Towards a Greener and Scalable Synthesis of Na2_{2}Ti6_{6}O13_{13} Nanorods and Their Application as Anodes in Batteries for Grid-Level Energy Storage

Grid applications require high power density (for frequency regulation, load leveling, and renewable energy integration), achievable by combining multiple batteries in a system without strict high capacity requirements. For these applications however, safety, cost efficiency, and the lifespan of electrode materials are crucial. Titanates, safe and longevous anode materials providing much lower energy density than graphite, are excellent candidates for this application. The innovative molten salt synthesis approach proposed in this work provides exceptionally pure Na$_{2}$Ti$_{6}$O$_{13}$ nanorods generated at 900–1100 °C in a yield ≥80 wt%. It is fast, cost‐efficient, and suitable for industrial upscaling. Electrochemical tests reveal stable performance providing capacities of ≈100 mA h g$^{-1}$ (Li) and 40 mA h g$^{-1}$ (Na). Increasing the synthesis temperature to 1100 °C leads to a capacity decrease, most likely resulting from 1) the morphology/volume change with the synthesis temperature and 2) distortion of the Na$_{2}$Ti$_{6}$O$_{13}$ tunnel structure indicated by electron energy‐loss and Raman spectroscopy. The suitability of pristine Na$_{2}$Ti$_{6}$O$_{13}$ as the anode for grid‐level energy storage systems has been proven a priori, without any performance‐boosting treatment, indicating considerable application potential especially due to the high yield and low cost of the synthesis route

The clinical relevance of oliguria in the critically ill patient : Analysis of a large observational database

Funding Information: Marc Leone reports receiving consulting fees from Amomed and Aguettant; lecture fees from MSD, Pfizer, Octapharma, 3 M, Aspen, Orion; travel support from LFB; and grant support from PHRC IR and his institution. JLV is the Editor-in-Chief of Critical Care. The other authors declare that they have no relevant financial interests. Publisher Copyright: © 2020 The Author(s). Copyright: Copyright 2020 Elsevier B.V., All rights reserved.Background: Urine output is widely used as one of the criteria for the diagnosis and staging of acute renal failure, but few studies have specifically assessed the role of oliguria as a marker of acute renal failure or outcomes in general intensive care unit (ICU) patients. Using a large multinational database, we therefore evaluated the occurrence of oliguria (defined as a urine output 16 years) patients in the ICON audit who had a urine output measurement on the day of admission were included. To investigate the association between oliguria and mortality, we used a multilevel analysis. Results: Of the 8292 patients included, 2050 (24.7%) were oliguric during the first 24 h of admission. Patients with oliguria on admission who had at least one additional 24-h urine output recorded during their ICU stay (n = 1349) were divided into three groups: transient - oliguria resolved within 48 h after the admission day (n = 390 [28.9%]), prolonged - oliguria resolved > 48 h after the admission day (n = 141 [10.5%]), and permanent - oliguria persisting for the whole ICU stay or again present at the end of the ICU stay (n = 818 [60.6%]). ICU and hospital mortality rates were higher in patients with oliguria than in those without, except for patients with transient oliguria who had significantly lower mortality rates than non-oliguric patients. In multilevel analysis, the need for RRT was associated with a significantly higher risk of death (OR = 1.51 [95% CI 1.19-1.91], p = 0.001), but the presence of oliguria on admission was not (OR = 1.14 [95% CI 0.97-1.34], p = 0.103). Conclusions: Oliguria is common in ICU patients and may have a relatively benign nature if only transient. The duration of oliguria and need for RRT are associated with worse outcome.publishersversionPeer reviewe

Observation of positronium annihilation in the 2S state: towards a new measurement of the 1S-2S transition frequency

We report the first observation of the annihilation of positronium from the 2S state. Positronium (Ps) is excited with a two-photon transition from the 1S to the 2S state where its lifetime is increased by a factor of eight compared to the ground state due to the decrease in the overlap of the positron electron wavefunction. The yield of delayed annihilation photons detected as a function of laser frequency is used as a new method of detecting laser-excited Ps in the 2S state. This can be considered the first step towards a new high precision measurement of the 1S-2S Ps line.Comment: 6 pages, 3 Figures, proceedings EXA 2014, accepted for publication in Hyperfine Interaction

Observation of positronium annihilation in the 2S state: towards a new measurement of the 1S-2S transition frequency

We report the first observation of the annihilation of positronium from the 2S state. Positronium (Ps) is excited with a two-photon transition from the 1S to the 2S state where its lifetime is increased by a factor of eight compared to the ground state due to the decrease in the overlap of the positron electron wave-function. The yield of delayed annihilation photons detected as a function of laser frequency is used as a new method of detecting laser-excited Ps in the 2S state. This can be considered the first step towards a new high precision measurement of the 1S-2S Ps line

The forward muon detector of L3

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