particle eigenstate, is a topological invariant characterized by a Chern integer. Physical implications of this observation are discussed.Comment: 4 pages, no figure. Title modified and significant revision made to the text. Final version appeared in PR

Aharonov-Bohm interferometry with quantum dots: scattering approach versus tunneling picture

We address the question of how to model electron transport through closed Aharonov-Bohm interferometers which contain quantum dots. By explicitly studying interferometers with one and two quantum dots, we establish the connection between a tunneling-Hamiltonian formulation on the one hand and a scattering-matrix approach on the other hand. We prove that, under certain circumstances, both approaches are equivalent, i.e., both types of models can describe the same experimental setups. Furthermore, we analyze how the interplay of the Aharonov-Bohm phase and the orbital phase associated with the lengths of the interferometers' arms affect transport properties.Comment: 8 pages, 8 figures, published versio

Spin Transport in Two Dimensional Hopping Systems

A two dimensional hopping system with Rashba spin-orbit interaction is considered. Our main interest is concerned with the evolution of the spin degree of freedom of the electrons. We derive the rate equations governing the evolution of the charge density and spin polarization of this system in the Markovian limit in one-particle approximation. If only two-site hopping events are taken into account, the evolution of the charge density and of the spin polarization is found to be decoupled. A critical electric field is found, above which oscillations are superimposed on the temporal decay of the total polarization. A coupling between charge density and spin polarization occurs on the level of three-site hopping events. The coupling terms are identified as the anomalous Hall effect and the recently proposed spin Hall effect. Thus, an unpolarized charge current through a sheet of finite width leads to a transversal spin accumulation in our model system.Comment: 15 pages, 3 figure

Dephasing in sequential tunneling through a double-dot interferometer

We analyze dephasing in a model system where electrons tunnel sequentially through a symmetric interference setup consisting of two single-level quantum dots. Depending on the phase difference between the two tunneling paths, this may result in perfect destructive interference. However, if the dots are coupled to a bath, it may act as a which-way detector, leading to partial suppression of the phase-coherence and the reappearance of a finite tunneling current. In our approach, the tunneling is treated in leading order whereas coupling to the bath is kept to all orders (using P(E) theory). We discuss the influence of different bath spectra on the visibility of the interference pattern, including the distinction between "mere renormalization effects" and "true dephasing".Comment: 18 pages, 8 figures; For a tutorial introduction to dephasing see http://iff.physik.unibas.ch/~florian/dephasing/dephasing.htm

Quantifying the levitation picture of extended states in lattice models

The behavior of extended states is quantitatively analyzed for two dimensional lattice models. A levitation picture is established for both white-noise and correlated disorder potentials. In a continuum limit window of the lattice models we find simple quantitative expressions for the extended states levitation, suggesting an underlying universal behavior. On the other hand, these results point out that the Quantum Hall phase diagrams may be disorder dependent.Comment: 5 pages, submitted to PR