Surface-atmosphere exchange of ammonia over peatland using QCL-based eddy-covariance measurements and inferential modeling

Recent advances in laser spectrometry offer new opportunities to investigate ecosystem-atmosphere exchange of environmentally relevant trace gases. In this study, we demonstrate the applicability of a quantum cascade laser (QCL) absorption spectrometer to continuously measure ammonia concentrations at high time resolution and thus to quantify the net exchange between a seminatural peatland ecosystem and the atmosphere based on the eddy-covariance approach. Changing diurnal patterns of both ammonia concentration and fluxes were found during different periods of the campaign. We observed a clear tipping point in early spring with decreasing ammonia deposition velocities and increasingly bidirectional fluxes that occurred after the switch from dormant vegetation to CO2 uptake but was triggered by a significant weather change. While several biophysical parameters such as temperature, radiation, and surface wetness were identified to partially regulate ammonia exchange at the site, the seasonal concentration pattern was clearly dominated by agricultural practices in the surrounding area. Comparing the results of a compensation point model with our measurement-based flux estimates showed considerable differences in some periods of the campaign due to overestimation of non-stomatal resistances caused by low acid ratios. The total cumulative campaign exchange of ammonia after 9 weeks, however, differed only in a 6% deviation with 911 and 857 gNH(3)-N ha(-1) deposition being found by measurements and modeling, respectively. Extrapolating our findings to an entire year, ammonia deposition was lower than reported by Hurkuck et al. (2014) for the same site in previous years using denuder systems. This was likely due to a better representation of the emission component in the net signal of eddy-covariance fluxes as well as better adapted site-specific parameters in the model. Our study not only stresses the importance of high-quality measurements for studying and assessing land surface-atmosphere interactions but also demonstrates the potential of QCL spectrometers for continuous observation of reactive nitrogen species as important additional instruments within long-term monitoring research infrastructures such as ICOS or NEON at sites with strong nearby ammonia sources leading to relatively high mean background concentrations and fluxes.Peer reviewe

Место и роль ценностей в механизме социализации

В статье рассматривается специфика механизма социализации и проблема ценностных ориентаций в условиях социокультурных трансформаций украинского общества. Определяются ценностные ориентиры гражданского общества как приоритетного для Украины.У статті розглядається специфика механізму соціалізації і проблема цінностних орієнтацій в умовах соціокультурних трансформацій українського суспільства. Визначаються цінностні орієнтири громадянського суспільства як приоритетного для України.The article deals with peculiarities of socialization and the problem of value ori-entation under the conditions of socio-cultural transformations of the Ukrainian society. We also define value orientation of the civil society as optimal for Ukraine

Non-stomatal exchange in ammonia dry deposition models: comparison of two state-of-the-art approaches

The accurate representation of bidirectional ammonia (N