Molecular dynamics simulations of nanosheets of polymeric carbon nitride and comparison with experimental observations

A computational study of the properties of polymeric carbon nitride using molecular dynamics is presented. The analysis of ideal infinite-extent sheets permits to evaluate the effect of temperature on the network of hydrogen bonds responsible for the linkage of the material. The weakening of this binding mechanism at sufficiently high temperatures, together with the inter-layer interactions characteristic of this type of 2D materials, is shown to determine the conformation properties of polymeric carbon nitride at the nanoscale. The results obtained from the simulation of finite samples in the canonical ensemble at varying temperatures are consistent with those from the characterization of our experimentally synthesized samples. Hydrogen bonding between adjacent polymer ribbons leads this process and is the cause of the typical crumpled structure of this material

From urea to melamine cyanurate: Study of a class of thermal condensation routes for the preparation of graphitic carbon nitride

Producción CientíficaThis work presents a survey of the intermediates in the well-known thermal synthesis of graphitic carbon nitride from urea. The analysis of the crystalline phases depicts a successive transformation of the precursor into different substances previously used as starting reactants, whereby melamine cyanurate arises as the ultimate precursor of a class of thermal condensation routes to obtain graphitic carbon nitride. The study of the optical properties of the synthesized materials evidences the simultaneous production of an amorphous phase with a significant presence of melon oligomers. These results are also supported by the further characterization of the materials performed using THz-TDS, FT-IR, HRTEM, and XPS techniques, and by theoretical studies conducted using semi-empirical quantum chemistry methods.Junta de Castilla y León (grant VA296P18)Ministerio de Ciencia, Innovación y Universidades (grant PID2020-320 119418GB-I00

Nuevos métodos de obtención de bioqueroseno a partir de extractos de algas

A partir de biomasa de algas en forma de pasta y procedente de su centrifugación (Nanochloropsis gaditana, Ascophyllum Nodosum y Laminaria Digitata) se elabora por procedimiento de solvólisis un biodiesel susceptible de hidrogenación en bioquioqueroseno y para su posterior uso como combustible de aviones. Este trabajo investiga la composición de las algas en ácido algínico y en sus unidades constituyentes o ácidos manurónico y gulurónico, y el contenido en alginato de sodio sobre algas secas. La valorización de residuos procedentes de centrifugados de algas con bajo contenido en aceite, se ha mostrado útil para la extracción de los mismos, y posterior solvolisis ácida y extracción con disolventes (acetilacetona y el etilenglicol). Especialmente la espectroscopía 1 HNMR y 13 CNMR se ha mostrado útil para identificar en los aceites, ácidos grasos próximos al ácido cis-cis-9,12- octadecadienoico. Por esterificación y subsiguiente hidrogenación se produce el bioqueroseno objeto de estudi

Confirmation of a New Metal-poor Globular Cluster in the Galactic Bulge

© 2018. The American Astronomical Society. All rights reserved.We use deep near-IR photometry of the VISTA Variables in the V'a L'ctea (VVV) Survey and deep DECam Plane Survey (DECaPS) optical photometry to confirm the physical reality of the candidate globular cluster (GC) Minni 22, which is located in the Galactic bulge. This object, which was detected as a high density region in our maps of bulge red giants, is now confirmed as a real GC based on the optical and near-IR color'magnitude diagrams. We also recover three known fundamental mode (ab type) RR Lyrae stars within 2 arcmin of the cluster center. The presence of RR Lyrae stars also seems to confirm Minni 22 as a bonafide old and metal-poor GC. We estimate a cluster reddening E(J - Ks) = 0.6 mag and determine its heliocentric distance D = 7.4 ± 0.3 kpc. The optical and near-IR color'magnitude diagrams reveal well-defined red giant branches in all cases, including a red giant branch bump at Ks = 13.30 ± 0.05 mag. The comparison with theoretical isochrones yields a mean metallicity of [Fe/H] = -1.3 ± 0.3 dex, and age of t ∼ 11.2 Gyr. This is a good example of a new low-luminosity (MV = -6.2 mag) GC found in the central bulge of the Milky Way. After discussing the different ways to confirm the existence of bulge GC candidates, we find that one of the best methods is to use the CMDs from the combination of the DECaPS + VVV photometries.Peer reviewe

VVV-WIT-12 and Its Fashionable Nebula: A 4 yr Long-period Young Stellar Object with a Light Echo?

© 2023. The Author(s). Published by the American Astronomical Society. This is an open access article distributed under the terms of the Creative Commons Attribution License (CC BY), https://creativecommons.org/licenses/by/4.0/We report the serendipitous discovery of VVV-WIT-12, an unusual variable source that seems to induce variability in its surrounding nebula. The source belongs to the rare objects that we call WITs (short for What Is This?) discovered within the VISTA Variables in the Vía Láctea (VVV) survey. VVV-WIT-12 was discovered during a pilot search for light echoes from distant supernovae in the Milky Way using the near-IR images of the VVV survey. This source has an extremely red spectral energy distribution, consistent with a very reddened (A V ∼ 100 mag) long-period variable star (P ∼ 1525 days). Furthermore, it is enshrouded in a nebula that changes brightness and color with time, apparently in sync with the central source variations. The near-IR light curve and complementary follow-up spectroscopy observations are consistent with a variable young stellar object illuminating its surrounding nebula. In this case the source periodic variation along the cycles produces an unprecedented light echo in the different regions of the nebula.Peer reviewe

Lights and shadows concerning platelet products for musculoskeletal regeneration.

