Screening process for activity determination of conductive oxide electrodes for organic oxidation

A modified method for the calculation of the normalized faradaic charge (q fN) is proposed. The method involves the simulation of an oxidation process, by cyclic voltammetry, by employing potentials in the oxygen evolution reaction region. The method is applicable to organic species whose oxidation is not manifested by a defined oxidation peak at conductive oxide electrodes. The variation of q fN for electrodes of nominal composition Ti/RuX Sn1-X O2 (x = 0.3, 0.2 and 0.1), Ti/Ir0.3Ti0.7O2 and Ti/Ru0.3Ti0.7O2 in the presence of various concentrations of formaldehyde was analyzed. It was observed that electrodes containing SnO2 are the most active for formaldehyde oxidation. Subsequently, in order to test the validity of the proposed model, galvanostatic electrolyses (40 mA cm-2) of two different formaldehyde concentrations (0.10 and 0.01 mol dm-3) were performed. The results are in agreement with the proposed model and indicate that this new method can be used to determine the relative activity of conductive oxide electrodes. In agreement with previous studies, it can be concluded that not only the nature of the electrode material, but also the organic species in solution and its concentration are important factors to be considered in the oxidation of organic compounds.Um método modificado para o cálculo da carga faradaica normalizada (q fN) é proposto. O método envolve a simulação de um processo de oxidação, por voltametria cíclica, empregando potenciais na região da reação de desprendimento de oxigênio (RDO). Este método é aplicável a espécies orgânicas, cuja oxidação não é manifestada por um pico de oxidação definido em eletrodos de óxidos condutores. A variação de q fN para eletrodos de composição nominal Ti/RuX Sn1-X O2 (x = 0,3; 0,2 e 0,1), Ti/Ir0,3Ti0,7O2 e Ti/Ru0,3Ti0,7O2, na presença de diferentes concentrações de formaldeído foi investigada. Foi observado que eletrodos contendo SnO2 são os mais ativos frente à oxidação de formaldeído. Subseqüentemente, para investigar a aplicabilidade do modelo proposto, eletrólises galvanostáticas (40 mA cm-2) de formaldeído foram efetuadas em duas concentrações distintas (0,10 e 0,01 mol dm-3). Os resultados estão de acordo com o modelo proposto e indicam que este novo método pode ser usado para determinar a atividade relativa de eletrodos de óxido. De acordo com trabalhos prévios, pode ser concluído que não somente a natureza do material eletródico, mas também a espécie orgânica em solução e a sua concentração são fatores importantes a serem considerados na oxidação de espécies orgânicas.FAPES

Electrochemical degradation of the dye reactive orange 16 using electrochemical flow-cell

Electrochemical removals of color and organic load from solutions containing the dye reactive orange 16 (RO16) were performed in an electrochemical flow-cell, using a platinum working electrode. The influence of the process variables flow-rate, such as NaCl concentration, applied potential and solution pH, were studied. The best color removal achieved was 93% (λ = 493 nm) after 60 min at 2.2 V vs. RHE electrolysis, using 1.00 g L-1 NaCl as supporting electrolyte. The rises in the concentration of NaCl and applied potential increased the color removal rate. The best total organic carbon removal (57%) was obtained at 1.8 V, without the separating membrane, indicating that the ideal conditions for the color removal are not necessarily the same as those to remove the total organic carbon. The degradation efficiency decreased with the solution pH decrease.As remoções eletroquímicas de cor e do conteúdo orgânico de soluções do corante laranja reativo 16 (RO16) foram efetuadas usando uma célula em fluxo e um eletrodo de trabalho de Pt. As influências das variáveis do sistema, tais como fluxo, concentração de NaCl, potencial aplicado e pH da solução, foram estudadas. A melhor remoção de cor foi de 93% (λ = 493 nm) após 60 min de eletrólise potentiostática a 2,2 V vs. ERH, usando 1,00 g L-1 NaCl como eletrólito suporte. Os aumentos na concentração de NaCl e do potencial aumentam a velocidade de remoção de cor. A melhor remoção de carbono orgânico total (57%) foi obtida com a aplicação de 1,8 V, sem membrana de separação, indicando que as melhores condições para remoção de cor não são necessariamente as melhores para remover conteúdo orgânico. A eficiência de degradação diminui com a diminuição do pH da solução.Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)FAPES

Effective electroosmotic transport of water in an intrinsically microporous polyamine (PIM-EA-TB)

