Nickel and Chromium Stable Isotopic Composition of Ureilites: Implications for the Earth's Core Formation and Differentiation of the Ureilite Parent Body

We report the first Ni and Cr stable isotope data for ureilite meteorites that are the mantle residue of a carbon-rich differentiated planet. Ureilites have similar Ni stable isotope compositions as chondrites, suggesting that the core-mantle differentiation of ureilite parent body (UPB) did not fractionate Ni isotopes. Since the size of Earth is potentially larger than that of UPB; with diameter >690 km), resulting in higher temperatures at the core-mantle boundary of Earth, it can be predicted that the terrestrial core formation may not directly cause Ni stable isotope fractionation. On the other hand, we also report high-precision Cr stable isotope composition of ureilites, including one ureilitic trachyandesite (ALM-A) that is enriched in lighter Cr stable isotopes relative to the main-group ureilites, which suggests that the partial melting occurred on UPB. The globally heavy Cr in the UPB compared to chondrites can be caused by sulfur-rich core formation processes

Multidisciplinary investigation on cold seeps with vigorous gas emissions in the Sea of Marmara (MarsiteCruise): Strategy for site detection and sampling and first scientific outcome

MarsiteCruise was undertaken in October/November 2014 in the Sea of Marmara to gain detailed insight into the fate of fluids migrating within the sedimentary column and partially released into the water column. The overall objective of the project was to achieve a more global understanding of cold-seep dynamics in the context of a major active strike-slip fault. Five remotely operated vehicle (ROV) dives were performed at selected areas along the North Anatolian Fault and inherited faults. To efficiently detect, select and sample the gas seeps, we applied an original procedure. It combines sequentially (1) the acquisition of ship-borne multibeam acoustic data from the water column prior to each dive to detect gas emission sites and to design the tracks of the ROV dives, (2) in situ and real-time Raman spectroscopy analysis of the gas stream, and (3) onboard determination of molecular and isotopic compositions of the collected gas bubbles. The in situ Raman spectroscopy was used as a decision-making tool to evaluate the need for continuing with the sampling of gases from the discovered seep, or to move to another one. Push cores were gathered to study buried carbonates and pore waters at the surficial sediment, while CTD-Rosette allowed collecting samples to measure dissolved-methane concentration within the water column followed by a comparison with measurements from samples collected with the submersible Nautile during the Marnaut cruise in 2007. Overall, the visited sites were characterized by a wide diversity of seeps. CO2- and oil-rich seeps were found at the westernmost part of the sea in the Tekirdag Basin, while amphipods, anemones and coral populated the sites visited at the easternmost part in the Cinarcik Basin. Methane-derived authigenic carbonates and bacterial mats were widespread on the seafloor at all sites with variable size and distributions. The measured methane concentrations in the water column were up to 377 μmol, and the dissolved pore-water profiles indicated the occurrence of sulfate depleting processes accompanied with carbonate precipitation. The pore-water profiles display evidence of biogeochemical transformations leading to the fast depletion of seawater sulfate within the first 25-cm depth of the sediment. These results show that the North Anatolian Fault and inherited faults are important migration paths for fluids for which a significant part is discharged into the water column, contributing to the increase of methane concentration at the bottom seawater and favoring the development of specific ecosystems

The distribution of (\u3csup\u3e234\u3c/sup\u3eU/\u3csup\u3e238\u3c/sup\u3eU) activity ratios in river sediments