Various types of platelet (PLT) products, such as Platelet Rich Plasma (PRP) and Platelet Gel (PG), derived from autologous peripheral blood, have been used for tissue repair. The good clinical outcomes, due mainly to their safety and Growth Factor (GF) content, have led to a wide use of PLT products in many fields of medicine. However, until now the existing literature adds controversies to the use of PLT concentrates. When talking about PLTs and their products, a great number of variables have to be considered. These variables are mainly related to PRP preparation methods, the type of activators, intra- and inter-species variability, types of pathology to be treated, the ways and times of administration and the association of PRP or PG with other treatments. This review considers and discusses these causes of variability with particular attention to orthopaedic implications. The possibility of improving the knowledge on variables affecting therapeutic efficacy will surely help in addressing the best combination of factors implied in the different steps of PLT concentrate preparation and use

A Benchmark White Dwarf-Ultracool Dwarf Wide Field Binary

© 2023 The Author(s). Published by Oxford University Press on behalf of Royal Astronomical Society. This is an open access article distributed under the terms of the Creative Commons Attribution License (CC BY), https://creativecommons.org/licenses/by/4.0/We present the discovery and multi-wavelength characterisation of VVV J1438-6158 AB, a new field wide-binary system consisting of a 4.6(+5.5-2.4) Gyr and Teff = 9500+/-125 K DA white dwarf (WD) and a Teff = 2400+/-50 K M8 ultracool dwarf (UCD). The projected separation of the system is a = 1236.73 au (~13.8"), and although along the line-of-sight towards the Scorpius-Centaurus (Sco-Cen) stellar association, VVV J1438-6158 AB is likely to be a field star, from a kinematic 6D probabilistic analysis. We estimated the physical, and dynamical parameters of both components via interpolations with theoretical models and evolutionary tracks, which allowed us to retrieve a mass of 0.62+/-0.18 MSun for the WD, and a mass of 98.5+/-6.2 MJup (~0.094+/-0.006 MSun) for the UCD. The radii of the two components were also estimated at 0.01309+/-0.0003 RSun and 1.22+/-0.05 RJup, respectively. VVV J1438-6158 AB stands out as a benchmark system for comprehending the evolution of WDs and low-mass companions given its status as one of the most widely separated WD+UCD systems known to date, which likely indicates that both components may have evolved independently of each other, and also being characterised by a large mass-ratio (q = 0.15+/-0.04), which likely indicates a formation pathway similar to that of stellar binary systems.Peer reviewe

KMT-2018-BLG-1292: A Super-Jovian Microlens Planet in the Galactic Plane

We report the discovery of KMT-2018-BLG-1292Lb, a super-Jovian $M_{\rm planet} = 4.5\pm 1.3\,M_J$ planet orbiting an F or G dwarf $M_{\rm host} = 1.5\pm 0.4\,M_\odot$, which lies physically within {\cal O}(10\,\pc) of the Galactic plane. The source star is a heavily extincted $A_I\sim 5.2$ luminous giant that has the lowest Galactic latitude, $b=-0.28^\circ$, of any planetary microlensing event. The relatively blue blended light is almost certainly either the host or its binary companion, with the first explanation being substantially more likely. This blend dominates the light at $I$ band and completely dominates at $R$ and $V$ bands. Hence, the lens system can be probed by follow-up observations immediately, i.e., long before the lens system and the source separate due to their relative proper motion. The system is well characterized despite the low cadence $\Gamma=0.15$--$0.20\,{\rm hr^{-1}}$ of observations and short viewing windows near the end of the bulge season. This suggests that optical microlensing planet searches can be extended to the Galactic plane at relatively modest cost.Comment: 35 pages, 3 Tables, 8 figure

Comparison of the activities of C2N and BCNO towards Congo red degradation

An n-type organic carbon nitride semiconductor, C2N, was synthesized by the pyrolysis of uric acid, and its properties were investigated by scanning electron and transmission electron microscopies, X-ray powder diffraction, and vibrational, UV-visible and X-ray photoelectron spectroscopies. This novel material, composed of crystalline flakes, featured a broad absorption centered at 700¿nm, possibly due to charge transfer, and a 2.49¿eV band gap. Its catalytic performance was assessed for the treatment of effluents with the diazo dye Congo red, comparing it with that of boron carbon nitrogen oxide, BCNO. Both wide band gap semiconductors exhibited decolorizing activity in the dark, although the mechanisms were different and were not photocatalytic: BCNO was more effective towards the adsorption-coordination due to the presence of B-O, while C2N was effective towards the adsorption and the advancement of the oxidation reaction. Their kinetic constants (0.19 and 0.02 min-1 for BCNO and C2N, respectively) were comparable to those of intermetallic compounds studied for azo dyes degradation in dark conditions. In view of the high color removal efficiency (97% after 20¿min) and good reusability of BCNO, this study suggests a potential application of this catalyst for wastewater treatment, alone or in combination with C2N