X-ray and electron spin resonance on YBa2Cu3O7 prepared by citrate synthesis

YBa2Cu3O7 samples were prepared by a citrate synthesis technique. Powder X-ray diffraction and resistance measurements were performed for sample characterization. This single-phase material has a Tc(R=0) of 91.2 K. Electron spin resonance experiments indicate the presence of 10 to 15% of Cu3+

Model-based Geostatistical Interpolation of the annual number of ozone exceedance days in the Netherlands

This paper discusses two model-based geostatistical methods for spatial interpolation of the number of days that ground level ozone exceeds a threshold level. The first method assumes counts to approximately follow a Poisson distribution, while the second method assumes a log-Normal distribution. First, these methods were compared using an extensive data set covering the Netherlands, Belgium and Germany. Second, the focus was placed on only the Netherlands, where only a small data set was used. Bayesian techniques were used for parameter estimation and interpolation. Parameter estimates are comparable due to the log-link in both models. Incorporating data from adjacent countries improves parameter estimation. The Poisson model predicts more accurately (maximum kriging standard deviation of 2.16 compared to 2.69) but shows smoother surfaces than the log-Normal model. The log-Normal approach ensures a better representation of the observations and gives more realistic patterns (an RMSE of 2.26 compared to 2.44). Model-based geostatistical procedures are useful to interpolate limited data sets of counts of ozone exceedance days. Spatial risk estimates using existing prior information can be made relating health effects to environmental threshold

Quantifying contributions of chlorofluorocarbon banks to emissions and impacts on the ozone layer and climate

Chlorofluorocarbon (CFC) banks from uses such as air conditioners or foams can be emitted after global production stops. Recent reports of unexpected emissions of CFC-11 raise the need to better quantify releases from these banks, and associated impacts on ozone depletion and climate change. Here we develop a Bayesian probabilistic model for CFC-11, 12, and 113 banks and their emissions, incorporating the broadest range of constraints to date. We find that bank sizes of CFC-11 and CFC-12 are larger than recent international scientific assessments suggested, and can account for much of current estimated CFC-11 and 12 emissions (with the exception of increased CFC-11 emissions after 2012). Left unrecovered, these CFC banks could delay Antarctic ozone hole recovery by about six years and contribute 9 billion metric tonnes of equivalent CO2 emission. Derived CFC-113 emissions are subject to uncertainty, but are much larger than expected, raising questions about its sources

Report on unexpected emissions of CFC-11

peer reviewedEXECUTIVE SUMMARY Global CFC-11 emissions were expected to decrease steadily after 2010 because of the full phaseout of production and consumption. Surprisingly, however, CFC-11 emissions began to increase in 2013 and were high from 2014 to 2018. After the publication of this emission increase in 2018, emissions were substantially lower in 2019. A large fraction of the emission increase was attributed to Eastern China based on regional emission estimates. These regional emissions also declined substantially from 2017 to 2019. The increase in global CFC-11 emissions was not a result of increased bank releases. The amounts of CFC-11 in banks and the release rates from the banks remain highly uncertain. The increases in emissions observed to date are small enough not to have a major impact on CFC-11 atmospheric abundances, so they will not have a major impact on the expected stratospheric ozone recovery. However, the increases in banks and how they might augment future emissions have large uncertainties

Deriving Global OH Abundance and Atmospheric Lifetimes for Long-Lived Gases: A Search for CH 3 CCl 3 Alternatives

An accurate estimate of global hydroxyl radical (OH) abundance is important for projections of air quality, climate, and stratospheric ozone recovery. As the atmospheric mixing ratios of methyl chloroform (CH₃CCl₃) (MCF), the commonly used OH reference gas, approaches zero, it is important to find alternative approaches to infer atmospheric OH abundance and variability. The lack of global bottom‐up emission inventories is the primary obstacle in choosing a MCF alternative. We illustrate that global emissions of long‐lived trace gases can be inferred from their observed mixing ratio differences between the Northern Hemisphere (NH) and Southern Hemisphere (SH), given realistic estimates of their NH‐SH exchange time, the emission partitioning between the two hemispheres, and the NH versus SH OH abundance ratio. Using the observed long‐term trend and emissions derived from the measured hemispheric gradient, the combination of HFC‐32 (CH₂F₂), HFC‐134a (CH₂FCF₃, HFC‐152a (CH₃CHF₂), and HCFC‐22 (CHClF₂), instead of a single gas, will be useful as a MCF alternative to infer global and hemispheric OH abundance and trace gas lifetimes. The primary assumption on which this multispecies approach relies is that the OH lifetimes can be estimated by scaling the thermal reaction rates of a reference gas at 272 K on global and hemispheric scales. Thus, the derived hemispheric and global OH estimates are forced to reconcile the observed trends and gradient for all four compounds simultaneously. However, currently, observations of these gases from the surface networks do not provide more accurate OH abundance estimate than that from MCF

The shared socio-economic pathway (SSP) greenhouse gas concentrations and their extensions to 2500

