Analysis of the flow imbalance on the profile shape during the extrusion of thin magnesium sheets

This article may be downloaded for personal use only. Any other use requires prior permission of the author and AIP Publishing. This article appeared in AIP Conference Proceedings 1567, 1098 (2013) and may be found at https://doi.org/10.1063/1.4850162.The extrusion process facilitates the production of magnesium sheets featuring a very thin thickness as well as excellent surface properties by using a single process step only. However, the extrusion of the magnesium sheets applying not optimized process parameters, e.g. low billet temperature or/ and poorly deformable magnesium alloy, produce pronounced buckling and waving of the extruded sheets as well as a variation of accuracy in profile shape along the cross section. The present investigation focuses on the FEM-simulation of the extrusion of magnesium sheets in order to clarify the origin of the mentioned effects. The simulations identify the flow imbalance during extrusion as the main critical factor. Due to the flow imbalance after passing the die a large compression stress zone is formed causing the buckling and waving of the thin sheets. Furthermore, the simulations of the magnesium sheet extrusion reveal that the interaction of the material flow gradients along the width and along the thickness direction near the die orifice lead to the variation of the accuracy in profile shape

Extrusion of Aluminum Tubes with Axially Graded Wall Thickness and Mechanical Characterization

In this study the indirect extrusion of seamless aluminum tubes with variable wall thickness was investigated. Therefore, an axially moveable stepped mandrel was applied. Investigations revealed that wall thickness transitions can either be graded over the tube length or very sharp. The microstructures in thin-walled and thick-walled tube sections were investigated. The local variation of the extrusion ratio and with that the tube wall thickness, product velocity and product temperature during the process lead to significantly different local microstructures at TB=400 °C. At TB=500 °C the microstructure was homogeneously recrystallized with similar grain size in all different tube sections. Furthermore, the mechanical tube properties were characterized by three point bending tests

Microstructure Evolution of Friction Boundary Layer during Extrusion of AA 6060

The tribological behavior between the aluminium alloy AA 6060 and the hot working steel 1.2344 has been recently studied using a new axial friction test for extrusion processes. With this new test, the friction forces as well as the specimens’ plastic deformations generated during sliding tests can be investigated. Selected specimens tested at high temperature (300-500 °C), normalized normal stress (σn/kfo=1.5) and high relative speed (0.1, 50 mm/s) have been sectioned and the microstructure on their mid-planes has been investigated. Light optical microscope analysis of the friction boundary layer revealed highly stretched grains and a thickness variation of the shear layer from 750 to 1600 μm depending on testing conditions. Moreover, EBSD analysis showed a grain refinement in the high shear zone especially at 300 °C with a grain size about 4 μm. Dynamic recrystallization was observed at 400 °C and an abnormal grain growth at 500 °C. Hardness measurements revealed a light hardening effect of 8% at 300 °C as well as a softening effect of 6% at 400 °C and 500 °C

A DFT Approach for Methanol Synthesis via Hydrogenation of CO on Gallia, Ceria and ZnO surfaces

A systematic theoretical study of the consecutive hydrogenation reactions of the CO molecule for the methanol synthesis catalyzed by different oxides of Zn, Ce and Ga is reported in this work. First, the CO hydrogenation with the formation of formyl species (HCO) was analyzed, followed by the successive hydrogenations that lead to formaldehyde (H2CO), methoxy (H3CO) and, finally, methanol (H3COH). The co-adsorption with H, in almost all the intermediate species, allows the corresponding hydrogenation reaction. Oxygen vacancies promote the reactivity in the generation of both formaldehyde and methoxy species. The formation of these species involves an important geometric difference between the initial and the final states, leading to high activation barriers. Comparing the surfaces studied in this work, we found that ZnO (0001)vacO has shown to be of a greater interest for methanol synthesis. However, the foregoing is not the most relevant of our results, but, instead, that the Brönsted Evans Polanyi (BEP) relationships between the initial or the final states and the transition states (TS) allowed to find a very good correlation between surface structure and reactivity.Fil: Reimers, Walter Guillermo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Física del Sur. Universidad Nacional del Sur. Departamento de Física. Instituto de Física del Sur; ArgentinaFil: Zubieta, Carolina Edith. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; ArgentinaFil: Baltanas, Miguel Angel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; ArgentinaFil: Branda, Maria Marta. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Física del Sur. Universidad Nacional del Sur. Departamento de Física. Instituto de Física del Sur; Argentin

