982 research outputs found

    The influence of vehicle aerodynamic and control response characteristics on driver-vehicle performance

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    The effects of changes in understeer, control sensitivity, and location of the lateral aerodynamic center of pressure (c.p.) of a typical passenger car on the driver's opinion and on the performance of the driver-vehicle system were studied in a moving-base driving simulator. Twelve subjects with no prior experience on the simulator and no special driving skills performed regulation tasks in the presence of both random and step wind gusts

    Predicting Rainfall in the Context of Rainfall Derivatives Using Genetic Programming

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    Rainfall is one of the most challenging variables to predict, as it exhibits very unique characteristics that do not exist in other time series data. Moreover, rainfall is a major component and is essential for applications that surround water resource planning. In particular, this paper is interested in the prediction of rainfall for rainfall derivatives. Currently in the rainfall derivatives literature, the process of predicting rainfall is dominated by statistical models, namely using a Markov-chain extended with rainfall prediction (MCRP). In this paper we outline a new methodology to be carried out by predicting rainfall with Genetic Programming (GP). This is the first time in the literature that GP is used within the context of rainfall derivatives. We have created a new tailored GP to this problem domain and we compare the performance of the GP and MCRP on 21 different data sets of cities across Europe and report the results. The goal is to see whether GP can outperform MCRP, which acts as a benchmark. Results indicate that in general GP significantly outperforms MCRP, which is the dominant approach in the literature

    Structure of nanoparticles embedded in micellar polycrystals

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    We investigate by scattering techniques the structure of water-based soft composite materials comprising a crystal made of Pluronic block-copolymer micelles arranged in a face-centered cubic lattice and a small amount (at most 2% by volume) of silica nanoparticles, of size comparable to that of the micelles. The copolymer is thermosensitive: it is hydrophilic and fully dissolved in water at low temperature (T ~ 0{\deg}C), and self-assembles into micelles at room temperature, where the block-copolymer is amphiphilic. We use contrast matching small-angle neuron scattering experiments to probe independently the structure of the nanoparticles and that of the polymer. We find that the nanoparticles do not perturb the crystalline order. In addition, a structure peak is measured for the silica nanoparticles dispersed in the polycrystalline samples. This implies that the samples are spatially heterogeneous and comprise, without macroscopic phase separation, silica-poor and silica-rich regions. We show that the nanoparticle concentration in the silica-rich regions is about tenfold the average concentration. These regions are grain boundaries between crystallites, where nanoparticles concentrate, as shown by static light scattering and by light microscopy imaging of the samples. We show that the temperature rate at which the sample is prepared strongly influence the segregation of the nanoparticles in the grain-boundaries.Comment: accepted for publication in Langmui

    Quantitative description of temperature induced self-aggregation thermograms determined by differential scanning calorimetry

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    A novel thermodynamic approach for the description of differential scanning calorimetry (DSC) experiments on self-aggregating systems is derived and presented. The method is based on a mass action model where temperature dependence of aggregation numbers is considered. The validity of the model was confirmed by describing the aggregation behavior of poly(ethylene oxide)-poly(propylene oxide) block copolymers, which are well-known to exhibit a strong temperature dependence. The quantitative description of the thermograms could be performed without any discrepancy between calorimetric and van 't Hoff enthalpies, and moreover, the aggregation numbers obtained from the best fit of the DSC experiments are in good agreement with those obtained by light scattering experiments corroborating the assumptions done in the derivation of the new model

    Pricing Rainfall Based Futures Using Genetic Programming

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    Rainfall derivatives are in their infancy since starting trading on the Chicago Mercantile Exchange (CME) since 2011. Being a relatively new class of financial instruments there is no generally recognised pricing framework used within the literature. In this paper, we propose a novel framework for pricing contracts using Genetic Programming (GP). Our novel framework requires generating a risk-neutral density of our rainfall predictions generated by GP supported by Markov chain Monte Carlo and Esscher transform. Moreover, instead of having a single rainfall model for all contracts, we propose having a separate rainfall model for each contract. We compare our novel framework with and without our proposed contract-specific models for pricing against the pricing performance of the two most commonly used methods, namely Markov chain extended with rainfall prediction (MCRP), and burn analysis (BA) across contracts available on the CME. Our goal is twofold, (i) to show that by improving the predictive accuracy of the rainfall process, the accuracy of pricing also increases. (ii) contract-specific models can further improve the pricing accuracy. Results show that both of the above goals are met, as GP is capable of pricing rainfall futures contracts closer to the CME than MCRP and BA. This shows that our novel framework for using GP is successful, which is a significant step forward in pricing rainfall derivatives

