367 research outputs found
Reaction Networks For Interstellar Chemical Modelling: Improvements and Challenges
We survey the current situation regarding chemical modelling of the synthesis
of molecules in the interstellar medium. The present state of knowledge
concerning the rate coefficients and their uncertainties for the major
gas-phase processes -- ion-neutral reactions, neutral-neutral reactions,
radiative association, and dissociative recombination -- is reviewed. Emphasis
is placed on those reactions that have been identified, by sensitivity
analyses, as 'crucial' in determining the predicted abundances of the species
observed in the interstellar medium. These sensitivity analyses have been
carried out for gas-phase models of three representative, molecule-rich,
astronomical sources: the cold dense molecular clouds TMC-1 and L134N, and the
expanding circumstellar envelope IRC +10216. Our review has led to the proposal
of new values and uncertainties for the rate coefficients of many of the key
reactions. The impact of these new data on the predicted abundances in TMC-1
and L134N is reported. Interstellar dust particles also influence the observed
abundances of molecules in the interstellar medium. Their role is included in
gas-grain, as distinct from gas-phase only, models. We review the methods for
incorporating both accretion onto, and reactions on, the surfaces of grains in
such models, as well as describing some recent experimental efforts to simulate
and examine relevant processes in the laboratory. These efforts include
experiments on the surface-catalysed recombination of hydrogen atoms, on
chemical processing on and in the ices that are known to exist on the surface
of interstellar grains, and on desorption processes, which may enable species
formed on grains to return to the gas-phase.Comment: Accepted for publication in Space Science Review
Review of important reactions for the nitrogen chemistry in the interstellar medium
Predictions of astrochemical models depend strongly on the reaction rate
coefficients used in the simulations. We reviewed a number of key reactions for
the chemistry of nitrogen-bearing species in the dense interstellar medium and
proposed new reaction rate coefficients for those reactions. The details of the
reviews are given in the form of a datasheet associated with each reaction. The
new recommended rate coefficients are given with an uncertainty and a
temperature range of validity and will be included in KIDA
(http://kida.obs.u-bordeaux1.fr).Comment: 39 pages, not published in refereed journal, datasheets are given in
KID
Spins, Electromagnetic Moments, and Isomers of 107-129Cd
The neutron-rich isotopes of cadmium up to the N=82 shell closure have been
investigated by high-resolution laser spectroscopy. Deep-UV excitation at 214.5
nm and radioactive-beam bunching provided the required experimental
sensitivity. Long-lived isomers are observed in 127Cd and 129Cd for the first
time. One essential feature of the spherical shell model is unambiguously
confirmed by a linear increase of the 11/2- quadrupole moments. Remarkably,
this mechanism is found to act well beyond the h11/2 shell
A hierarchical model for aging
We present a one dimensional model for diffusion on a hierarchical tree
structure. It is shown that this model exhibits aging phenomena although no
disorder is present. The origin of aging in this model is therefore the
hierarchical structure of phase space.Comment: 10 pages LaTeX, 4 postscript-figures include
Magnetically-driven explosions of rapidly-rotating white dwarfs following Accretion-Induced Collapse
We present 2D multi-group flux-limited diffusion magnetohydrodynamics (MHD)
simulations of the Accretion-Induced Collapse (AIC) of a rapidly-rotating white
dwarf. We focus on the dynamical role of MHD processes after the formation of a
millisecond-period protoneutron star. We find that including magnetic fields
and stresses can lead to a powerful explosion with an energy of a few Bethe,
rather than a weak one of at most 0.1 Bethe, with an associated ejecta mass of
~0.1Msun, instead of a few 0.001Msun. The core is spun down by ~30% within
500ms after bounce, and the rotational energy extracted from the core is
channeled into magnetic energy that generates a strong magnetically-driven
wind, rather than a weak neutrino-driven wind. Baryon loading of the ejecta,
while this wind prevails, precludes it from becoming relativistic. This
suggests that a GRB is not expected to emerge from such AICs during the early
protoneutron star phase, except in the unlikely event that the massive white
dwarf has sufficient mass to lead to black hole formation. In addition, we
predict both negligible 56Ni-production (that should result in an
optically-dark, adiabatically-cooled explosion) and the ejection of 0.1Msun of
material with an electron fraction of 0.1-0.2. Such pollution by neutron-rich
nuclei puts strong constraints on the possible rate of such AICs. Moreover,
being free from ``fallback,'' such highly-magnetized millisecond-period
protoneutron stars may later become magnetars, and the magnetically-driven
winds may later transition to Poynting-flux-dominated, relativistic winds,
eventually detectable as GRBs at cosmological distances. However, the low