Creep behavior of a γ′-strengthened Co-base alloy with zero γ/γ′-lattice misfit at 800 °C, 196 MPa

Dieser Beitrag ist mit Zustimmung des Rechteinhabers aufgrund einer (DFG geförderten) Allianz- bzw. Nationallizenz frei zugänglich.This publication is with permission of the rights owner freely accessible due to an Alliance licence and a national licence (funded by the DFG, German Research Foundation) respectively.Deformation and structural behavior of an experimental γ′-strengthened Co-base alloy during creep at 800 °C and 196 MPa have been investigated. The characteristic features of this alloy are zero γ/γ′-lattice misfit and a fine γ/γ′-microstructure. In the initial condition, the γ′-precipitates in this alloy are small (size of about 100 nm), have polyhedral morphology, and are separated by the very narrow γ-channels (width of about 10 nm). The tests performed up to about 1% creep strain (about 500 h creep time) gave creep curves with a slow constant strain rate and without an apparent transient creep, typical for superalloys with nonzero misfit. In this initial stage of creep, entering of the narrow γ-channels by dislocations is blocked by a strong Orowan force. The micromechanism of creep was identified as an octahedral glide of 〈011〉 superdislocations simultaneously in two phases, γ and γ′. The γ/γ′-microstructure with zero misfit shows no rafting but rapidly coarsens isotropically. It is concluded that zero misfit is beneficial at the initial stages of the creep but is unfavourable for long-term creep because of the continuous microstructural coarsening

The Intrinsically X-ray Weak Quasar PHL 1811. II. Optical and UV Spectra and Analysis

This is the second of two papers reporting observations and analysis of the unusually bright (m_b=14.4), luminous (M_B=-25.5), nearby (z=0.192) narrow-line quasar PHL 1811. The first paper reported that PHL 1811 is intrinsically X-ray weak, and presented a spectral energy distribution (SED). Here we present HST STIS optical and UV spectra, and ground-based optical spectra. The optical and UV line emission is very unusual. There is no evidence for forbidden or semiforbidden lines. The near-UV spectrum is dominated by very strong FeII and FeIII, and unusual low-ionization lines such as NaID and CaII H&K are observed. High-ionization lines are very weak; CIV has an equivalent width of 6.6A, a factor of ~5 smaller than measured from quasar composite spectra. An unusual feature near 1200A can be deblended in terms of Ly\alpha, NV, SiII, and CIII* using the blueshifted CIV profile as a template. Photoionization modeling shows that the unusual line emission can be explained qualitatively by the unusually soft SED. Principally, a low gas temperature results in inefficient emission of collisionally excited lines, including the semiforbidden lines generally used as density diagnostics. The emission resembles that of high-density gas; in both cases this is a consequence of inefficient cooling. PHL 1811 is very unusual, but we note that quasar surveys are generally biased against finding similar objects.Comment: Accepted for publication in ApJS. Full resolution figures available here: http://www.nhn.ou.edu/~leighly/phl1811_paper1.pd

