The Creation of Anions by Rydberg Electron Transfer or Laser Vaporization and Their Examination using Anion Photoelectron Spectroscopy

Negatively charged atomic, molecular, and cluster ions were studied in the gas phase by anion photoelectron spectroscopy. The photoelectron spectra map the electronic structure of these anionic species and, when combined with theoretical calculations, the geometry of the anionic and corresponding neutral species can be determined. A variety of experiments were performed using time-of-flight mass spectrometry coupled with negative ion photoelectron spectroscopy, after the negative ions were made by assorted sources. These studies focused on a wide range of electron binding strengths, i.e., from diffuse electron states to valence-bound states, and included organic molecules that exist in a few conformations, each with different multipole moments; atomic metal anions; complexes between atomic or cluster metal anions and small molecules; and superatomic anions, which have varied ligands. After introducing the experimental methods, Chapter III presents these studies in detail, starting with the multiple dipole-bound anions that introduced our Rydberg Electron Transfer capabilities, the correlation-bound anion of p-chloroaniline, and the dipole- and/or quadrupole-bound anions of the succinonitrile, dicyanocyclohexane and silatrane molecules and divulging into the more strongly bound negative ions from interactions of metal atoms and clusters with pyridine, hydroxylamine, water, and carbon dioxide, as well as the hardness of metal borides and the effects ligands have on cobalt sulfide superatoms

A mantle plume origin for the Palaeoproterozoic Circum-Superior Large Igneous Province

The Circum-Superior Large Igneous Province (LIP) consists predominantly of ultramafic-mafic lavas and sills with minor felsic components, distributed as various segments along the margins of the Superior Province craton. Ultramafic-mafic dykes and carbonatite complexes of the LIP also intrude the more central parts of the craton. Most of this magmatism occurred ∼1880 Ma. Previously a wide range of models have been proposed for the different segments of the CSLIP with the upper mantle as the source of magmatism. New major and trace element and Nd-Hf isotopic data reveal that the segments of the CSLIP can be treated as a single entity formed in a single tectonomagmatic environment. In contrast to most previous studies that have proposed a variety of geodynamic settings, the CSLIP is interpreted to have formed from a single mantle plume. Such an origin is consistent with the high MgO and Ni contents of the magmatic rocks, trace element signatures that similar to oceanic-plateaus and ocean island basalts and εNd-εHf isotopic signatures which are each more negative than those of the estimated depleted upper mantle at ∼1880 Ma. Further support for a mantle plume origin comes from calculated high degrees of partial melting, mantle potential temperatures significantly greater than estimated ambient Proterozoic mantle and the presence of a radiating dyke swarm. The location of most of the magmatic rocks along the Superior Province margins probably represents the deflection of plume material by the thick cratonic keel towards regions of thinner lithosphere at the craton margins. The primary magmas, generated by melting of the heterogeneous plume head, fractionated in magma chambers within the crust, and assimilated varying amounts of crustal material in the process

On kaonic hydrogen. Phenomenological quantum field theoretic model revisited

We argue that due to isospin and U-spin invariance of strong low-energy interactions the S-wave scattering lengths a^0_0 and a^1_0 of bar-KN scattering with isospin I=0 and I = 1 satisfy the low-energy theorem a^0_0 + 3 a^1_0 = 0 valid to leading order in chiral expansion. In the model of strong low-energy bar-KN interactions at threshold (EPJA 21,11 (2004)) we revisit the contribution of the Sigma(1750) resonance, which does not saturate the low-energy theorem a^0_0 + 3 a^1_0 = 0, and replace it by the baryon background with properties of an SU(3) octet. We calculate the S-wave scattering amplitudes of K^-N and K^-d scattering at threshold. We calculate the energy level displacements of the ground states of kaonic hydrogen and kaonic deuterium. The result obtained for kaonic hydrogen agrees well with recent experimental data by the DEAR Collaboration. We analyse the cross sections for elastic and inelastic K^-p scattering for laboratory momenta of the incident K^- meson from the domain 70 MeV/c < p_K < 150 MeV/c. The theoretical results agree with the available experimental data within two standard deviations.Comment: 20 pages, Latex, We have slightly corrected the contribution of the double scattering. This changes the S-wave scattering length of K^-d scattering by 17%, which is commensurable with the theoretical uncertaint

Origins of the sarsen megaliths at Stonehenge

The sources of the stone used to construct Stonehenge around 2500 BCE have been debated for over four centuries. The smaller “bluestones” near the center of the monument have been traced to Wales, but the origins of the sarsen (silcrete) megaliths that form the primary architecture of Stonehenge remain unknown. Here, we use geochemical data to show that 50 of the 52 sarsens at the monument share a consistent chemistry and, by inference, originated from a common source area. We then compare the geochemical signature of a core extracted from Stone 58 at Stonehenge with equivalent data for sarsens from across southern Britain. From this, we identify West Woods, Wiltshire, 25 km north of Stonehenge, as the most probable source area for the majority of sarsens at the monument

Casimir effect for tachyonic fields

In this paper we examine Casimir effect in the case of tachyonic field, which is connected with particles with negative four-momentum square. We consider here only the case of one dimensional, scalar field. In order to describe tachyonic field, we use the absolute synchronization scheme preserving Lorentz invariance. The renormalized vacuum energy is calculated by means of Abel-Plana formula. Finaly, the Casimir energy and Casimir force as the functions of distance are obtained. In order to compare the resulting formula with the standard one, we calculate the Casimir energy and Casimir force for massive, scalar field.Comment: 7 pages, 9 figure