Future sea ice weakening amplifies winddriven trends in surface stress and Arctic Ocean spin-up

Arctic sea ice mediates atmosphere-ocean momentum transfer, which drives upper ocean circulation. How Arctic Ocean surface stress and velocity respond to sea ice decline and changing winds under global warming is unclear. Here we show that state-of-the-art climate models consistently predict an increase in future (2015–2100) ocean surface stress in response to increased surface wind speed, declining sea ice area, and a weaker ice pack. While wind speeds increase most during fall (+2.2% per decade), surface stress rises most in winter (+5.1% per decade) being amplified by reduced internal ice stress. This is because, as sea ice concentration decreases in a warming climate, less energy is dissipated by the weaker ice pack, resulting in more momentum transfer to the ocean. The increased momentum transfer accelerates Arctic Ocean surface velocity (+31–47% by 2100), leading to elevated ocean kinetic energy and enhanced vertical mixing. The enhanced surface stress also increases the Beaufort Gyre Ekman convergence and freshwater content, impacting Arctic marine ecosystems and the downstream ocean circulation. The impacts of projected changes are profound, but different and simplified model formulations of atmosphere-ice-ocean momentum transfer introduce considerable uncertainty, highlighting the need for improved coupling in climate models.publishedVersio

Methane release from open leads and new ice following an Arctic winter storm event

We examine an Arctic winter storm event, which led to ice break–up, the formation of open leads, and the subsequent freezing of these leads. The methane (CH4) concentration in under–ice surface water before and during the storm event was 8–12 nmol L−1, which resulted in a potential sea–to–air CH4 flux ranging from +0.2 to +2.1 mg CH4 m−2 d−1 in open leads. CH4 ventilation between seawater and atmosphere occurred when both open water fraction and wind speed increased. Over the nine days after the storm, sea ice grew 27 cm thick. Initially, CH4 concentrations in the sea ice brine were above the equilibrium with the atmosphere. As the ice grew thicker, most of the CH4 was lost from upper layers of sea ice into the atmosphere, implying continued CH4 evasion after the leads were ice–covered. This suggests that wintertime CH4 emissions need to be better constrained

Snow contribution to first-year and second-year Arctic sea ice mass balance north of Svalbard

The salinity and water oxygen isotope composition (δ18O) of 29 first-year (FYI) and second-year (SYI) Arctic sea ice cores (total length 32.0 m) from the drifting ice pack north of Svalbard were examined to quantify the contribution of snow to sea ice mass. Five cores (total length 6.4 m) were analyzed for their structural composition, showing variable contribution of 10–30% by granular ice. In these cores, snow had been entrained in 6–28% of the total ice thickness. We found evidence of snow contribution in about three quarters of the sea ice cores, when surface granular layers had very low δ18O values. Snow contributed 7.5–9.7% to sea ice mass balance on average (including also cores with no snow) based on δ18O mass balance calculations. In SYI cores, snow fraction by mass (12.7–16.3%) was much higher than in FYI cores (3.3–4.4%), while the bulk salinity of FYI (4.9) was distinctively higher than for SYI (2.7). We conclude that oxygen isotopes and salinity profiles can give information on the age of the ice and enables distinction between FYI and SYI (or older) ice in the area north of Svalbard

Methane release from open leads and new ice following an Arctic winter storm event

We examine an Arctic winter storm event, which led to ice break–up, the formation of open leads, and the subsequent freezing of these leads. The methane (CH4) concentration in under–ice surface water before and during the storm event was 8–12 nmol L−1, which resulted in a potential sea–to–air CH4 flux ranging from +0.2 to +2.1 mg CH4 m−2 d−1 in open leads. CH4 ventilation between seawater and atmosphere occurred when both open water fraction and wind speed increased. Over the nine days after the storm, sea ice grew 27 cm thick. Initially, CH4 concentrations in the sea ice brine were above the equilibrium with the atmosphere. As the ice grew thicker, most of the CH4 was lost from upper layers of sea ice into the atmosphere, implying continued CH4 evasion after the leads were ice–covered. This suggests that wintertime CH4 emissions need to be better constrainedMethane release from open leads and new ice following an Arctic winter storm eventacceptedVersio

Warming of Atlantic Water in two west Spitsbergen fjords over the last century (1912-2009)

