Development of a global pollution model for CO, CH4, and CH2O

The current status of a global pollution model for carbon monoxide, methane, and formaldehyde is described. The physico-chemical action is considered of these three pollutants in the troposphere. This geographic restriction is convenient since the tropopause provides a natural boundary across which little transport occurs. The data on sources and sinks for these pollutants is based on available information and assumptions relative to the major man-made and natural contributions. The distributions and concentrations of methane, formaldehyde, and carbon monoxide in the atmosphere are interrelated by the chemical reactions in which they participate. A chemical kinetic model based on the pseudo-steady state approximation for the intermediate species was developed to account for these reactions. The numerical procedure used to mathematically describe the pollution transport is a mass conservative scheme employing an integral flux approach

An algorithm to generate input data from meteorological and space shuttle observations to validate a CH4-CO model

Objective procedures to analyze data from meteorological and space shuttle observations to validate a three dimensional model were investigated. The transport and chemistry of carbon monoxide and methane in the troposphere were studied. Four aspects were examined: (1) detailed evaluation of the variational calculus procedure, with the equation of continuity as a strong constraint, for adjustment of global tropospheric wind fields; (2) reduction of the National Meteorological Center (NMC) data tapes for data input to the OSTA-1/MAPS Experiment; (3) interpolation of the NMC Data for input to the CH4-CO model; and (4) temporal and spatial interpolation procedures of the CO measurements from the OSTA-1/MAPS Experiment to generate usable contours of the data

The ozone oxidation of ethylene as it pertains to air pollution

Reaction kinetics of ozone oxidation of ethylene pertinent to air pollutio

Further development of a global pollution model for CO, CH4, and CH2 O

Global tropospheric pollution models are developed that describe the transport and the physical and chemical processes occurring between the principal sources and sinks of CH4 and CO. Results are given of long term static chemical kinetic computer simulations and preliminary short term dynamic simulations

The Arizona Radio Observatory CO Mapping Survey of Galactic Molecular Clouds: III. The Serpens Cloud in CO J=2-1 and 13CO J=2-1 Emission

We mapped 12CO and 13CO J = 2-1 emission over 1.04 square deg of the Serpens molecular cloud with 38 arcsec spatial and 0.3 km/s spectral resolution using the Arizona Radio Observatory Heinrich Hertz Submillimeter telescope. Our maps resolve kinematic properties for the entire Serpens cloud. We also compare our velocity moment maps with known positions of Young Stellar Objects (YSOs) and 1.1 mm continuum emission. We find that 12CO is self-absorbed and 13CO is optically thick in the Serpens core. Outside of the Serpens core, gas appears in filamentary structures having LSR velocities which are blue-shifted by up to 2 km/s relative to the 8 km/s systemic velocity of the Serpens cloud. We show that the known Class I, Flat, and Class II YSOs in the Serpens core most likely formed at the same spatial location and have since drifted apart. The spatial and velocity structure of the 12CO line ratios implies that a detailed 3-dimensional radiative transfer model of the cloud will be necessary for full interpretation of our spectral data. The starless cores region of the cloud is likely to be the next site of star formation in Serpens.Comment: 41 pages, 15 figure

A hybrid model for chaotic front dynamics: From semiconductors to water tanks

We present a general method for studying front propagation in nonlinear systems with a global constraint in the language of hybrid tank models. The method is illustrated in the case of semiconductor superlattices, where the dynamics of the electron accumulation and depletion fronts shows complex spatio-temporal patterns, including chaos. We show that this behavior may be elegantly explained by a tank model, for which analytical results on the emergence of chaos are available. In particular, for the case of three tanks the bifurcation scenario is characterized by a modified version of the one-dimensional iterated tent-map.Comment: 4 pages, 4 figure

Modulation of ecdysal cyst and toxin dynamics of two Alexandrium (Dinophyceae) species under small-scale turbulence

