Raman tensor analysis of hexagonal polyoxymethylene and its application to study the molecular arrangement in highly crystalline electrospun nanofibers

The orientation dependence in space of Raman-active vibrations in the hexagonal structure of polyoxymethylene (POM) is discussed in terms of Raman tensor elements as intrinsic physical parameters of the lattice. The variation of polarized intensity for the A1 and the E1 vibrational modes with respect to the POM molecular orientation is systematically studied, from both theoretical and experimental viewpoints, according to the symmetry assignments of each vibrational mode. A set of working equations including the Raman selection rules associated with the A1 and the E1 modes and the orientation distribution function are explicitly formulated and validated by means of a least-square fitting procedure on experimental data. In addition, an approach based on the introduction of orientation distribution functions is applied to quantitatively assess and compare on a statistical base the molecular orientation of two different types of electrospun POM nanofibers. Copyright (c) 2012 John Wiley & Sons, Ltd

Transverse Dynamics and Energy Tuning of Fast Electrons Generated in Sub-Relativistic Intensity Laser Pulse Interaction with Plasmas

The regimes of quasi-mono-energetic electron beam generation were experimentally studied in the sub-relativistic intensity laser plasma interaction. The observed electron acceleration regime is unfolded with two-dimensional-particle-in-cell simulations of laser-wakefield generation in the self-modulation regime.Comment: 10 pages, 5 figure

Sero- and Molecular Epidemiology of HIV-1 in Papua Province, Indonesia

Background: human immunodeficiency virus (HIV) infection and acquired immune deficiency syndrome (AIDS) cause serious health problems and affect the Indonesian economy. Papua province has the highest prevalence of HIV infection in the country; however, epidemiological data are limited. Therefore, in order to reveal the current situation of HIV/AIDS in Papua province, sero- and molecular epidemiological studies of HIV were conducted. Methods: serological tests were conducted on 157 healthy individuals from the general population residing in Paniai, Papua. In addition, a molecular epidemiological study was then conducted on HIV type 1 (HIV-1) genes derived from infected individuals. Peripheral blood samples from HIV-1-positive individuals and 15 additionally enrolled, previously confirmed HIV-1-positive individuals were subjected to a genotypic analysis. Results: serological tests revealed that 2 out of 157 (1.27%) healthy individuals were HIV-positive. In addition, HIV-1 subtyping revealed that subtype B and CRF01_AE were the major subtype and circulating recombinant form (CRF) of HIV-1 prevalent in the region, while subtype A1 and a recombinant form including viral gene fragments of CRF01_AE and subtype B was also detected. In addition, HIV drug resistance-associated major mutations were detected in the reverse transcriptase gene derived from infected individual on antiretroviral therapy. Conclusion: these results provide important information for clearer understanding on the current situation of HIV/AIDS in Papua province in Indonesia

Soft X-ray harmonic comb from relativistic electron spikes

We demonstrate a new high-order harmonic generation mechanism reaching the `water window' spectral region in experiments with multi-terawatt femtosecond lasers irradiating gas jets. A few hundred harmonic orders are resolved, giving uJ/sr pulses. Harmonics are collectively emitted by an oscillating electron spike formed at the joint of the boundaries of a cavity and bow wave created by a relativistically self-focusing laser in underdense plasma. The spike sharpness and stability are explained by catastrophe theory. The mechanism is corroborated by particle-in-cell simulations

Stability improvement of a laser-accelerated electron beam and the pulse width measurement of the electron beam

