Transparent metal electrodes from ordered nanosphere arrays

We show that perforated metal electrode arrays, fabricated using nanosphere lithography, provide a viable alternative to conductive metal oxides as transparent electrode materials. The inter-aperture spacing is tuned by varying etching times in an oxygen plasma, and the effect of inter-aperture “wire” thickness on the optical and electronic properties of perforated silver films is shown. Optical transmission is limited by reflection and surface plasmons, and for these results do not exceed 73%. Electrical sheet resistance is shown to be as low as 3 Ω ◻−1 for thermally evaporated silver films. The performance of organic photovoltaic devices comprised of a P3HT:PCBM bulk heterojunction deposited onto perforated metal arrays is shown to be limited by optical transmission, and a simple model is presented to overcome these limitations

Effect of Increased Nitrogen Application Rates and Environment on Protein, Oil, Fatty Acids, and Minerals in Sesame (Sesamum indicum) Seed Grown under Mississippi Delta Conditions

Information on the effect of nitrogen fertilizer rates and environment on sesame seed composition and nutrition is scarce. The objective of this research was to investigate the effects of nitrogen fertilizer application rates on sesame seed yield, protein, oil, fatty acids, and mineral nutrition. A two-year (2014, 2015) field experiment was conducted. Nitrogen fertilizer (urea ammonium nitrate) solution (UAN, 32% N) was applied by side dressing to four sesame varieties (S-34, S-35, S-38, S-39) at rates of 44.7, 67.2, 89.6 and 112.0 kg\ub7ha-1. Rate of 44.7 kg\ub7ha-1 was used as control since this rate is traditionally recommended in the region. Increasing nitrogen application rates resulted in higher protein and oleic acid contents in two varieties in 2014, and in all varieties in 2015. Increased protein and oleic acid were accompanied by lower total oil and linoleic acid. Increased nitrogen application also resulted in higher seed N, S, B, Cu, Fe, and Zn in 2014 in S-34 and S-35, but either a decline or no clear change was observed in seed levels of these nutrients in S-38 and S-39. In 2015, increased nitrogen application resulted in significantly higher seed N in all varieties, and higher S, B, Cu, Fe, and Zn in some varieties. A significant positive correlation was observed between nitrogen application rate and yield, and with seed levels of protein, oleic, acid, N, B, Cu, Fe, and Zn. A significant negative correlation was observed between nitrogen application rate and seed oil and linoleic acid. Thus, increased nitrogen fertilizer application resulted in higher seed protein, oleic acid, and some mineral nutrients, but lower oil and linoleic acid. However, this effect depended on variety and environmental conditions. Because higher protein and oleic acid are desirable traits for sesame seed nutritional value and oil stability, regional breeders should select sesame varieties for efficient fertilizer response

Dataset of historic and modern bread and durum wheat cultivar performance under conventional and reduced tillage with full and reduced irrigation

Conservation agriculture (CA) is an agronomic management system based on zero tillage and residue retention. Due to its potential for climate change adaptation through the reduction of soil erosion and improved water availability, CA is becoming more important in many regions of the world. However, increased bulk density and large amounts of crop residues may be a constraint for early plant establishment. This holds especially true under irrigated production areas with high yield potential. Genotype × tillage effects on yield are not well understood and it is unclear whether tillage should be an evaluation factor in breeding programs. Fourteen CIMMYT bread (Triticum aestivum) and thirteen durum (Triticum turgidum) wheat genotypes, created between 1964 and 2011, were tested for yield and agronomic performance at CIMMYT's experimental station near Ciudad Obregon, Mexico, during nine seasons. The genotypes were subjected to different tillage and irrigation treatments which consisted of conventional and permanent raised beds with full and reduced irrigation. The dataset includes traits collected during the growing period (days to emergence, days to flowering, maturity, plant height, NDVI, days from flowering to maturity, grain production rate) and at harvest (yield, harvest index, thousand grain weight, spikes/m², grains/m², test weight) and weather data (daily minimum and maximum temperature, rainfall). Six years of data of 26 genotypes were published along with the Honsdorf et al. (2018) paper in Field Crops Research (DOI: s10.1016/j.fcr.2017.11.011). This updated dataset includes three additional seasons of data (harvest years 2016 to 2018) and an additional bread wheat genotype (Borlaug100)

A method for continuous239Pu determinations in Arctic and Antarctic ice cores

Atmospheric nuclear weapons testing (NWT) resulted in the injection of plutonium (Pu) into the atmosphere and subsequent global deposition. We present a new method for continuous semi-quantitative measurement of 239Pu in ice cores, which was used to develop annual records of fallout from NWT in ten ice cores from Greenland and Antarctica. The 239Pu was measured directly using an Inductively Coupled Plasma – Sector Field Mass Spectrometer, thereby reducing analysis time and increasing depth-resolution with respect to previous methods. To validate this method, we compared our one year averaged results to published 239Pu records and other records of NWT. The 239Pu profiles from four Arctic ice cores reflected global trends in NWT and were in agreement with discrete Pu profiles from lower latitude ice cores. The 239Pu measurements in the Antarctic ice cores tracked low latitude NWT, consistent with previously published discrete records from Antarctica. Advantages of the continuous 239Pu measurement method are (1) reduced sample preparation and analysis time; (2) no requirement for additional ice samples for NWT fallout determinations; (3) measurements are exactly co-registered with all other chemical, elemental, isotopic, and gas measurements from the continuous analytical system; and (4) the long half-life means the 239Pu record is stable through time

