117 research outputs found
Perturbations of AES orbits from tesseral harmonics of gravitational potential expansion
Satellite orbit perturbations from tesseral harmonics of gravitational potential expansio
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Laccase-Enzyme Treated Flax Fibre for Use in Natural Fibre Epoxy Composites
Natural fibres have a high potential as reinforcement of polymer matrices, as they combine a high specific strength and modulus with sustainable production and reasonable prices. Modifying the fibre surface is a common method to increase the adhesion and thereby enhance the mechanical properties of composites. In this study, a novel sustainable surface treatment is presented: the fungal enzyme laccase was utilised with the aim of covalently binding the coupling agent dopamine to flax fibre surfaces. The goal is to improve the interfacial strength towards an epoxy matrix. SEM and AFM micrographs showed that the modification changes the surface morphology, indicating a deposition of dopamine on the surface. Fibre tensile tests, which were performed to check whether the fibre structure was damaged during the treatment, showed that no decrease in tensile strength or modulus occurred. Single fibre pullout tests showed a 30% increase in interfacial shear strength (IFSS) due to the laccase-mediated bonding of the coupling agent dopamine. These results demonstrate that a laccase + dopamine treatment modifies flax fibres sustainably and increases the interfacial strength towards epoxy
Coating of Carbon Nanotube Fibers: Variation of Tensile Properties, Failure Behavior, and Adhesion Strength
An experimental study of the tensile properties of CNT fibers and their interphasial behavior in epoxy matrices is reported. One of the most promising applications of CNT fibers is their use as reinforcement in multifunctional composites. For this purpose, an increase of the tensile strength of the CNT fibers in unidirectional composites as well as strong interfacial adhesion strength is desirable. However, the mechanical performance of the CNT fiber composites manufactured so far is comparable to that of commercial fiber composites. The interfacial properties of CNT fiber/polymer composites have rarely been investigated and provided CNT fiber/epoxy interfacial shear strength (IFSS) of 14.4 MPa studied by the microbond test. In order to improve the mechanical performance of the CNT fibers, an epoxy compatible coating with nano-dispersed aqueous-based polymeric film formers and low viscous epoxy resin, respectively, was applied. For impregnation of high homogeneity, low molecular weight epoxy film formers and polyurethane film formers were used. The aqueous-based epoxy film formers were not crosslinked and able to interdiffuse with the matrix resin after impregnation. Due to good wetting of the individual CNT fibers by the film formers, the degree of activation of the fibers was improved, leading to increased tensile strength and Young’s modulus. Cyclic tensile loading and simultaneous determination of electric resistance enabled to characterize the fiber’s durability in terms of elastic recovery and hysteresis. The pull-out tests and SEM study reveal different interfacial failure mechanisms in CNT fiber/epoxy systems for untreated and film former treated fibers, on the one hand, and epoxy resin treated ones, on the other hand. The epoxy resin penetrated between the CNT bundles in the reference or film former coated fiber, forming a relatively thick CNT/epoxy composite layer and thus shifting the fracture zone within the fiber. In contrast to this, shear sliding along the interface between the matrix and the outer fiber layer impregnated with the resin was observed for epoxy resin-coated fibers. These fibers have been successfully pulled out of the matrix droplets and shown that the average local interfacial shear stress value was 63 MPa (with apparent IFSS values 33–60 MPa). The interfacial frictional stress between the fiber and the matrix was rather high (9.5 MPa), which can be attributed to the complex structure of the interface and the fiber twisting
Investigation of fiber/matrix adhesion: test speed and specimen shape effects in the cylinder test
The cylinder test, developed from the microdroplet test, was adapted to assess the interfacial adhesion strength between fiber and matrix. The sensitivity of cylinder test to pull-out speed and specimen geometry was measured. It was established that the effect of test speed can be described as a superposition of two opposite, simultaneous effects which have been modeled mathematically by fitting two parameter Weibull curves on the measured datas. Effects of the cylinder size and its geometrical relation on the measured strength values have been analyzed by finite element method. It was concluded that the geometry has a direct influence on the stress formation. Based on the results achieved, recommendations were given on how to perform the novel single fiber cylinder test
Transient Multiple Removal and Subsequent Reimplantation of Abdominal and Retroperitoneal Organs with Multisystemic Neoplastic Lesions
The aim of the study was to develop simple, minimally invasive method of transient multiple removal and subsequent reimplantation of abdominal and retroperitoneal organs with multisystemic neoplastic lesions, allowing subsequent reimplantation of the organ block after extracorporeal surgery.