Laser wakefield acceleration has the possibility to generate an ultrashort electron beam of the order of femtoseconds or less. In applications of these laser accelerated electron beams, stable and controllable electron beams are necessary. A high stability electron bunch is generated by laser wakefield acceleration with the help of a colliding laser pulse (optical injection). Stable and monoenergetic electron beams have been generated in the self-injection scheme of laser acceleration by using a Nitrogen gas jet target. The electron interaction with the laser field results in transverse oscillations of the electron beam. From the electron oscillation period dependence on the electron energy we find that the electron beam width is equal to 1.7 fs (rms).В процессе ускорения кильватерными волнами возможна генерация сверхкоротких электронных пучков фемтосекундной длительностью. Для приложений требуются электронные пучки с воспроизводимыми и котролируемыми параметрами. Оптическая инжекция, использующая сталкивающиеся лазерные импульсы, обеспечивает высокую воспроизводимость параметров пучков ускоренных электронов. Моноэнергетические пучки электронов с воспроизводимыми параметрами были получены при «самоинжекции» в кильватерную волну в экспериментах, использующих в качестве мишени струю азота. Взаимодействие электронов с излучением лазерного импульса приводит к поперечным осцилляциям электронного пучка. Анализ наблюдаемой в эксперименте зависимости периода осцилляций от энергии электронов позволяет найти длительность электронного пучка, равную 1.7 фс.В процесі прискорення кільватерними хвилями можлива генерація надкоротких електронних пучків фемтосекундної тривалості. Для додатків потрібні електронні пучки з відтворюючими і котролюючими параметрами. Оптична інжекція, що використовує зіштовхуючі лазерні імпульси, забезпечує високу відтворюваність параметрів пучків прискорених електронів. Моноенергетичні пучки електронів з відтворюваними параметрами були отримані при «самоінжекції» в кільватерну хвилю в експериментах, в яких в якості мішені використовувалася струмінь азоту. Взаємодія електронів з випромінюванням лазерного імпульсу призводить до поперечних осциляцій електронного пучка. Аналіз спостерігаючої в експерименті залежності періоду осциляцій від енергії електронів дозволяє знайти тривалість електронного пучка, яка дорівнює 1.7 фс

High-order alloharmonics produced by nonperiodic drivers

High-order harmonics are ubiquitous in nature and present in electromagnetic, acoustic, and gravitational waves. They are generated by periodic nonlinear processes or periodic high-frequency pulses. However, this periodicity is often inexact, such as that in chirped (frequency-swept) optical waveforms or interactions with nonstationary matter -- for instance, reflection from accelerating mirrors. Spectra observed in such cases contain complicated sets of harmonic-like fringes. We encountered such fringes in our experiment on coherent extreme ultraviolet generation via BISER, and could not interpret them using currently available knowledge. Here, we present a comprehensive theory based on interference of harmonics with different orders fully explaining the formation of these fringes, which we call alloharmonics. Like atomic spectra, the complex alloharmonic spectra depend on several integer numbers and bear a unique imprint of the emission process, which the theory can decipher, avoiding confusion or misinterpretation. We also demonstrate the alloharmonics in simulations of gravitational waves emitted by binary black hole mergers. Further, we predict the presence of alloharmonics in the radio spectra of pulsars and in optical frequency combs, and propose their use for measurement of extremely small accelerations necessary for testing gravity theories. The alloharmonics phenomenon generalizes classical harmonics and is critical in research fields such as laser mode locking, frequency comb generation, attosecond pulse generation, pulsar studies, and future gravitational wave spectroscopy.Comment: 29 pages, 9 figures, 3 table

Observation of Burst Intensification by Singularity Emitting Radiation generated from relativistic plasma with a high-intensity laser

Coherent x-rays via the Burst Intensification by Singularity Emitting Radiation (BISER) mechanism are generated from relativistic plasma in helium gas target. A broad modulation of the BISER spectrum, which is significantly wider than the harmonic order, is observed and characterized. In particular, we found that the modulation period can be as large as 41 eV

Organic waste as a sustainable feedstock for platform chemicals

Biorefineries have been established since the 1980s for biofuel production, and there has been a switch lately from first to second generation feedstocks in order to avoid the food versus fuel dilemma. To a lesser extent, many opportunities have been investigated for producing chemicals from biomass using by-products of the present biorefineries, simple waste streams. Current facilities apply intensive pre-treatments to deal with single substrate types such as carbohydrates. However, most organic streams such as municipal solid waste or algal blooms present a high complexity and variable mixture of molecules, which makes specific compound production and separation difficult. Here we focus on flexible anaerobic fermentation and hydrothermal processes that can treat complex biomass as a whole to obtain a range of products within an integrated biorefinery concept