Gezielte Steuerung der Bauteileigenspannungen durchinkrementelle Blechumformung

Die Prozessführung der inkrementellen Blechumformung beeinflusst maßgeblich den Eigenspannungszustand einer gefertigten Komponente und damit die Produkteigenschaften. Eine kontinuierliche Variation des Zustellinkrements im Umformprozess ermöglicht die lokale Ausbildung vordefinierter Eigenspannungen im Bauteil. Um die lokale Beeinflussung von Eigenspannungen zu analysieren, werden vier Prozessrouten mit unterschiedlichen Zustellinkrement-Kombinationen zur Herstellung einer Kegelstumpfgeometrie experimentell verglichen. Eine Änderung der Zustellinkremente im Prozess verursacht eine Erhöhung des Eigenspannungsniveaus bei sonst gleichbleibenden Produkteigenschaften

Signals of the cosmological reionization in the radio sky through C and O fine structure lines

We study the excitation of fine structure levels of C I, C II and O I by ultraviolet (UV) photons around strong UV sources which are also ionizing sources of the cosmological reionization at redshift of $\sim 10$. The evolutions of ionized regions around a point source are calculated by solving rate equations for non-equilibrium chemistry. Signals of UV photons through the fine structure lines are considered to be stronger at locations of more abundant chemical species of C I, C II and O I. Such environments would be realized where strong fluxes of non-ionizing UV line photons available for the pumping up of fine structure levels exist, and simultaneously ionizing UV photons are effectively shielded by dense H I regions. Signals from H I regions of moderately large densities induced by redshifted UV photons emitted at the point sources are found to be dominantly large over those of others. We discuss the detectability of the signals, and show that signals from idealized environments will be possibly detected by radio observations with next-generation arrays to come after the Atacama Large Millimeter/submillimeter Array (ALMA).Comment: 23 pages, 21 figures, significant revisions in Secs. 2, 3, and 4, and Appendix, main conclusions unchanged, accepted for publication in Monthly Notices of the Royal Astronomical Societ

Dft Study Of Polar Zno (000-1) Surface Stability Due To Transition Metals (Co, Mn) As Dopants

En este trabajo hemos estudiado, mediante la teoría del funcional de la densidad (DFT), el efecto de Co y Mn como dopantes -sustitucionales e intersticiales- en la superficie de ZnO polar. Se calcularon energías de formación de estas superficies dopadas, y se realizó un análisis de los cambios magnéticos que estas especies inducen. También se estudiaron los cambios geométricos producidos por estos dopantes. En cuanto a la energía de formación, para ambos dopantes, la ubicación intersticial en la primera bicapa es más favorable respecto a la sustitucional. El mayor valor de momento magnético se obtiene en Co como impureza sustitucional, mientras que intersticial para la especie Mn. Ambas especies producen un debilitamiento de los enlaces zinc 3 oxígenos superficiales.This work presents a study, through the density functional theory (DFT), of the effect of Co and Mn as dopants -substitutional and interstitial- on the surface of polar ZnO. Formation energy, of these doped surfaces, was calculated and it is performed an analysis of the magnetic changes induced by these dopant species. Moreover, the geometric changes were studied. From the formation energy values obtained, it is observed that the interstitial location in the first bilayer is more favorable for both dopants. The highest magnetic moment values are obtained for substitutional Co and interstitial Mn. Finally, both impurities produce a weakening of the surface zinc-oxygen bonds.Fil: Reimers, Walter Guillermo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Física del Sur. Universidad Nacional del Sur. Departamento de Física. Instituto de Física del Sur; ArgentinaFil: Gallegos, María Victoria. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; ArgentinaFil: Luna, Carla Romina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Física del Sur. Universidad Nacional del Sur. Departamento de Física. Instituto de Física del Sur; ArgentinaFil: Damonte, Laura Cristina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Física La Plata. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Física La Plata; ArgentinaFil: Sambeth, Jorge Enrique. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; ArgentinaFil: Marchetti, Jorge Mario. Norwegian University of Life Sciences; Noruega. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Física del Sur. Universidad Nacional del Sur. Departamento de Física. Instituto de Física del Sur; ArgentinaFil: Juan, Alfredo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Física del Sur. Universidad Nacional del Sur. Departamento de Física. Instituto de Física del Sur; Argentin