Anthropogenic increases in atmospheric greenhouse gas concentrations are the main driver of current and future climate change. The integrated assessment community has quantified anthropogenic emissions for the shared socio-economic pathway (SSP) scenarios, each of which represents a different future socio-economic projection and political environment. Here, we provide the greenhouse gas concentrations for these SSP scenarios – using the reduced-complexity climate–carbon-cycle model MAGICC7.0. We extend historical, observationally based concentration data with SSP concentration projections from 2015 to 2500 for 43 greenhouse gases with monthly and latitudinal resolution. CO2 concentrations by 2100 range from 393 to 1135 ppm for the lowest (SSP1-1.9) and highest (SSP5-8.5) emission scenarios, respectively. We also provide the concentration extensions beyond 2100 based on assumptions regarding the trajectories of fossil fuels and land use change emissions, net negative emissions, and the fraction of non-CO2 emissions. By 2150, CO2 concentrations in the lowest emission scenario are approximately 350 ppm and approximately plateau at that level until 2500, whereas the highest fossil-fuel-driven scenario projects CO2 concentrations of 1737 ppm and reaches concentrations beyond 2000 ppm by 2250. We estimate that the share of CO2 in the total radiative forcing contribution of all considered 43 long-lived greenhouse gases increases from 66 % for the present day to roughly 68 % to 85 % by the time of maximum forcing in the 21st century. For this estimation, we updated simple radiative forcing parameterizations that reflect the Oslo Line-By-Line model results. In comparison to the representative concentration pathways (RCPs), the five main SSPs (SSP1-1.9, SSP1-2.6, SSP2-4.5, SSP3-7.0, and SSP5-8.5) are more evenly spaced and extend to lower 2100 radiative forcing and temperatures. Performing two pairs of six-member historical ensembles with CESM1.2.2, we estimate the effect on surface air temperatures of applying latitudinally and seasonally resolved GHG concentrations. We find that the ensemble differences in the March–April–May (MAM) season provide a regional warming in higher northern latitudes of up to 0.4 K over the historical period, latitudinally averaged of about 0.1 K, which we estimate to be comparable to the upper bound (∼5 % level) of natural variability. In comparison to the comparatively straight line of the last 2000 years, the greenhouse gas concentrations since the onset of the industrial period and this studies' projections over the next 100 to 500 years unequivocally depict a “hockey-stick” upwards shape. The SSP concentration time series derived in this study provide a harmonized set of input assumptions for long-term climate science analysis; they also provide an indication of the wide set of futures that societal developments and policy implementations can lead to – ranging from multiple degrees of future warming on the one side to approximately 1.5 ∘C warming on the other

A perspective on the next generation of Earth system model scenarios: towards representative emission pathways (REPs)

In every IPCC Assessment cycle, a multitude of scenarios are assessed, with different scope and emphasis throughout the various Working Group and Special Reports and their respective chapters. Within the reports, the ambition is to integrate knowledge on possible climate futures across the Working Groups and scientific research domains based on a small set of ‘framing pathways’, such as the so-called RCP pathways from the Fifth IPCC Assessment report (AR5) and the SSP-RCP scenarios in the Sixth Assessment Report (AR6). This perspective, initiated by discussions at the IPCC Bangkok workshop in April 2023 on the “Use of Scenarios in AR6 and Subsequent Assessments”, is intended to serve as one of the community contributions to highlight needs for the next generation of framing pathways that is being advanced under the CMIP umbrella for use in the IPCC AR7. Here we suggest a number of policy research objectives that such a set of framing pathways should ideally fulfil, including mitigation needs for meeting the Paris Agreement objectives, the risks associated with carbon removal strategies, the consequences of delay in enacting that mitigation, guidance for adaptation needs, loss and damage, and for achieving mitigation in the wider context of Societal Development goals. Based on this context we suggest that the next generation of climate scenarios for Earth System Models should evolve towards ‘Representative Emission Pathways’ (REPs) and suggest key categories for such pathways. These ‘framing pathways’ should address the most critical mitigation policy and adaptation needs over the next 5–10 years. In our view the most important categories are those relevant in the context of the Paris Agreement long-term goal, specifically an immediate action (low overshoot) 1.5 °C pathway, and a delayed action (high overshoot) 1.5 °C pathway. Two other key categories are a pathway category approximately in line with current (as expressed by 2023) near- and long-term policy objectives, and a higher emissions category that is approximately in line with “current policies” (as expressed by 2023). We also argue for the scientific and policy relevance in exploring two ‘worlds that could have been’. One of these categories has high emission trajectories well above what is implied by current policies, and the other has very low emission trajectories that assume that global mitigation action in line with limiting warming to 1.5 °C without overshoot had begun in 2015. Finally, we note that timely provision of new scientific information on pathways is critical to inform the development and implementation of climate policy. For the second Global Stocktake under the Paris Agreement in 2028, and to inform subsequent development of Nationally Determined Contributions (NDCs) up to 2040, scientific inputs are required well before 2028. These needs should be carefully considered in the development timeline of community modelling activities including those under CMIP7