Antarctic ice sheet paleo-constraint database

We present a database of observational constraints on past Antarctic Ice Sheet changes during the last glacial cycle intended to consolidate the observations that represent our understanding of past Antarctic changes, for state-space estimation, and paleo-model calibrations. The database is a major expansion of the initial work of Briggs and Tarasov (2013). It includes new data types and multi-tier data quality assessment. The updated constraint database “AntICE2” consists of observations of past grounded and floating ice sheet extent, past ice thickness, past relative sea level, borehole temperature profiles, and present-day bedrock displacement rates. In addition to paleo-observations, the present-day ice sheet geometry and surface ice velocities are incorporated to constrain the present-day ice sheet configuration. The method by which the data is curated using explicitly defined criteria is detailed. Moreover, the observational uncertainties are specified. The methodology by which the constraint database can be applied to evaluate a given ice sheet reconstruction is discussed. The implementation of the “AntICE2” database for Antarctic Ice Sheet model calibrations will improve Antarctic Ice Sheet predictions during past warm and cold periods and yield more robust paleo model spin ups for forecasting future ice sheet changes

Improved estimates of preindustrial biomass burning reduce the magnitude of aerosol climate forcing in the Southern Hemisphere.

Fire plays a pivotal role in shaping terrestrial ecosystems and the chemical composition of the atmosphere and thus influences Earth's climate. The trend and magnitude of fire activity over the past few centuries are controversial, which hinders understanding of preindustrial to present-day aerosol radiative forcing. Here, we present evidence from records of 14 Antarctic ice cores and 1 central Andean ice core, suggesting that historical fire activity in the Southern Hemisphere (SH) exceeded present-day levels. To understand this observation, we use a global fire model to show that overall SH fire emissions could have declined by 30% over the 20th century, possibly because of the rapid expansion of land use for agriculture and animal production in middle to high latitudes. Radiative forcing calculations suggest that the decreasing trend in SH fire emissions over the past century largely compensates for the cooling effect of increasing aerosols from fossil fuel and biofuel sources

Improved estimates of preindustrial biomass burning reduce the magnitude of aerosol climate forcing in the Southern Hemisphere.

Fire plays a pivotal role in shaping terrestrial ecosystems and the chemical composition of the atmosphere and thus influences Earth's climate. The trend and magnitude of fire activity over the past few centuries are controversial, which hinders understanding of preindustrial to present-day aerosol radiative forcing. Here, we present evidence from records of 14 Antarctic ice cores and 1 central Andean ice core, suggesting that historical fire activity in the Southern Hemisphere (SH) exceeded present-day levels. To understand this observation, we use a global fire model to show that overall SH fire emissions could have declined by 30% over the 20th century, possibly because of the rapid expansion of land use for agriculture and animal production in middle to high latitudes. Radiative forcing calculations suggest that the decreasing trend in SH fire emissions over the past century largely compensates for the cooling effect of increasing aerosols from fossil fuel and biofuel sources

A horizontal ice core from Taylor Glacier, its implications for Antarctic climate history, and an improved Taylor Dome ice core time scale

Ice core records from Antarctica show mostly synchronous temperature variations during the last deglacial transition, an indication that the climate of the entire continent reacted as one unit to the global changes. However, a record from the Taylor Dome ice core in the Ross Sea sector of East Antarctica has been suggested to show a rapid warming, similar in style and synchronous with the Oldest Dryas—Bølling warming in Greenland. Since publication of the Taylor Dome record, a number of lines of evidence have suggested that this interpretation is incorrect and reflects errors in the underlying time scale. The issues raised regarding the dating of Taylor Dome currently linger unresolved, and the original time scale remains the de facto chronology. We present new water isotope and chemistry data from nearby Taylor Glacier to resolve the confusion surrounding the Taylor Dome time scale. We find that the Taylor Glacier record is incompatible with the original interpretation of the Taylor Dome ice core, showing that the warming in the area was gradual and started at ∼18 ka BP (before 1950) as seen in other East Antarctic ice cores. We build a consistent, up‐to‐date Taylor Dome chronology from 0 to 60 ka BP by combining new and old age markers based on synchronization to other ice core records. The most notable feature of the new TD2015 time scale is a gas age—ice age difference of up to 12,000 years during the Last Glacial Maximum, by far the largest ever observed

Antarctic ice rises and rumples: Their properties and significance for ice-sheet dynamics and evolution

Locally grounded features in ice shelves, called ice rises and rumples, play a key role buttressing discharge from the Antarctic Ice Sheet and regulating its contribution to sea level. Ice rises typically rise several hundreds of meters above the surrounding ice shelf; shelf flow is diverted around them. On the other hand, shelf ice flows across ice rumples, which typically rise only a few tens of meters above the ice shelf. Ice rises contain rich histories of deglaciation and climate that extend back over timescales ranging from a few millennia to beyond the last glacial maximum. Numerical model results have shown that the buttressing effects of ice rises and rumples are significant, but details of processes and how they evolve remain poorly understood. Fundamental information about the conditions and processes that cause transitions between floating ice shelves, ice rises and ice rumples is needed in order to assess their impact on ice-sheet behavior. Targeted high-resolution observational data are needed to evaluate and improve prognostic numerical models and parameterizations of the effects of small-scale pinning points on grounding-zone dynamics