Tertiary-amine-based Polymers of Intrinsic Microporosity (PIMs) provide a class of highly porous molecularly rigid materials for the electrochemical transport of both ionic and neutral species. Here, the transport of water molecules together with chloride anions (i.e. the electroosmotic drag coefficient) is studied for the intrinsically microporous polyamine PIM-EA-TB immersed in aqueous 0.01 M NaCl (i) when protonated for pH  4. Preliminary data suggest that in both cases a high electroosmotic drag coefficient is observed based on direct H2O transport into a D2O-filled compartment (quantified by 1H-NMR). For PIM-EA-TB there is a strong pH dependence with a higher electroosmotic drag coefficient in less acidic solutions (going from approx. 400 H2O per anion at pH 3 to approx. 4000 H2O per anion at pH 7), although the underlying absolute rate of water transport at a fixed voltage of −1 V appears to be essentially pH independent. Water transport through the PIM-EA-TB microchannels is rationalised based on the relative populations of chloride anions and of water in the micropores (essentially a ‘piston’ mechanism)

Constituting monetary conservatives via the 'savings habit': New Labour and the British housing market bubble

The ongoing world credit crunch might well kill off the most recent bubble dynamics in the British housing market by driving prices systematically downwards from their 2007 peak. Nonetheless, the experience of that bubble still warrants analytical attention. The Labour Government might not have been responsible for consciously creating it, but it has certainly grasped the opportunities the bubble has provided in an attempt to enforce a process of agential change at the heart of the British economy. The key issue in this respect is the way in which the Government has challenged the legitimacy of passive welfare receipts in favour of establishing a welfare system based on incorporating the individual into an active asset-holding society. The housing market has taken on new political significance as a means for individuals first to acquire assets and then to accumulate wealth on the back of asset ownership. The ensuing integration of the housing market into an increasingly reconfigured welfare system has permeated into the politics of everyday life. It has been consistent with individuals remaking their political subjectivities in line with preferences for the type of conservative monetary policies that typically keep house price bubbles inflated

The difference that tenure makes

This paper argues that housing tenures cannot be reduced to either production relations or consumption relations. Instead, they need to be understood as modes of housing distribution, and as having complex and dynamic relations with social classes. Building on a critique of both the productionist and the consumptionist literature, as well as of formalist accounts of the relations between tenure and class, the paper attempts to lay the foundations for a new theory of housing tenure. In order to do this, a new theory of class is articulated, which is then used to throw new light on the nature of class-tenure relations

Risk, commercialism and social purpose: Repositioning the English housing association sector

Originally seen as the ‘third arm’ of UK housing policy, the independent, not-for-profit housing association sector had long been seen as effective in ‘filling the gap’ where the state or market were unable to provide for households in need. Since the 1980s in particular, successive governments had viewed housing associations in favourable terms as efficient, semi-autonomous social businesses, capable of leveraging significant private funding. By 2015, in contrast, central government had come to perceive the sector as inefficient, bureaucratic and wasteful of public subsidy. Making use of institutional theory, this paper considers this paradigm shift and examines the organisational responses to an increasingly challenging operating environment. By focusing, in particular, on large London housing associations, the paper analyses their strategic decision-making to address the opportunities and threats presented. The paper argues that in facing an era of minimal subsidy, low security and high risk, the 2015 reforms represent a critical juncture for the sector. Housing organisations face a stark dilemma about whether to continue a strategy of ‘profit for purpose’ or to embrace an unambiguously commercial ethos. The article contends that the trajectory of decision-making (although not unidirectional) leads ultimately towards an increased exposure to risk and vulnerability to changes in the housing market. More fundamentally, the attempt to reconcile social and commercial logics is likely to have wider consequences for the legitimacy of the sector

Managing housing needs in post conflict housing reconstruction in Sri Lanka: gaps versus recommendations

Addressing housing needs in post conflict housing reconstruction leads to successful housing reconstruction. As part of a study of investigating how the housing needs can be effectively addressed in post conflict housing reconstruction, this paper identifies the gaps in managing housing needs in post conflict housing reconstruction within the context of Sri Lanka and presents the recommendations to minimise such gaps. Data was collected through un-structured interviews conducted with 37 participants, comprising policy makers, practitioners, academics and beneficiaries who engaged in post conflict housing reconstruction in Sri Lanka. Gaps were mainly found in conflict sensitivity, measures related to physical housing, performance of implementing agencies, policy and practice issues. On the job training, application of ‘do no harm’ principles, enhanced beneficiary participation, enhanced accountability, effective monitoring, enhanced knowledge sharing, adequate drinking water facilities, irrigation development and initiatives for material manufacturing were suggested as recommendations to minimise these gaps. Identification of gaps in managing housing needs in post conflict housing reconstruction and recommendations to minimise them inform policy makers to address the housing needs effectively through incorporating these aspects into the related policies. This in turn enhances the sustainability in housing development after conflicts