The recently observed warming of west Spitsbergen fjords has led to anomalous sea-ice conditions and has implications for the marine ecosystem. We investigated long-term trends of maximum temperature of Atlantic Water (AW) in two west Spitsbergen fjords. The data set is composed of more than 400 oceanographic stations for Isfjorden and Grønfjorden (78.1°N), spanning from 1876 to 2009. Trends throughout the last century (1912–2009) indicate an increase of 1.9°C and 2.1°C in the maximum temperature during autumn for Isfjorden and Grønfjorden, respectively. A recent warming event in the beginning of the 21st century is found to be more than 1°C higher than the second warmest period in the time series. Mean sea-level pressure (MSLP) data from ERA-40 and ERA-Interim data sets produced by the European Centre for Medium-Range Weather Forecasts and mean temperature in the core of the West Spitsbergen Current (WSC) at the Sørkapp Section along 76.3°N were used to explain the variability of the maximum temperature. A correlation analysis confirmed previous findings, showing that variability in the oceanography of the fjords can be explained mainly by two external factors: AW temperature variability in the WSC and regional patterns of the wind stress field. To take both processes into consideration, a multiple regression model accounting for temperature in the WSC core and MSLP over the area was developed. The predicted time series shows a reasonable agreement with observed maxima temperature in Isfjorden for the period 1977–2009 (N=24), with a statistically significant multiple correlation coefficient of 0.60 (R2=0.36) at P<0.05.publishedVersio

Linkages between the circulation and distribution of dissolved organic matter in the White Sea, Arctic Ocean

AbstractThe White Sea is a semi-enclosed Arctic marginal sea receiving a significant loading of freshwater (225–231km3yr−1 equaling an annual runoff yield of 2.5m) and dissolved organic matter (DOM) from river run-off. We report discharge weighed values of stable oxygen isotope ratios (δ18O) of −14.0‰ in Northern Dvina river for the period 10 May–12 October 2012. We found a significant linear relationship between salinity (S) and δ18O (δ18O=−17.66±0.58+0.52±0.02×S; R2=0.96, N=162), which indicates a dominant contribution of river water to the freshwater budget and little influence of sea ice formation or melt. No apparent brine additions from sea-ice formation is evident in the White Sea deep waters as seen from a joint analysis of temperature (T), S, δ18O and aCDOM(350) data, confirming previous suggestions about strong tidal induced vertical mixing in winter being the likely source of the deep waters. We investigated properties and distribution of colored dissolved organic matter (CDOM) and dissolved organic carbon (DOC) in the White Sea basin and coastal areas in summer. We found contrasting DOM properties in the inflowing Barents Sea waters and White Sea waters influenced by terrestrial runoff. Values of absorption by CDOM at 350nm (aCDOM(350)) and DOC (exceeding 10m−1 and 550µmoll−1, respectively) in surface waters of the White Sea basin are higher compared to other river-influenced coastal Arctic domains. Linear relationship between S and CDOM absorption, and S and DOC (DOC=959.21±52.99–25.80±1.79×S; R2=0.85; N=154) concentrations suggests conservative mixing of DOM in the White Sea. The strongest linear correlation between CDOM absorption and DOC was found in the ultraviolet (DOC=56.31±2.76+9.13±0.15×aCDOM(254); R2=0.99; N=155), which provides an easy and robust tool to trace DOC using CDOM absorption measurements as well as remote sensing algorithms. Deviations from this linear relationship in surface waters likely indicate contribution from different rivers along the coast of the White Sea. Characteristics of CDOM further indicate that there is limited removal or change in the DOM pool before it exits to the Barents Sea

Contrasting optical properties of surface waters across the Fram Strait and its potential biological implications