    Towards generalized measures grasping CA dynamics

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    In this paper we conceive Lyapunov exponents, measuring the rate of separation between two initially close configurations, and Jacobians, expressing the sensitivity of a CA's transition function to its inputs, for cellular automata (CA) based upon irregular tessellations of the n-dimensional Euclidean space. Further, we establish a relationship between both that enables us to derive a mean-field approximation of the upper bound of an irregular CA's maximum Lyapunov exponent. The soundness and usability of these measures is illustrated for a family of 2-state irregular totalistic CA

    Degradation versus self-assembly of block copolymer micelles

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    The stability of micelles self-assembled from block copolymers can be altered by the degradation of the blocks. Slow degradation shifts the equilibrium size distribution of block copolymer micelles and change their properties. Quasi-equilibrium scaling theory shows that the degradation of hydrophobic blocks in the core of micelles destabilize the micelles reducing their size, while the degradation of hydrophilic blocks forming coronas of micelles favors larger micelles and may, at certain conditions, induce the formation of micelles from individual chains.Comment: Published in Langmuir http://pubs.acs.org/doi/pdf/10.1021/la204625

    Re-structuring of marine communities exposed to environmental change

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    Species richness is the most commonly used but controversial biodiversity metric in studies on aspects of community stability such as structural composition or productivity. The apparent ambiguity of theoretical and experimental findings may in part be due to experimental shortcomings and/or heterogeneity of scales and methods in earlier studies. This has led to an urgent call for improved and more realistic experiments. In a series of experiments replicated at a global scale we translocated several hundred marine hard bottom communities to new environments simulating a rapid but moderate environmental change. Subsequently, we measured their rate of compositional change (re-structuring) which in the great majority of cases represented a compositional convergence towards local communities. Re-structuring is driven by mortality of community components (original species) and establishment of new species in the changed environmental context. The rate of this re-structuring was then related to various system properties. We show that availability of free substratum relates negatively while taxon richness relates positively to structural persistence (i.e., no or slow re-structuring). Thus, when faced with environmental change, taxon-rich communities retain their original composition longer than taxon-poor communities. The effect of taxon richness, however, interacts with another aspect of diversity, functional richness. Indeed, taxon richness relates positively to persistence in functionally depauperate communities, but not in functionally diverse communities. The interaction between taxonomic and functional diversity with regard to the behaviour of communities exposed to environmental stress may help understand some of the seemingly contrasting findings of past research

    Adsorption of F127 onto Single-Walled Carbon Nanotubes Characterized Using Small-Angle Neutron Scattering

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    Aqueous single-walled carbon nanotube dispersions are often made using polymers from the pluronic family of amphiphilic block copolymers; however, relatively few studies have been conducted using small-angle neutron scattering techniques to discover the mechanism by which they act. SANS results reported here show that a relatively simple core-shell cylinder model can be used to fit data successfully at different contrasts. The results across all contrasts showed that the best fit gave an inner nanotube radius of 10 Å, corresponding to small nanotube bundles with a small amount of water present (20%), and a polydisperse adsorbed layer thickness of 61 Å, with a water content of 94% in the adsorbed layer. The data fitting is thus consistent with a small SWCNT bundle surrounded by an extended and water-swollen F127 adsorbed layer. Comparing the scattering from F127/SWCNT at different contrasts, it has been found that the polymer-decorated SWCNTs are contrast matched at a D2O/H2O volume ratio of 0.36:0.64, corresponding to a scattering-length density of 1.92 × 10-6 Å-2. (Figure Presented).</p
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