Material and Methods.
Ten human cadavers of subjects who died of causes unrelated to pathology of the abdominal organs were
used in this study. The anatomical experiment involved transient multiple removal of the abdominal and retroperitoneal organs with multisystemic neoplastic lesions and their subsequent reimplantation. Surgery was performed using the method developed at the Department of Operative Surgery and Topographic Anatomy of I.M. Sechenov First Moscow State Medical University (Patent RU 2601100).
Results.
The proposed method showed several advantages: consistency of cold perfusion in deep hypothermia of the patient,hypothermic circulatory arrest of the abdominal organs (up to 4–6 h); feasibility of insertion and subsequent removal of arterial and venous shunts, reimplantation of the abdominal organs; restoration of arterial and venous blood flow in the patient (cadaver) and preserved integrity of the transected anatomical structures.
Conclusion.
The proposed method of transient multiple removal and subsequent reimplantation of the abdominal and retroperitoneal organs with multisystemic neoplastic lesions provides sustained viability of the organs and can be recommended as a suitable model for further application in clinical practice
Hierarchical scaling law for the strength of composite fibre bundles
This paper presents an analytical model for size effects on the longitudinal tensile strength of composite fibre bundles. The strength of individual fibres is modelled by a Weibull distribution, while the matrix (or fibre–matrix interface) is represented through a perfectly–plastic shear–lag model. A probabilistic analysis of the failure process in hierarchical bundles (bundles of bundles) is performed, so that a scaling law relating the strength distributions and characteristic lengths of consecutive bundle levels is derived. An efficient numerical scheme (based on asymptotic limits) is proposed, hence coupon– sized bundle strength distributions are obtained almost instantaneously. Parametric studies show that both fibre and matrix properties are critical for bundle strength; model predictions at different scales are validated against experimental results available in the literature
First results from the Soviet-American gallium experiment
The Soviet-American Gallium Experiment is the first experiment able to measure the dominant flux of low energy p-p solar neutrinos. Four extractions made during January to May 1990 from 30 tons of gallium have been counted and indicate that the flux is consistent with 0 SNU and is less than 72 SNU (68% CL) and less than 138 SNU (95% CL). This is to be compared with the flux of 132 SNU predicted by the Standard Solar Model. © 1991
The Baksan gallium solar neutrino experiment
A radiochemical 71Ga-71Ge experiment to determine the integral flux of neutrinos from the sun has been constructed at the Baksan Neutrino Observatory in the USSR. Measurements have begun with 30 tonnes of gallium. An additional 30 tonnes of gallium are being installed so as to perform the full experiment with a 60-tonne target. The motivation, experiment procedures, and present status of this experiment are described. © 1990
The usability of recycled carbon fibres in short fibre thermoplastics: interfacial properties
The objective of this study was to investigate the feasibility of combining discontinuous recycled carbon fibres with polypropylene, to produce a low-cost, high specific stiffness material for high-volume applications. The inherent low affinity of carbon fibre and polypropylene motivated a detailed study of the surface characteristics of carbon fibre and interfacial behaviour between the two materials, using the microbond test. The effects of removing the sizing from the fibres, as well as introducing a maleic anhydride-grafted polypropylene coupling agent, were extensively investigated. Polypropylene was found to degrade when prepared under atmospheric conditions; therefore, it was necessary to form droplets under nitrogen. Removal of the sizing from the fibre using pyrolysis and solvolysis techniques altered the surface morphology of the fibre and increased the interfacial shear strength (IFSS) by 4 and 33 %, respectively. A more significant improvement in the fibre–matrix adhesion was achieved by adding a maleic anhydride coupling agent at 2 wt%, which increased the IFSS by 320 %
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The Soviet-American gallium experiment at Baksan
A gallium solar neutrino detector is sensitive to the full range of the solar neutrino spectrum, including the low-energy neutrinos from the fundamental proton-proton fusion reaction. If neutrino oscillations in the solar interior are responsible for the suppressed {sup 8}B flux measured by the Homestake {sup 37}Cl experiment and the Kamiokande water Cherenkov detector, then a comparison of the gallium, chlorine, and water results may make possible a determination of the neutrino mass difference and mixing angle. A 30-ton gallium detector is currently operating in the Baksan laboratory in the Soviet Union, with a ratio of expected solar signal to measured background (during the first one to two {sup 71}Ge half lives) of approximately one. 28 refs
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