AbstractUnderwater light regime is controlled by distribution and optical properties of colored dissolved organic matter (CDOM) and particulate matter. The Fram Strait is a region where two contrasting water masses are found. Polar water in the East Greenland Current (EGC) and Atlantic water in the West Spitsbergen Current (WSC) differ with regards to temperature, salinity and optical properties. We present data on absorption properties of CDOM and particles across the Fram Strait (along 79° N), comparing Polar and Atlantic surface waters in September 2009 and 2010. CDOM absorption of Polar water in the EGC was significantly higher (more than 3-fold) compared to Atlantic water in the WSC, with values of absorption coefficient, aCDOM(350), m−1 of 0.565±0.100 (in 2009) and 0.458±0.117 (in 2010), and 0.138±0.036 (in 2009) and 0.153±0.039 (in 2010), respectively. An opposite pattern was observed for particle absorption with higher absorption found in the eastern part of the Fram Strait. Average values of particle absorption (aP(440), m−1) were 0.016±0.013 (in 2009) and 0.014±0.011 (in 2010), and 0.047±0.012 (in 2009) and 0.016±0.014 (in 2010), respectively for Polar and Atlantic water. Thus absorption of light in eastern part of the Fram Strait is dominated by particles — predominantly phytoplankton, and the absorption of light in the western part of the strait is dominated by CDOM, with predominantly terrigenous origin. As a result the balance between the importance of CDOM and particulates to the total absorption budget in the upper 0–10m shifts across Fram Strait. Under water spectral irradiance profiles were generated using ECOLIGHT 5.4.1 and the results indicate that the shift in composition between dissolved and particulate material does not influence substantially the penetration of photosynthetic active radiation (PAR, 400–700nm), but does result in notable differences in ultraviolet (UV) light penetration, with higher attenuation in the EGC. Future changes in the Arctic Ocean system will likely affect EGC through diminishing sea-ice cover and potentially increasing CDOM export due to increase in river runoff into the Arctic Ocean. Role of attenuation of light by CDOM in determining underwater light regime will become more important, with a potential for future increase in marine productivity in the area of EGC due to elevated PAR and lowered UV light exposures

Observations of preferential summer melt of Arctic sea-ice ridge keels from repeated multibeam sonar surveys

Sea-ice ridges constitute a large fraction of the total Arctic sea-ice area (up to 40 %–50 %); nevertheless, they are the least studied part of the ice pack. Here we investigate sea-ice melt rates using rare, repeated underwater multibeam sonar surveys that cover a period of 1 month during the advanced stage of sea-ice melt. Bottom melt increases with ice draft for first- and second-year level ice and a first-year ice ridge, with an average of 0.46, 0.55, and 0.95 m of total snow and ice melt in the observation period, respectively. On average, the studied ridge had a 4.6 m keel bottom draft, was 42 m wide, and had 4 % macroporosity. While bottom melt rates of ridge keel were 3.8 times higher than first-year level ice, surface melt rates were almost identical but responsible for 40 % of ridge draft decrease. Average cross-sectional keel melt ranged from 0.2 to 2.6 m, with a maximum point ice loss of 6 m, showcasing its large spatial variability. We attribute 57 % of the ridge total (surface and bottom) melt variability to keel draft (36 %), slope (32 %), and width (27 %), with higher melt for ridges with a larger draft, a steeper slope, and a smaller width. The melt rate of the ridge keel flanks was proportional to the draft, with increased keel melt within 10 m of its bottom corners and the melt rates between these corners comparable to the melt rates of level ice.</p

Marine CDOM accumulation during a coastal Arctic mesocosm experiment: No response to elevated pCO2levels

A large-scale multidisciplinary mesocosm experiment in an Arctic fjord (Kongsfjorden, Svalbard; 78°56.2′N) was used to study Arctic marine food webs and biogeochemical elements cycling at natural and elevated future carbon dioxide (CO2) levels. At the start of the experiment, marine-derived chromophoric dissolved organic matter (CDOM) dominated the CDOM pool. Thus, this experiment constituted a convenient case to study production of autochthonous CDOM, which is typically masked by high levels of CDOM of terrestrial origin in the Arctic Ocean proper. CDOM accumulated during the experiment in line with an increase in bacterial abundance; however, no response was observed to increased pCO2 levels. Changes in CDOM absorption spectral slopes indicate that bacteria were most likely responsible for the observed CDOM dynamics. Distinct absorption peaks (at ~ 330 and ~ 360 nm) were likely associated with mycosporine-like amino acids (MAAs). Due to the experimental setup, MAAs were produced in absence of ultraviolet exposure providing evidence for MAAs to be considered as multipurpose metabolites rather than simple photoprotective compounds. We showed that a small increase in CDOM during the experiment made it a major contributor to total absorption in a range of photosynthetically active radiation (PAR, 400–700 nm) and, therefore, is important for spectral light availability and may be important for photosynthesis and phytoplankton groups composition in a rapidly changing Arctic marine ecosystem