Optical spectroscopy of tungsten carbide (WC)

Journal ArticleResonant two-photon ionization spectroscopy has been used to study the diatomic transition-metal carbide, WC. A low-resolution scan revealed a five-member vibrational progression beginning with the 0-0 band at 17 585 cm-1. Analysis of this progression yielded a vibrational frequency of ?'e8(184W12C)=752.6(4.9) cm-1 and a bond length of r'e8(184W12C)=1.747(4) ?. Several unassigned bands were also rotationally resolved and analyzed. All of the observed bands are ?'=2??"=1 transitions, confirming the predicted ground state of 3?1 arising from a 14??8rr?15??4?116?1 configuration. The measured line positions in these bands were simultaneously fitted to provide B"=0.509 66(10) cm-1 for 184W12C, corresponding to r"0(184W12C)=1.713 5(2) ?. These values are corrected for spin-uncoupling effects in the ground state and represent our best estimate of the true bond length of WC. Dispersed fluorescence studies provide the ground-state vibrational constants of ?e=983(4) cm-1 and ?exe=11(1) cm-1, and have also permitted the low-lying [1.2] 3?2 and [4.75] states to be located and characterized. These results on WC are discussed in relation to the isovalent molecule MoC and other transition-metal carbides

Dust cloud lightning in extraterrestrial atmospheres

Lightning is present in all solar system planets which form clouds in their atmospheres. Cloud formation outside our solar system is possible in objects with much higher temperatures than on Earth or on Jupiter: Brown dwarfs and giant extrasolar gas planets form clouds made of mixed materials and a large spectrum of grain sizes. These clouds are globally neutral obeying dust-gas charge equilibrium which is, on short timescales, inconsistent with the observation of stochastic ionization events of the solar system planets. We argue that a significant volume of the clouds in brown dwarfs and extrasolar planets is susceptible to local discharge events and that the upper cloud layers are most suitable for powerful lightning-like discharge events. We discuss various sources of atmospheric ionisation, including thermal ionisation and a first estimate of ionisation by cosmic rays, and argue that we should expect thunderstorms also in the atmospheres of brown dwarfs and giant gas planets which contain mineral clouds.Comment: refereed conference paper accepted for publication in PSS Special Issue: Outer Planets VIII, 16 page

Material Around the Centaur (2060) Chiron from the 2018 November 28 UT Stellar Occultation

A stellar occultation of Gaia DR3 2646598228351156352 by the Centaur (2060) Chiron was observed from the South African Astronomical Observatory on 2018 November 28 UT. Here we present a positive detection of material surrounding Chiron from the 74-in telescope for this event. Additionally, a global atmosphere is ruled out at the tens of mircobar level for several possible atmospheric compositions. There are multiple 3-sigma drops in the 74-in light curve: three during immersion and two during emersion. Occulting material is located between 242-270 km from the center of the nucleus in the sky plane. Assuming the ring-plane orientation proposed for Chiron from the 2011 occultation, the flux drops are located at 352, 344, and 316 km (immersion), and 357, and 364 km (emersion) from the center, with normal optical depths of 0.26, 0.36, and 0.22 (immersion) and 0.26 and 0.18 (emersion), and equivalent widths between 0.7-1.3 km. This detection is similar to the previously proposed two-ring system and is located within the error bars of that ring-pole plane; however, the normal optical depths are less than half of the previous values, and three features are detected on immersion. These results suggest that the properties of the surrounding material have evolved between the 2011, 2018, and 2022 observations.Comment: Accepted by the Planetary Science Journal 21 Oct. 2023; 13 pages, 9 figures, 4 table

Fluorescence measurements for evaluating the application of multivariate analysis techniques to optically thick environments.

Laser-induced fluorescence measurements of cuvette-contained laser dye mixtures are made for evaluation of multivariate analysis techniques to optically thick environments. Nine mixtures of Coumarin 500 and Rhodamine 610 are analyzed, as well as the pure dyes. For each sample, the cuvette is positioned on a two-axis translation stage to allow the interrogation at different spatial locations, allowing the examination of both primary (absorption of the laser light) and secondary (absorption of the fluorescence) inner filter effects. In addition to these expected inner filter effects, we find evidence that a portion of the absorbed fluorescence is re-emitted. A total of 688 spectra are acquired for the evaluation of multivariate analysis approaches to account for nonlinear effects

High resolution spectroscopy of methyltrioxorhenium: towards the observation of parity violation in chiral molecules

Originating from the weak interaction, parity violation in chiral molecules has been considered as a possible origin of the biohomochirality. It was predicted in 1974 but has never been observed so far. Parity violation should lead to a very tiny frequency difference in the rovibrational spectra of the enantiomers of a chiral molecule. We have proposed to observe this predicted frequency difference using the two photon Ramsey fringes technique on a supersonic beam. Promising candidates for this experiment are chiral oxorhenium complexes, which present a large effect, can be synthesized in large quantity and enantiopure form, and can be seeded in a molecular beam. As a first step towards our objective, a detailed spectroscopic study of methyltrioxorhenium (MTO) has been undertaken. It is an ideal test molecule as the achiral parent molecule of chiral candidates for the parity violation experiment. For the 187Re MTO isotopologue, a combined analysis of Fourier transform microwave and infrared spectra as well as ultra-high resolution CO2 laser absorption spectra enabled the assignment of 28 rotational lines and 71 rovibrational lines, some of them with a resolved hyperfine structure. A set of spectroscopic parameters in the ground and first excited state, including hyperfine structure constants, was obtained for the antisymmetric Re=O stretching mode of this molecule. This result validates the experimental approach to be followed once a chiral derivative of MTO will be synthesized, and shows the benefit of the combination of several spectroscopic techniques in different spectral regions, with different set-ups and resolutions. First high resolution spectra of jet-cooled MTO, obtained on the set-up being developed for the observation of molecular parity violation, are shown, which constitutes a major step towards the targeted objective.Comment: 20 pages, 6 figure