Analysis of CO₂ leakage through "low-permeability" faults from natural reservoirs in the Colorado Plateau, southern Utah

The numerous CO2 reservoirs in the Colorado Plateau region of the United States are natural analogues for potential geologic CO2 sequestration repositories. To better understand the risk of leakage from reservoirs used for long-term underground CO2 storage, we examine evidence for CO2 migration along two normal faults from a reservoir in east-central Utah. CO2 -charged springs, geysers, and a hydrocarbon seep are localised along these faults. These include natural springs that have been active for long periods of time, and springs that were induced by recent drilling. The CO2 -charged spring waters have deposited travertine mounds and carbonate veins. The faults cut siltstones, shales, and sandstones and the fault rocks are fine-grained, clay-rich gouge, generally thought to be barriers to fluid flow. The geologic and geochemical data are consistent with these faults being conduits for CO2 to the surface. Consequently, the injection of CO2 into faulted geologic reservoirs, including faults with clay gouge, must be carefully designed and monitored to avoid slow seepage or fast rupture to the biosphere

The structure and properties of horse muscle acylphosphatase in solution Mobility of antigenic and active site regions

AbstractThe solution structure of acylphosphatase determined by proton nuclear magnetic resonance spectroscopy is described. The results allow us to discuss the fold of the protein (101 amino acids), to correlate the exposure and the mobility of the backbone with the antigenicity, and to locate the active site

In-situ stress orientations in the UK Southern North Sea: regional trends, deviations and detachment of the post-Zechstein stress field

The orientation of the maximum horizontal compressive stress (SHmax) in the UK Southern North Sea has been determined using data derived from borehole breakout analysis of four-arm caliper logs. The results agree with existing stress models for NW Europe, confirming that horizontal stresses in the region have an approximately NW–SE orientation of SHmax. This is interpreted as being a result of plate boundary convergence. Local deviations in the SHmax orientations are observed spatially and also vertically within some wells. Some of these deviations are attributed to rotations of the stress field adjacent to faults or between different fault blocks. The data also suggest detachment of the stress regime in the post-Permian cover rocks, caused by the presence of a thick underlying Permian-aged evaporite sequence and associated halokinesis. Analyses of borehole resistivity image logs have been used to verify the SHmax orientations in some wells. These image logs validate some of the stress indicators whilst highlighting a number of deficiencies in the use of four-arm caliper data to characterise borehole breakouts. From the available data it is difficult to unambiguously define the nature of variations from the mean SHmax orientations observed. Further analyses of image log data over greater depth-ranges are therefore required in order to investigate more fully the effects of stress rotations near faults and apparent stress detachment above salt-cored anticlinal structures

The reaction of cytochrome c with [Fe(EDTA)(H2O)]−

AbstractThe interaction of horse ferricytochrome c with the reagents [Fe(EDTA)(H2O)]− and [Cr(CN)6]3− were studied at pH 7 and 25°C by 1H-NMR spectroscopy. Two binding regions near to the heme crevice of cytochrome c were identified. Both regions bound both reagents but they exhibited different selectivities.The relevance of this finding to the electron-transfer function of cytochrome c is discussed

The implementation and characterization of electron transfer dissociation (ETD) on an ion mobility enabled Q-TOF mass spectrometer

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SMA Observations on faint submillimeter galaxies with S 850 < 2 mJy: ultra dusty low-luminosity galaxies at high redshift

We obtained Submillimeter Array (SMA) observations of eight faint (intrinsic 850 μm fluxes < 2 mJy) submillimeter galaxies (SMGs) discovered in SCUBA images of the massive lensing cluster fields A370, A2390, and A1689 and detected five. In total, we obtain five SMA detections, all of which have de-lensed fluxes <1 mJy with estimated total infrared luminosities 1010-1012 L ☉, comparable to luminous infrared galaxies and normal star-forming galaxies. Based on the latest number counts, these galaxies contribute ~70% of the 850 μm extragalactic background light and represent the dominant star-forming galaxy population in the dusty universe. However, only 40$^{+30}_{-16}$% of our faint SMGs would be detected in deep optical or near-infrared surveys, which suggests many of these sources are at high redshifts (z gsim 3) or extremely dusty, and they are not included in current star formation history estimates

How to name atoms in phosphates, polyphosphates, their derivatives and mimics, and transition state analogues for enzyme-catalysed phosphoryl transfer reactions (IUPAC Recommendations 2016)

Procedures are proposed for the naming of individual atoms, P, O, F, N, and S in phosphate esters, amidates, thiophosphates, polyphosphates, their mimics, and analogues of transition states for enzyme-catalyzed phosphoryl transfer reactions. Their purpose is to enable scientists in very different fields, e.g. biochemistry, biophysics, chemistry, computational chemistry, crystallography, and molecular biology, to share standard protocols for the labelling of individual atoms in complex molecules. This will facilitate clear and unambiguous descriptions of structural results, as well as scientific intercommunication concerning them. At the present time, perusal of the Protein Data Bank (PDB) and other sources shows that there is a limited degree of commonality in nomenclature, but a large measure of irregularity in more complex structures. The recommendations described here adhere to established practice as closely as possible, in particular to IUPAC and IUBMB recommendations and to "best practice" in the PDB, especially to its atom labelling of amino acids, and particularly to Cahn-Ingold-Prelog rules for stereochemical nomenclature. They are designed to work in complex enzyme sites for binding phosphates but also to have utility for non-enzymatic systems. Above all, the recommendations are designed to be easy to comprehend and user-friendly