Multipore zeolites: synthesis and catalytic applications

[EN] In the last few years, important efforts have been made to synthesize so-called "multipore" zeolites, which contain channels of different dimensions within the same crystalline structure. This is a very attractive subject, since the presence of pores of different sizes would favor the preferential diffusion of reactants and products through those different channel systems, allowing unique catalytic activities for specific chemical processes. In this Review we describe the most attractive achievements in the rational synthesis of multipore zeolites, containing small to extra-large pores, and the improvements reported for relevant chemical processes when these multipore zeolites have been used as catalysts.Financial support by the Spanish Government-MINECO through “Severo Ochoa” (SEV 2012-0267), Consolider Ingenio 2010-Multicat, MAT2012-37160, MAT2012-31657 and Intramural-201480I015 is acknowledged.Moliner Marin, M.; Martínez, C.; Corma Canós, A. (2015). Multipore zeolites: synthesis and catalytic applications. Angewandte Chemie International Edition. 54(12):3560-3579. https://doi.org/10.1002/anie.201406344S35603579541

Synthesis, Characterization and Catalytic Applications of Organized Mesoporous Aluminas

The synthesis of organized mesoporous aluminas has opened a very interesting area for application of this type of materials, particularly as catalysts or catalyst supports. This review focuses on the individual synthesis routes to produce organized mesoporous aluminas with large surface areas and narrow pore size distributions, and on the evaluation of their textural, chemical and thermal properties and outlines examples of catalytic applications of organized mesoporous alumina-based catalysts. We tried to rationalize the synthetic approaches to prepare organized mesoporous aluminas, to relate their properties to synthetic procedures used as well as to their catalytic behavior in different reactions. Utilization of various structure-directing agents for “cationic,” “neutral,” “anionic,” “nanocasting,” and special approaches leading to scaffolding and lathlike organized mesoporous aluminas is discussed in the first part of this review, as well as textural and structural characterization and thermal stability of mesoporous aluminas synthesized by different synthetic approaches. In the second part, catalytic applications of organized mesoporous aluminas described in the open literature are evaluated from the standpoint of the importance of these reactions for technological applications.Grant Agency of the Academy of Sciences of the Czech Republic (A4040411) Ministry of Industry and Trade of the Czech Republic (FTA/042) European Community (SES6-CT-2005–020133) Ministry of Science and Education of Spain (MAT2003-07769-C02-02; CTQ-2006-06282) CSIC & Academy of Sciences of the Czech Republic(2006CZ0027)Peer reviewe

Space debris observations with the Slovak AGO70telescope: Astrometry and light curves

The Faculty of Mathematics, Physics and Informatics of Comenius University in Bratislava, Slovakia (FMPI) operates its own 0.7-m Newtonian telescope (AGO70) dedicated to the space surveillance tracking and research, with an emphasis on space debris. The observation planning focuses on objects on geosynchronous (GEO), eccentric (GTO and Molniya) and global navigation satellite system (GNSS) orbits. To verify the system’s capabilities, we conducted an observation campaign in 2017, 2018 and 2019 focused on astrometric and photometric measurements. In last two years we have built up a light curve catalogue of space debris which is now freely available for the scientific community. We report periodic signals extracted from more than 285 light curves of 226 individual objects. We constructed phase diagrams for 153 light curves for which we obtained apparent amplitudes