© 2020 Elsevier Ltd Uranium (U) isotopes can be used to estimate the comminution age of sediments, i.e. the time elapsed from sediment production on continents, via weathering and physical erosion, to deposition in the sedimentary record. The calculation of this comminution age is based on measured (234U/238U) activity ratios in river sediments, and inferred time-dependent recoil effect, which leads to the preferential release of 234U from mineral lattices during erosion processes. In this study, we report on a large-scale (234U/238U) investigation of modern river sediments worldwide, with the aim to determine the extent to which parameters such as grain size, lithology, weathering, climate and geomorphology may influence the distribution of U isotopes in fine-grained sediments. Our extensive dataset (N = 64) includes U isotopic measurements for many of the world\u27s largest rivers, but also rivers draining particular climatic and geological settings. Our results indicate that sediments collected from river basins draining mostly igneous, metamorphic or volcanic rocks often display (234U/238U) ratios \u3e 1, with clay-size fractions (\u3c4 µm) being less depleted in 234U (higher 234U/238U) than corresponding silt-size fractions (4–63 µm). In contrast, sediments derived from multi-lithological basins or draining sedimentary rocks are typically characterized by (234U/238U) ratios \u3c1, with clays generally exhibiting more depleted 234U signatures than silts. Taken together, these observations suggest that the formation of secondary clay minerals in soils from basins draining mostly igneous, metamorphic is accompanied by partial incorporation by recoil injection of 234U initially released during weathering processes, possibly from U-rich minerals, such as sphene or apatite. Instead, in multi-lithological catchments draining sedimentary rocks, we propose that the erosion of recycled sediments having experienced several cycles of weathering, possibly over glacial-interglacial timescales, could explain the much lower (234U/238U) ratios observed in clay-size fractions. While no direct relationships can be identified between sediment (234U/238U) ratios and lithology, weathering intensity, climatic or geomorphic parameters in corresponding river basins, we show that the catchment size probably plays an important role in controlling the distribution of (234U/238U) in river sediments, through its direct influence on the sediment residence time. Finally, a multiple regression analysis of our data, combining various environmental parameters for the lithology, climate and geomorphology of studied river basins, indicates predicted (234U/238U) values that are very similar to measured values (with R2 ∼ 0.8). This finding provides further support for the usefulness of (234U/238U) ratios in the sedimentary record for reconstructing past landscape changes and their effect on sediment transport and residence time in river basins

The distribution of (234U/238U) activity ratios in river sediments

Uranium (U) isotopes can be used to estimate the comminution age of sediments, i.e. the time elapsed from sediment production on continents, via weathering and physical erosion, to deposition in the sedimentary record. The calculation of this comminution age is based on measured (234U/238U) activity ratios in river sediments, and inferred time-dependent recoil effect, which leads to the preferential release of 234U from mineral lattices during erosion processes. In this study, we report on a large-scale (234U/238U) investigation of modern river sediments worldwide, with the aim to determine the extent to which parameters such as grain size, lithology, weathering, climate and geomorphology may influence the distribution of U isotopes in fine-grained sediments. Our extensive dataset (N=64) includes U isotopic measurements for many of the world’s largest rivers, but also rivers draining particular climatic and geological settings. Our results indicate that sediments collected from river basins draining mostly igneous, metamorphic or volcanic rocks often display (234U/238U) ratios >1, with clay-size fractions (<4 µm) being less depleted in 234U (higher 234U/238U) than corresponding silt-size fractions (4-63 µm). In contrast, sediments derived from multi-lithological basins or draining sedimentary rocks are typically characterized by (234U/238U) ratios <1, with clays generally exhibiting more depleted 234U signatures than silts. Taken together, these observations suggest that the formation of secondary clay minerals in soils from basins draining mostly igneous, metamorphic is accompanied by partial incorporation by recoil injection of 234U initially released during weathering processes, possibly from U-rich minerals, such as sphene or apatite. Instead, in multi-lithological catchments draining sedimentary rocks, we propose that the erosion of recycled sediments having experienced several cycles of weathering, possibly over glacial-interglacial timescales, could explain the much lower (234U/238U) ratios observed in clay-size fractions. While no direct relationships can be identified between sediment (234U/238U) ratios and lithology, weathering intensity, climatic or geomorphic parameters in corresponding river basins, we show that the catchment size probably plays an important role in controlling the distribution of (234U/238U) in river sediments, through its direct influence on the sediment residence time. Finally, a multiple regression analysis of our data, combining various environmental parameters for the lithology, climate and geomorphology of studied river basins, indicates predicted (234U/238U) values that are very similar to measured values (with R2 ∼ 0.8). This finding provides further support for the usefulness of (234U/238U) ratios in the sedimentary record for reconstructing past landscape changes and their effect on sediment transport and residence time in river basins

