Trace elements: critical insights from 15 years of monitoring in the Venice Lagoon catchment basin (Italy)

The study focused on selected trace elements (As, Cd, Cr, Hg, Ni, Pb) monitored in surface waters of the Venice Lagoon catchment basin (North East Italy) over the period 2000-2015. The monitoring was undertaken to verify the achievement of the quality objectives set by the European and national legislations. The available results have been analyzed to evaluate the chemical status of water bodies. The limit of quantification (LOQ) of the applied analytic techniques appears critical for the adequate water monitoring; for some parameters, the percentage of not visible values due to non-satisfactory LOQ was higher in the beginning of the period; the subsequent improvement of LOQ allowed assessing the respect of environmental quality standards (EQSs). The study analyzes time trends in single stations and the differences between detected concentrations in the considered stations. Moreover, maximum concentrations and water flows have been considered to understand the potential correlation. Cumulated frequency curves for the most critical parameters have been built to identify situation of potential overtaking of the EQSs in force. The most polluted sampling stations of the drainage basin for the six trace elements were found in Cuori and Fiumazzo rivers. Although LOQs changed over time, the recorded trends show a quality improvement and a good compliance with respect to EQSs set by European legislation, while considering EQSs set by local special legislation, the objectives are not yet satisfied. Arsenic is ubiquitous; thus, it can be supposed to be originated as a background environmental concentration, while nickel appears of industrial origin according to its point and local presence

Pharmaceutical pollution of the world's rivers

Environmental exposure to active pharmaceutical ingredients (APIs) can have negative effects on the health of ecosystems and humans. While numerous studies have monitored APIs in rivers, these employ different analytical methods, measure different APIs, and have ignored many of the countries of the world. This makes it difficult to quantify the scale of the problem from a global perspective. Furthermore, comparison of the existing data, generated for different studies/regions/continents, is challenging due to the vast differences between the analytical methodologies employed. Here, we present a global-scale study of API pollution in 258 of the world's rivers, representing the environmental influence of 471.4 million people across 137 geographic regions. Samples were obtained from 1,052 locations in 104 countries (representing all continents and 36 countries not previously studied for API contamination) and analyzed for 61 APIs. Highest cumulative API concentrations were observed in sub-Saharan Africa, south Asia, and South America. The most contaminated sites were in low- to middle-income countries and were associated with areas with poor wastewater and waste management infrastructure and pharmaceutical manufacturing. The most frequently detected APIs were carbamazepine, metformin, and caffeine (a compound also arising from lifestyle use), which were detected at over half of the sites monitored. Concentrations of at least one API at 25.7% of the sampling sites were greater than concentrations considered safe for aquatic organisms, or which are of concern in terms of selection for antimicrobial resistance. Therefore, pharmaceutical pollution poses a global threat to environmental and human health, as well as to delivery of the United Nations Sustainable Development Goals

Water scarcity and contamination in eastern Ukraine

No abstract available

Monitoring of trace metals and pharmaceuticals as anthropogenic and socio-economic indicators of urban and industrial impact on surface waters

International audienc

Removal efficiency of pharmaceuticals in a full scale constructed wetland in East Ukraine

Pharmaceuticals in surface water are a threat to drinking water supplies. The removal of 12 pharmaceuticals was investigated in a full scale constructed wetland processing hospital wastewaters in East Ukraine. Passive integrative samplers POCIS were used to monitor target compounds in the wastewater inlet and outlet at the beginning of the constructed wetland operation in 2012 and three years later in 2015. Pharmaceuticals were effectively removed; however, their removal efficiency differed among the compounds and years of the operation. An increase of removal efficiency was observed for androstenedione, carbamazepine, caffeine, diclofenac, estrone, ibuprofen, paracetamol, propranolol and triclosan with greater water residence time and an increase in macrophyte cover. Removal patterns of pharmaceuticals were discussed based on specific physical chemical properties of molecules, changes in the operational conditions of the constructed wetland and inlet pollutant concentrations. Further research is needed to fully understand how the maturation of constructed wetlands influences the removal of emerging contaminants from wastewater

Quantification of water and sewage leakages from urban infrastructure into a shallow aquifer in East Ukraine

International audienceLeaky water supply and sewer mains can become unmanaged sources of urban groundwater recharge and contamination posing environmental and health risks. Stable isotopes of water and hydrochemical tracer were applied to quantify water and sewage leakages in a shallow aquifer of a large Ukrainian city. Binary and ternary mixing models were used based on the d-excess and chloride concentrations of tap water, rural and urban groundwater to estimate fractions of natural recharge, urban seepage, volumes of water supply and sewage leakages in urban springs. Water supply leakages that recharge aquifer were ~ 3% (6.5 Mm 3 a − 1) of the total water supply and strongly correlated with failures on the water infrastructure. Sewage leakages (1.4 Mm 3 a − 1) to the aquifer were less in amount than water supply leakages, but induced nitrate and associated contaminants pollution risk of urban groundwater. The proposed method is useful for the pilot evaluation of urban groundwater recharge and contamination and can be applied in other regions worldwide to support the decision-making in water management

Nutrient dynamics in temperate European catchments of different land use under changing climate

Study region: Vltava River basin, South Bohemian Region of the Czech Republic, Central Europe Study focus: To understand the dynamics of nutrients (nitrogen, phosphorus, and organic carbon) in streams, we combined hydrometeorological, hydrochemical and isotopic data (stable water and nitrate isotopes) from three catchments with different predominant land-use effects (forest, agricultural and settlement). New hydrological insights for the study region: Our study underlines that current climate change and associated hydrological changes, such as decrease in flow, play an important role in the transport and dynamics of nutrients in the catchment. We have found that due to the different origins and pathways, individual nutrients had diverse behaviour patterns in streams and responded differently to changing climate. Hydrological patterns in streams became clear when systematic and continuous monitoring under a changing climate was applied, highlighting the need for such data to better understand the impact of hydrological drivers, particularly for long-term dynamics. In three studied catchments, streamflow showed a decreasing trend in line with rising air temperature, declining snow cover and increasing evapotranspiration. Time series analyses of nitrate concentrations revealed decreasing trends, whereas dissolved organic carbon increased in all catchments regardless of land use. Long-term trends of total phosphorus concentrations were positive in anthropogenically impacted streams. Stable nitrate isotopes indicated distinct nitrate sources and processes, but also their seasonality in relation to hydrological patterns and land use

Groundwater dependent ecosystems in coastal Mediterranean regions: Characterization, challenges and management for their protection

International audienc

Constraining nitrate contamination in a shallow urban aquifer: integrating stable nitrate isotope measurements and land use analysis.

A combined hydrochemical and stable isotope approach was used to investigate the origin of nitrate in the shallow unconfined groundwater of Kharkiv city, Eastern Ukraine. The contamination was investigated in the context of land use within the catchment area. The observed enrichment of sulfate, chloride and nitrate suggests significant groundwater contamination in the shallow urban aquifer, which is widely used as drinking water source for the urban population. Characteristic nitrate/chloride ratios as well as stable isotope ratios (N and O) of nitrate in the most contaminated springs confirmed that septic waste from leaky sewer systems was the main source of nitrate contamination in the groundwater. Nitrate contamination is linked to the type of land use and sewage treatment regime in the catchment area. It is also modulated by the regional hydrogeology, which determines the susceptibility of a given aquifer toward groundwater pollution. A more quantitative assessment of nitrate sources based on the nitrate isotope analysis alone is rather difficult. However, our study confirms that the combination of hydrochemical tracers, robust land-use analysis and nitrate stable isotope measurements represents a valuable approach to identify the origin of the nitrate contamination