expected event rate of AICs will constrain them to be, at best, a small subset
of GRB and/or magnetar progenitors.Comment: 16 pages, 8 figures, paper accepted to ApJ; High resolution version
available at http://hermes.as.arizona.edu/~luc/aic_mhd/aic_mhd.htm
A spectral line survey of Orion KL in the bands 486-492 and 541-577 GHz with the Odin satellite I. The observational data
Spectral line surveys are useful since they allow identification of new
molecules and new lines in uniformly calibrated data sets. Nonetheless, large
portions of the sub-millimetre spectral regime remain unexplored due to severe
absorptions by H2O and O2 in the terrestrial atmosphere. The purpose of the
measurements presented here is to cover wavelength regions at and around 0.55
mm -- regions largely unobservable from the ground. Using the Odin
astronomy/aeronomy satellite, we performed the first spectral survey of the
Orion KL molecular cloud core in the bands 486--492 and 541--576 GHz with
rather uniform sensitivity (22--25 mK baseline noise). Odin's 1.1 m size
telescope, equipped with four cryo-cooled tuneable mixers connected to broad
band spectrometers, was used in a satellite position-switching mode. Two mixers
simultaneously observed different 1.1 GHz bands using frequency steps of 0.5
GHz (25 hours each). An on-source integration time of 20 hours was achieved for
most bands. The entire campaign consumed ~1100 orbits, each containing one hour
of serviceable astro-observation. We identified 280 spectral lines from 38
known interstellar molecules (including isotopologues) having intensities in
the range 80 to 0.05 K. An additional 64 weak lines remain unidentified. Apart
from the ground state rotational 1(1,0)--1(0,1) transitions of ortho-H2O, H218O
and H217O, the high energy 6(2,4)--7(1,7) line of para-H2O and the
HDO(2,0,2--1,1,1) line have been observed, as well as the 1,0--0,1 lines from
NH3 and its rare isotopologue 15NH3. We suggest assignments for some
unidentified features, notably the new interstellar molecules ND and SH-.
Severe blends have been detected in the line wings of the H218O, H217O and 13CO
lines changing the true linewidths of the outflow emission.Comment: 21 pages, 10 figures, 7 tables, accepeted for publication in
Astronomy and Astrophysics 30 August 200
THERMAL RADIATION FROM MAGNETIZED NEUTRON STARS: A look at the Surface of a Neutron Star.
Surface thermal emission has been detected by ROSAT from four nearby young
neutron stars. Assuming black body emission, the significant pulsations of the
observed light curves can be interpreted as due to large surface temperature
differences produced by the effect of the crustal magnetic field on the flow of
heat from the hot interior toward the cooler surface. However, the energy
dependence of the modulation observed in Geminga is incompatible with blackbody
emission: this effect will give us a strong constraint on models of the neutron
star surface.Comment: 10 pages. tar-compressed and uuencoded postcript file. talk given at
the `Jubilee Gamow Seminar', St. Petersburg, Sept. 1994
Counting individual 41Ca atoms with a magneto-optical trap
Atom Trap Trace Analysis (ATTA), a novel method based upon laser trapping and
cooling, is used to count individual atoms of 41Ca present in biomedical
samples with isotopic abundance levels between 10^-8 and 10^-10. ATTA is
calibrated against Resonance Ionization Mass Spectrometry, demonstrating a good
agreement between the two methods. The present ATTA system has a counting
efficiency of 2x10^-7. Within one hour of observation time, its 3-sigma
detection limit on the isotopic abundance of 41Ca reaches 4.5x10^-10
Seeking legitimacy through CSR: Institutional Pressures and Corporate Responses of Multinationals in Sri Lanka
Arguably, the corporate social responsibility (CSR) practices of multinational enterprises (MNEs) are influenced by a wide range of both internal and external factors. Perhaps most critical among the exogenous forces operating on MNEs are those exerted by state and other key institutional actors in host countries. Crucially, academic research conducted to date offers little data about how MNEs use their CSR activities to strategically manage their relationship with those actors in order to gain legitimisation advantages in host countries. This paper addresses that gap by exploring interactions between external institutional pressures and firm-level CSR activities, which take the form of community initiatives, to examine how MNEs develop their legitimacy-seeking policies and practices. In focusing on a developing country, Sri Lanka, this paper provides valuable insights into how MNEs instrumentally utilise community initiatives in a country where relationship-building with governmental and other powerful non-governmental actors can be vitally important for the long-term viability of the business. Drawing on neo-institutional theory and CSR literature, this paper examines and contributes to the embryonic but emerging debate about the instrumental and political implications of CSR. The evidence presented and discussed here reveals the extent to which, and the reasons why, MNEs engage in complex legitimacy-seeking relationships with Sri Lankan institutions
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