Geochemical and iron isotopic insights into hydrothermal iron oxyhydroxide deposit formation at loihi seamount

Low-temperature hydrothermal vents, such as those encountered at Loihi Seamount, harbor abundant microbial communities and provide ideal systems to test hypotheses on biotic versus abiotic formation of hydrous ferric oxide (FeOx) deposits at the seafloor. Hydrothermal activity at Loihi Seamount produces abundant microbial mats associated with rust-colored FeOx deposits and variably encrusted with Mn-oxyhydroxides. Here, we applied Fe isotope systematics together with major and trace element geochemistry to study the formation mechanisms and preservation of such mineralized microbial mats. Iron isotope composition of warm (< 60 °C), Fe-rich and H2S-depleted hydrothermal fluids yielded δ56Fe values near +0.1 ‰, indistinguishable from basalt values. Suspended particles in the vent fluids and FeOx deposits recovered nearby active vents yielded systematically positive δ56Fe values. The enrichment in heavy Fe isotopes between +1.05 ‰ and +1.43 ‰ relative to Fe(II) in vent fluids suggest partial oxidation of Fe(II) during mixing of the hydrothermal fluid with seawater. By comparing the results with experimentally determined Fe isotope fractionation factors, we determined that less than 20% of Fe(II) is oxidized within active microbial mats, although this number may reach 80% in aged or less active deposits. These results are consistent with Fe(II) oxidation mediated by microbial processes considering the expected slow kinetics of abiotic Fe oxidation in low oxygen bottom water at Loihi Seamount. In contrast, FeOx deposits recovered at extinct sites have distinctly negative Fe-isotope values down to -1.77 ‰ together with significant enrichment in Mn and occurrence of negative Ce anomalies. These results are best explained by the near-complete oxidation of an isotopically light Fe(II) source produced during the waning stage of hydrothermal activity under more oxidizing conditions. Light Fe isotope values of FeOx are therefore generated by subsurface precipitation of isotopically heavy Fe-oxides rather than by the activity of dissimilatory Fe reduction in the subsurface. Overall, Fe-isotope compositions of microbial mats at Loihi Seamount display a remarkable range between -1.2 ‰ and +1.6 ‰ which indicate that Fe isotope compositions of hydrothermal Fe-oxide precipitates are particularly sensitive to local environmental conditions where they form, and are less sensitive to abiotic versus biotic origins. It follows that FeOx deposits at Loihi Seamount provides important modern analogues for ancient seafloor Fe-rich deposits allowing for testing hypotheses about the biogeochemical cycling of Fe isotopes on early Earth

A global survey of radiogenic strontium isotopes in river sediments

Radiogenic strontium isotopes are routinely used in provenance studies, but their application to sediments is often complicated by various grain size and weathering effects, which can influence measured 87Sr/86Sr ratios. Here, we report Sr isotopic data for a large number of sediment samples (n = 61) from the world's largest rivers and other river catchments draining particular geological and climatic settings; using both clay-rich (20 °C, intense feldspar weathering leads to the preferential incorporation of unradiogenic Sr into secondary clay minerals; a process which results in negative Δ87Sr/86Sr Clay-Silt values. In addition to climate forcing, the degree of size-dependent Sr isotope decoupling is also shown to be dependent on the type of weathering regime in watersheds, being more pronounced in low-elevation environments ( 4000 m) dominated by kinetically-limited weathering regimes. While further studies will be required to test the validity of these conclusions at the local scale of weathering profiles, these findings suggest that combined Sr isotopic analyses of separate size fractions could be used as a new weathering proxy in sediment records, ideally complementing the conventional use of radiogenic Sr isotopes as provenance tracers. Finally, our results are also used to re-assess the mean Sr flux and 87Sr/86Sr composition of the suspended sediment exported to the ocean yearly, yielding a global flux-weighted average of 0.7160, identical to that proposed earlier in the seminal study of Goldstein and Jacobsen (1988)

Trace elements in coralline algae as a new proxy for seawater chemistry and metal pollution