Some dinoflagellate species have shown different physiological responses to certain turbulent conditions. Here we investigate how two levels of turbulent kinetic energy dissipation rates (epsilon = 0.4 and 27 cm(2) s(-3)) affect the PSP toxins and ecdysal cyst dynamics of two bloom forming species, Alexandrium minutum and A. catenella. The most striking responses were observed at the high epsilon generated by an orbital shaker. In the cultures of the two species shaken for more than 4 days, the cellular GTX(1+4) toxin contents were significantly lower than in the still control cultures. In A. minutum this trend was also observed in the C(1+2) toxin content. For the two species, inhibition of ecdysal cyst production occurred during the period of exposure of the cultures to stirring (4 or more days) at any time during their growth curve. Recovery of cyst abundances was always observed when turbulence stopped. When shaking persisted for more than 4 days, the net growth rate significantly decreased in A. minutum (from 0.25 +/- 0.01 day(-1) to 0.19 +/- 0.02 day(-1)) and the final cell numbers were lower (ca. 55.4%) than in the still control cultures. In A. catenella, the net growth rate was not markedly modified by turbulence although under long exposure to shaking, the cultures entered earlier in the stationary phase and the final cell numbers were significantly lower (ca. 23%) than in the control flasks. The described responses were not observed in the experiments performed at the low turbulence intensities with an orbital grid system, where the population development was favoured. In those conditions, cells appeared to escape from the zone of the influence of the grids and concentrated in calmer thin layers either at the top or at the bottom of the containers. This ecophysiological study provides new evidences about the sensitivity to high levels of small-scale turbulence by two life cycle related processes, toxin production and encystment, in dinoflagellates. This can contribute to the understanding of the dynamics of those organisms in nature

EC9908 One Dish Meals

Extension Circular 9908: This circular contains information about simple, one dish meals to prepare. It also lists recipes and instructions for each dish discussed

Spin effects in gravitational radiation backreaction II. Finite mass effects

A convenient formalism for averaging the losses produced by gravitational radiation backreaction over one orbital period was developed in an earlier paper. In the present paper we generalize this formalism to include the case of a closed system composed from two bodies of comparable masses, one of them having the spin S. We employ the equations of motion given by Barker and O'Connell, where terms up to linear order in the spin (the spin-orbit interaction terms) are kept. To obtain the radiative losses up to terms linear in the spin, the equations of motion are taken to the same order. Then the magnitude L of the angular momentum L, the angle kappa subtended by S and L and the energy E are conserved. The analysis of the radial motion leads to a new parametrization of the orbit. From the instantaneous gravitational radiation losses computed by Kidder the leading terms and the spin-orbit terms are taken. Following Apostolatos, Cutler, Sussman and Thorne, the evolution of the vectors S and L in the momentary plane spanned by these vectors is separated from the evolution of the plane in space. The radiation-induced change in the spin is smaller than the leading-order spin terms in the momentary angular momentum loss. This enables us to compute the averaged losses in the constants of motion E, L and L_S=L cos kappa. In the latter, the radiative spin loss terms average to zero. An alternative description using the orbital elements a,e and kappa is given. The finite mass effects contribute terms, comparable in magnitude, to the basic, test-particle spin terms in the averaged losses.Comment: 12 pages, 1 figure, Phys.Rev.D15, March, 199

Outsourcing CO2 within China

Recent studies have shown that the high standard of living enjoyed by people in the richest countries often comes at the expense of CO2 emissions produced with technologies of low efficiency in less affluent, developing countries. Less apparent is that this relationship between developed and developing can exist within a single country’s borders, with rich regions consuming and exporting high-value goods and services that depend upon production of low-cost and emission-intensive goods and services from poorer regions in the same country. As the world’s largest emitter of CO2, China is a prominent and important example, struggling to balance rapid economic growth and environmental sustainability across provinces that are in very different stages of development. In this study, we track CO2 emissions embodied in products traded among Chinese provinces and internationally. We find that 57% of China’s emissions are related to goods that are consumed outside of the province where they are produced. For instance, up to 80% of the emissions related to goods consumed in the highly developed coastal provinces are imported from less developed provinces in central and western China where many low–value-added but high–carbon-intensive goods are produced. Without policy attention to this sort of interprovincial carbon leakage, the less developed provinces will struggle to meet their emissions intensity targets, whereas the more developed provinces might achieve their own targets by further outsourcing. Consumption-based accounting of emissions can thus inform effective and equitable climate policy within China