Enhanced spontaneous raman signal collected evanescently by silicon nitride slot waveguides

We investigate the effect of waveguide geometry on the conversion efficiency of Raman signals collected by integrated photonic waveguides. Compared to strip-type photonic wires, we report a six-fold increase in conversion efficiency for silicon-nitride slot-waveguides

Enhancement of raman scattering efficiency by a metallic nano-antenna on top of a high index contrast waveguide

We theoretically study coupling of dipole radiation into integrated Si3N4 strip waveguides functionalized with a nanoplasmonic antenna. This structure enables efficient coupling of enhanced Raman signals into the fundamental TE-mode of the waveguide

Surface enhanced Raman spectroscopy on single mode nanophotonic-plasmonic waveguides

We analyze the generation of Surface Enhanced Raman Spectroscopy signals from integrated bowtie antennas, excited and collected by a single mode silicon nitride waveguide, and discuss strategies to enhance the Signal-to-Noise Ratio

Surface enhanced Raman spectroscopy using a single mode nanophotonic-plasmonic platform

Surface Enhanced Raman Spectroscopy (SERS) is a well-established technique for enhancing Raman signals. Recently photonic integrated circuits have been used, as an alternative to microscopy based excitation and collection, to probe SERS signals from external metallic nanoparticles. However, in order to develop quantitative on-chip SERS sensors, integration of dedicated nanoplasmonic antennas and waveguides is desirable. Here we bridge this gap by demonstrating for the first time the generation of SERS signals from integrated bowtie nanoantennas, excited and collected by a single mode waveguide, and rigorously quantify the enhancement process. The guided Raman power generated by a 4-Nitrothiophenol coated bowtie antenna shows an 8 x 10^6 enhancement compared to the free-space Raman scattering. An excellent correspondence is obtained between the theoretically predicted and observed absolute Raman power. This work paves the way towards fully integrated lab-on-a-chip systems where the single mode SERS-probe can be combined with other photonic, fluidic or biological functionalities.Comment: Submitted to Nature Photonic

Silicon-nitride waveguides for on-chip Raman spectroscopy

The evanescent tail of the guided modes can efficiently excite Raman active molecules located in the cladding of a waveguide. Similarly, a significant fraction of the total emitted Stokes power is evanescently coupled to the same mode. Further, the enhancement effects inherent to the waveguide, alongside with the long interaction length, lead to an increased light-matter interaction, resulting in a higher sensitivity as required by spectroscopic applications, especially in the context of Raman spectroscopy. We calculate the spontaneous Raman scattering efficiency as a function of siliconnitride strip waveguide dimensions and show that under typical conditions, the overall efficiency is approximately two orders of magnitude higher than in confocal configuration in the free space. We also report the experimental demonstration of the use of silicon-nitride based photonic waveguides in a lab-on-a-chip context for Raman spectroscopy. To the best of our knowledge, this is the first demonstration of Raman spectroscopy using photonic waveguides

Near-infrared grating couplers for silicon nitride photonic wires

Silicon nitride is a promising high-index material for dense photonic circuits and applications in the visible-midinfrared wavelength regime. Design, fabrication, and optical characterization of silicon nitride waveguides at visible-near-infrared wavelength are presented. Finally, design and experimental results are presented for the first time for linear and focused grating couplers (GCs) at near-infrared wavelength (900 nm) for plasma-enhanced chemical vapor deposition silicon nitride wires (220 x 500 nm) and compared with theoretical simulations. An experimental efficiency of 5.7 and 6.5 dB and 1-dB bandwidth of 26 and 40 nm are reported for the linear and focused GCs, respectively

Determining size of an optically trapped particle via modulated Raman spectroscopy

The average Raman signal power obtained in a modulated optical trap is dependent on the Brownian motion - therefore hydrodynamic properties of the trapped particle. Hence, in addition to the molecular properties obtained from the Raman signal, it is possible to study hydrodynamic properties (e.g. size) of the particle by analyzing the change in the average Raman power as a function of modulation frequency. Our results, based on the over-damped Langevin equation, show that several minimas exist for the Raman signal at unique modulating frequencies for a given particle size and signal acquisition time. In typical experimental conditions, such minimas can be as low as 50% of the Raman signal in an unmodulated trap

Nanophotonic waveguide enhanced Raman spectroscopy of biological submonolayers

Characterizing a monolayer of biological molecules has been a major challenge. We demonstrate nanophotonic wave-guide enhanced Raman spectroscopy (NWERS) of monolayers in the near-infrared region, enabling real-time measurements of the hybridization of DNA strands and the density of sub-monolayers of biotin-streptavidin complex immobilized on top of a photonics chip. NWERS is based on enhanced evanescent excitation and collection of spontaneous Raman scattering near nanophotonic waveguides, which for a one centimeter silicon nitride waveguide delivers a signal that is more than four orders of magnitude higher in comparison to a confocal Raman microscope. The reduced acquisition time and specificity of the signal allows for a quantitative and real-time characterization of surface species, hitherto not possible using Raman spectroscopy. NWERS provides a direct analytic tool for monolayer research and also opens a route to compact microscope-less lab-on-a-chip devices with integrated sources, spectrometers and detectors fabricated using a mass-producible CMOS technology platform