International audienceThe abundances of some macronutrients, and trace elements (K, Al, P, V, Mn, Co, Ni, Cu, Zn, Rb, Sr, Mo, Cs, Ba, Pb, Th, U, Y and REE) were determined in a series of coralline algae (Lithothamnion corallioides) samples (n = 101) collected alive in the Bay of Brest and the Iroise Sea (Western Brittany, NW France), in order to assess the potential of these algae as archives of seawater chemistry and potential metal pollution. REE and Y (REY) patterns are similar in shape to those of local seawater, exhibiting similar La, Ce and Y anomalies, but with abundances ranging between 4 and 5 orders of magnitude higher than seawater values. Variations in La anomalies (La/La* = 1.29-2.08), Y anomalies (Y/Ho = 38.6-55.8), and heavy rare earth enrichments (Prsn/Ersn = 0.22-0.52) are consistent with mixing of seawater with rivers flowing into the Bay of Brest. The behavior of other trace elements, such as Al and Cs, also reflects this mixing. Other parameters and processes can control the abundances of the other elements measured. For example, the presence of organic matter in studied samples controls the abundances of K and Rb. The abundances of base metals (e.g., Co, Ni, Cu) are highly sensitive to the various pollutants present in the Bay of Brest. In particular, the Pb content of coralline algae clearly reflects the pollution caused by mining of a nearby Pb deposit from the 18th to the early 20th century. Our results demonstrate the potential of coralline algae not only for tracing water masses, but also for studying metal pollution

Extensive wet episodes in Late Glacial Australia resulting from high-latitude forcings

Millennial-scale cooling events termed Heinrich Stadials punctuated Northern Hemisphere climate during the last glacial period. Latitudinal shifts of the intertropical convergence zone (ITCZ) are thought to have rapidly propagated these abrupt climatic signals southward, influencing the evolution of Southern Hemisphere climates and contributing to major reorganisation of the global ocean-atmosphere system. Here, we use neodymium isotopes from a marine sediment core to reconstruct the hydroclimatic evolution of subtropical Australia between 90 to 20 thousand years ago. We find a strong correlation between our sediment provenance proxy data and records for western Pacific tropical precipitations and Australian palaeolakes, which indicates that Northern Hemisphere cooling phases were accompanied by pronounced excursions of the ITCZ and associated rainfall as far south as about 32°S. Comparatively, however, each of these humid periods lasted substantially longer than the mean duration of Heinrich Stadials, overlapping with subsequent warming phases of the southern high-latitudes recorded in Antarctic ice cores. In addition to ITCZ-driven hydroclimate forcing, we infer that changes in Southern Ocean climate also played an important role in regulating late glacial atmospheric patterns of the Southern Hemisphere subtropical regions

Fungal population, including Ochratoxin A producing Aspergillus section Nigri strains from Ivory Coast coffee bean

The mycotoxin contamination in foods has become a growing threat and aroused many researches in science area. According to the food control authorities, Ochratoxin A (OTA) is among mycotoxins priority of food contaminants. The current work focuses on coffee cherries quality environment in Ivory Coast. The neglecting of good agricultural practices would lead to recurrent contamination of ivorian coffee in mycotoxinogen fungi and mycotoxin. We investigated and sampled during the post-harvest drying process of Robusta coffee bean, brought from Ivory Coast in 2008 and 2009. Morphological identification of total fungal flora and the determination of OTA producers of Aspergillus section Nigri have been performed. The reliability of the overall evaluated fungal contamination is estimated at 97%, being 7.03 in one coffee sample package of 300 g. Strains were isolated on potato dextrose agar (PDA) by the direct plating technique, and were grown at 25°C. Morphological study was performed using macroscopic and microscopic morphological characters. From the two hundred and eighteen strains of fungi isolated, the following were identified: Aspergillus section Nigri, Aspergillus section Fumigati, Penicillium, Mucor, Fusarium amongst others. Aspergillus section Nigri was found to be the most important group representing 52% of the population. Within this section OTA production was evaluated on czapeck yeast agar (CYA) and quantify by High-performance liquid chromatography (HPLC). Twenty percent of produced detectable OTA with concentrations ranging from 0.3 to 56 µg/g of agar medium. The objectives of this study is to define the risk contamination in post-harvest fungi on coffee