Phase transition in the two-component symmetric exclusion process with open boundaries

We consider single-file diffusion in an open system with two species $A,B$ of particles. At the boundaries we assume different reservoir densities which drive the system into a non-equilibrium steady state. As a model we use an one-dimensional two-component simple symmetric exclusion process with two different hopping rates $D_A,D_B$ and open boundaries. For investigating the dynamics in the hydrodynamic limit we derive a system of coupled non-linear diffusion equations for the coarse-grained particle densities. The relaxation of the initial density profile is analyzed by numerical integration. Exact analytical expressions are obtained for the self-diffusion coefficients, which turns out to be length-dependent, and for the stationary solution. In the steady state we find a discontinuous boundary-induced phase transition as the total exterior density gradient between the system boundaries is varied. At one boundary a boundary layer develops inside which the current flows against the local density gradient. Generically the width of the boundary layer and the bulk density profiles do not depend on the two hopping rates. At the phase transition line, however, the individual density profiles depend strongly on the ratio $D_A/D_B$. Dynamic Monte Carlo simulation confirm our theoretical predictions.Comment: 26 pages, 6 figure

Amplification of Molecular Traffic Control in catalytic grains with novel channel topology design

We investigate the conditions for reactivity enhancement of catalytic processes in porous solids by use of molecular traffic control (MTC). With dynamic Monte-Carlo simulations and continuous-time master equation theory applied to the high concentration regime we obtain a quantitative description of the MTC effect for a network of intersecting single-file channels in a wide range of grain parameters and for optimal external operating conditions. Implementing the concept of MTC in models with specially designed alternating bimodal channels we find the efficiency ratio (compared with a topologically and structurally similar reference system without MTC) to be enhanced with increasing grain diameter, a property verified for the first time for an MTC system. Even for short intersection channels, MTC leads to a reactivity enhancement of up to approximately 65%. This suggests that MTC may significantly enhance the efficiency of a catalytic process for small as well as large porous particles with a suitably chosen binary channel topology.Comment: 15 pages, 12 figure

Amplication of Molecular Traffic Control in catalytic grains with novel channel topology design

We investigate the conditions for reactivity enhancement of catalytic processes in porous solids by the use of molecular traffic control (MTC). With dynamic Monte-Carlo simulations and continuous-time master equation theory applied to the high concentration regime, we obtain a quantitative description of the MTC effect for a network of intersecting single-file channels in a wide range of grain parameters and for optimal external operating conditions. Implementing the concept of MTC in models with specially designed alternating bimodal channels, we find the efficiency ratio (compared with a topologically and structurally similar reference system without MTC) to be enhanced with increasing grain diameter, a property verified for the first time for a MTC system. Even for short intersection channels, MTC leads to a reactivity enhancement of up to approximately 65%. This suggests that MTC may significantly enhance the efficiency of a catalytic process for small as well as large porous particles with a suitably chosen binary channel topology

Boundary-induced bulk phase transition and violation of Fick's law in two-component single-file diffusion with open boundaries

We study two-component single-file diffusion inside a narrow channel that at its ends is open and connected with particle reservoirs. Using a two-species version of the symmetric simple exclusion process as a model, we propose a hydrodynamic description of the coarse-grained dynamics with a self-diffusion coefficient that is inversely proportional to the length of the channel. The theory predicts an unexpected nonequilibrium phase transition for the bulk particle density as the external total density gradient between the reservoirs is varied. The individual particle currents do not in general satisfy Fick's first law. These results are confirmed by extensive dynamical Monte-Carlo simulations for equal diffusivities of the two components.Comment: 12 pages, 3 figure

Molecular Traffic Control in a 3D network of single file channels and fast reactivity

We study the conditions for reactivity enhancement of catalytic processes in porous solids by use of molecular traffic control (MTC) as a function of grain size. We extend a recently introduced two dimensional model system to three dimensions. With dynamic Monte-Carlo simulations and analytical solution of the associated Master equation we obtain a quantitative description of the MTC effect in the limit of fast reactivity. The efficiency ratio (compared with a topologically and structurally similar reference system without MTC) is inversely proportional to the grain diameter.Comment: corrected affiliatio

Bestimmung digitaler Geländemodelle in Wattgebieten aus Laserscannerdaten

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Umsetzung der Istanbul-Kovention

UMSETZUNG DER ISTANBUL-KOVENTION Umsetzung der Istanbul-Kovention / Brzank, Petra (Rights reserved) ( -

“It’s Always Good to Ask”:A Mixed Methods Study on the Perceived Role of Sexual Health Practitioners Asking Gay and Bisexual Men About Experiences of Domestic Violence and Abuse

Development of joint displays is a valued approach to merging qualitative and quantitative findings in mixed methods research. This study aimed to illustrate a case series mixed methods display and the utility of using mixed methods for broadening our understanding of domestic violence and abuse. Using a convergent design, 532 gay and bisexual men participated in a Health and Relationship Survey in a U.K. sexual health service and 19 in an interview. Quantitative and qualitative data were analyzed separately and integrated at the level of interpretation and reporting. There were inconsistencies in perceptions and reports of abuse. Men were supportive of selective enquiry for domestic violence and abuse by practitioners (62.6%; 95% confidence interval = 58.1% to 66.7%) while being mindful of contextual factors.</p

“It’s always good to ask”: a mixed methods study on the perceived role of sexual health practitioners asking gay and bisexual men about experiences of domestic violence and abuse

Development of joint displays is a valued approach to merging qualitative and quantitative findings in mixed methods research. This study aimed to illustrate a case series mixed methods display and the utility of using mixed methods for broadening our understanding of domestic violence and abuse. Using a convergent design, 532 gay and bisexual men participated in a Health and Relationship Survey in a U.K. sexual health service and 19 in an interview. Quantitative and qualitative data were analyzed separately and integrated at the level of interpretation and reporting. There were inconsistencies in perceptions and reports of abuse. Men were supportive of selective enquiry for domestic violence and abuse by practitioners (62.6%; 95% confidence interval = 58.1% to 66.7%) while being mindful of contextual factors

Particle current in symmetric exclusion process with time-dependent hopping rates

In a recent study, (Jain et al 2007 Phys. Rev. Lett. 99 190601), a symmetric exclusion process with time-dependent hopping rates was introduced. Using simulations and a perturbation theory, it was shown that if the hopping rates at two neighboring sites of a closed ring vary periodically in time and have a relative phase difference, there is a net DC current which decreases inversely with the system size. In this work, we simplify and generalize our earlier treatment. We study a model where hopping rates at all sites vary periodically in time, and show that for certain choices of relative phases, a DC current of order unity can be obtained. Our results are obtained using a perturbation theory in the amplitude of the time-dependent part of the hopping rate. We also present results obtained in a sudden approximation that assumes large modulation frequency.Comment: 17 pages, 2 figure