Xe 4d photoionization in Xe@C60, Xe@C240, and Xe@C60@C240

Re-evaluated parameters for the square-well potential model for photoionization of endo-fullerenes are proposed and employed to reveal the spectacular modifications in the Xe 4d photoionization giant resonance along the path from Xe@C60 to Xe@C240 to multi-walled Xe@[email protected]: 1 page, 1 figure. 2011 International Conference on Photonic, Electronic, and Atomic Collisions (Belfast, UK, 2011), abstract Tue13

Cold adaptation and replicable microbial community development during long-term low temperature anaerobic digestion treatment of synthetic sewage

The development and, activity of a cold-adapting microbial community was monitored during low temperature anaerobic digestion (LtAD) treatment of wastewater. Two replicate hybrid anaerobic sludge bed-fixed-film reactors treated a synthetic sewage wastewater at 12°C, at organic loading rates of 0.25–1.0 kg Chemical Oxygen Demand (COD) m−3 d−1, over 889 days. The inoculum was obtained from a full-scale AD reactor, which was operated at 37˚C. Both LtAD reactors readily degraded the influent with COD removal efficiencies regularly exceeding 78% for both the total and soluble COD fractions. The biomass from both reactors was sampled temporally and tested for activity against hydrolytic and methanogenic substrates at 12˚C and 37˚C. Data indicated that significantly enhanced low-temperature hydrolytic and methanogenic activity developed in both systems. For example, the hydrolysis rate constant (K) at 12°C had increased 20–30-fold by comparison to the inoculum by day 500. Substrate affinity also increased for hydrolytic substrates at low temperature. Next generation sequencing demonstrated that a shift in community structure occurred over the trial, involving a 1-log-fold change in 25 SEQS (OTU-free approach) from the inoculum. Microbial community structure changes and process performance were replicable in the LtAD reactors

Reionization in Technicolor

We present the Technicolor Dawn simulations, a suite of cosmological radiation-hydrodynamic simulations of the first 1.2 billion years. By modeling a spatially-inhomogeneous UVB on-the-fly with 24 frequencies and resolving dark matter halos down to $10^8 M_\odot$ within 12 $h^{-1}$ Mpc volumes, our simulations unify observations of the intergalactic and circumgalactic media, galaxies, and reionization into a common framework. The only empirically-tuned parameter, the fraction $f_{\mathrm{esc,gal}}(z)$ of ionizing photons that escape the interstellar medium, is adjusted to match observations of the Lyman-$\alpha$ forest and the cosmic microwave background. With this single calibration, our simulations reproduce the history of reionization; the stellar mass-star formation rate relation of galaxies; the number density and metallicity of damped Lyman-$\alpha$ absorbers (DLAs) at $z\sim5$; the abundance of weak metal absorbers; the ultraviolet background (UVB) amplitude; and the Lyman-$\alpha$ flux power spectrum at $z=5.4$. The galaxy stellar mass and UV luminosity functions are underproduced by $\leq2\times$, suggesting an overly vigorous feedback model. The mean transmission in the Lyman-$\alpha$ forest is underproduced at $z<6$, indicating tension between measurements of the UVB amplitude and Lyman-$\alpha$ transmission. The observed SiIV column density distribution is reasonably well-reproduced ($\sim 1\sigma$ low). By contrast, CIV remains significantly underproduced despite being boosted by an intense $>4$ Ryd UVB. Solving this problem by increasing metal yields would overproduce both weak absorbers and DLA metallicities. Instead, the observed strength of high-ionization emission from high-redshift galaxies and absorption from their environments suggest that the ionizing flux from conventional stellar population models is too soft.Comment: 24 pages, 17 figures, accepted to MNRA

Quantum chaotic resonances from short periodic orbits

We present an approach to calculating the quantum resonances and resonance wave functions of chaotic scattering systems, based on the construction of states localized on classical periodic orbits and adapted to the dynamics. Typically only a few of such states are necessary for constructing a resonance. Using only short orbits (with periods up to the Ehrenfest time), we obtain approximations to the longest living states, avoiding computation of the background of short living states. This makes our approach considerably more efficient than previous ones. The number of long lived states produced within our formulation is in agreement with the fractal Weyl law conjectured recently in this setting. We confirm the accuracy of the approximations using the open quantum baker map as an example.Comment: 4 pages, 4 figure

Periodic orbit bifurcations and scattering time delay fluctuations

We study fluctuations of the Wigner time delay for open (scattering) systems which exhibit mixed dynamics in the classical limit. It is shown that in the semiclassical limit the time delay fluctuations have a distribution that differs markedly from those which describe fully chaotic (or strongly disordered) systems: their moments have a power law dependence on a semiclassical parameter, with exponents that are rational fractions. These exponents are obtained from bifurcating periodic orbits trapped in the system. They are universal in situations where sufficiently long orbits contribute. We illustrate the influence of bifurcations on the time delay numerically using an open quantum map.Comment: 9 pages, 3 figures, contribution to QMC200

Autocorrelation of Random Matrix Polynomials

We calculate the autocorrelation functions (or shifted moments) of the characteristic polynomials of matrices drawn uniformly with respect to Haar measure from the groups U(N), O(2N) and USp(2N). In each case the result can be expressed in three equivalent forms: as a determinant sum (and hence in terms of symmetric polynomials), as a combinatorial sum, and as a multiple contour integral. These formulae are analogous to those previously obtained for the Gaussian ensembles of Random Matrix Theory, but in this case are identities for any size of matrix, rather than large-matrix asymptotic approximations. They also mirror exactly autocorrelation formulae conjectured to hold for L-functions in a companion paper. This then provides further evidence in support of the connection between Random Matrix Theory and the theory of L-functions

5s correlation confinement resonances in Xe-endo-fullerenes

Spectacular trends in the modification of the Xe 5s photoionization via interchannel coupling with confinement resonances emerging in the Xe 4d giant resonance upon photoionization of the Xe@C60, Xe@C240 and Xe@C60@C240 endo-fullerenes are theoretically unraveled and interpreted.Comment: 1 page, 1 figure. 2011 International Conference on Photonic, Electronic, and Atomic Collisions (Belfast, UK, 2011). Paper number We15

Ozone reference models for the middle atmosphere (new CIRA)

Models of ozone vertical structure were generated that were based on multiple data sets from satellites. The very good absolute accuracy of the individual data sets allowed the data to be directly combined to generate these models. The data used for generation of these models are from some of the most recent satellite measurements over the period 1978 to 1983. A discussion is provided of validation and error analyses of these data sets. Also, inconsistencies in data sets brought about by temporal variations or other factors are indicated. The models cover the pressure range from from 20 to 0.003 mb (25 to 90 km). The models for pressures less than 0.5 mb represent only the day side and are only provisional since there was limited longitudinal coverage at these levels. The models start near 25 km in accord with previous COSPAR international reference atmosphere (CIRA) models. Models are also provided of ozone mixing ratio as a function of height. The monthly standard deviation and interannual variations relative to zonal means are also provided. In addition to the models of monthly latitudinal variations in vertical structure based on satellite measurements, monthly models of total column ozone and its characteristic variability as a function of latitude based on four years of Nimbus 7 measurements, models of the relationship between vertical structure and total column ozone, and a midlatitude annual mean model are incorporated in this set of ozone reference atmospheres. Various systematic variations are discussed including the annual, semiannual, and quasibiennial oscillations, and diurnal, longitudinal, and response to solar activity variations

Europe as a multilevel federation

Peer reviewedPublisher PD