48 research outputs found
Gas phase formation of the prebiotic molecule formamide: insights from new quantum computations
New insights into the formation of interstellar formamide, a species of great
relevance in prebiotic chemistry, are provided by electronic structure and
kinetic calculations for the reaction NH2 + H2CO -> NH2CHO + H. Contrarily to
what previously suggested, this reaction is essentially barrierless and can,
therefore, occur under the low temperature conditions of interstellar objects
thus providing a facile formation route of formamide. The rate coefficient
parameters for the reaction channel leading to NH2CHO + H have been calculated
to be A = 2.6x10^{-12} cm^3 s^{-1}, beta = -2.1 and gamma = 26.9 K in the range
of temperatures 10-300 K. Including these new kinetic data in a refined
astrochemical model, we show that the proposed mechanism can well reproduce the
abundances of formamide observed in two very different interstellar objects:
the cold envelope of the Sun-like protostar IRAS16293-2422 and the molecular
shock L1157-B2. Therefore, the major conclusion of this Letter is that there is
no need to invoke grain-surface chemistry to explain the presence of formamide
provided that its precursors, NH2 and H2CO, are available in the gas-phase.Comment: MNRAS Letters, in pres
The census of interstellar complex organic molecules in the Class I hot corino of SVS13-A
We present the first census of the interstellar Complex Organic Molecules
(iCOMs) in the low-mass Class I protostar SVS13-A, obtained by analysing data
from the IRAM-30m Large Project ASAI (Astrochemical Surveys At IRAM). They
consist of an high-sensitivity unbiased spectral survey at the 1mm, 2mm and 3mm
IRAM bands. We detected five iCOMs: acetaldehyde (CHCHO), methyl formate
(HCOOCH), dimethyl ether (CHOCH), ethanol (CHCHOH) and
formamide (NHCHO). In addition we searched for other iCOMs and ketene
(HCCO), formic acid (HCOOH) and methoxy (CHO), whose only ketene was
detected. The numerous detected lines, from 5 to 37 depending on the species,
cover a large upper level energy range, between 15 and 254 K. This allowed us
to carry out a rotational diagram analysis and derive rotational temperatures
between 35 and 110 K, and column densities between and
cm on the 0."3 size previously determined by
interferometric observations of glycolaldehyde. These new observations clearly
demonstrate the presence of a rich chemistry in the hot corino towards SVS13-A.
The measured iCOMs abundances were compared to other Class 0 and I hot corinos,
as well as comets, previously published in the literature. We find evidence
that (i) SVS13-A is as chemically rich as younger Class 0 protostars, and (ii)
the iCOMs relative abundances do not substantially evolve during the
protostellar phase.Comment: 24 pages, MNRAS in pres
Seeds of Life in Space (SOLIS) VI. Chemical evolution of sulfuretted species along the outflows driven by the low-mass protostellar binary NGC1333-IRAS4A
Context: Low-mass protostars drive powerful molecular outflows that can be observed with millimetre and submillimetre telescopes.
Various sulfuretted species are known to be bright in shocks and could be used to infer the physical and chemical conditions throughout
the observed outflows.
Aims: The evolution of sulfur chemistry is studied along the outflows driven by the NGC 1333-IRAS4A protobinary system located
in the Perseus cloud to constrain the physical and chemical processes at work in shocks.
Methods: We observed various transitions from OCS, CS, SO, and SO2 towards NGC 1333-IRAS4A in the 1.3, 2, and 3 mm bands
using the IRAM NOrthern Extended Millimeter Array and we interpreted the observations through the use of the Paris-Durham shock
model.
Results: The targeted species clearly show different spatial emission along the two outflows driven by IRAS4A. OCS is brighter
on small and large scales along the south outflow driven by IRAS4A1, whereas SO2 is detected rather along the outflow driven by
IRAS4A2 that is extended along the north east–south west direction. SO is detected at extremely high radial velocity up to +25 km s−1
relative to the source velocity, clearly allowing us to distinguish the two outflows on small scales. Column density ratio maps estimated
from a rotational diagram analysis allowed us to confirm a clear gradient of the OCS/SO2 column density ratio between the IRAS4A1
and IRAS4A2 outflows. Analysis assuming non Local Thermodynamic Equilibrium of four SO2 transitions towards several SiO emission peaks suggests that the observed gas should be associated with densities higher than 105
cm−3
and relatively warm (T > 100 K)
temperatures in most cases.
Conclusions: The observed chemical differentiation between the two outflows of the IRAS4A system could be explained by a different chemical history. The outflow driven by IRAS4A1 is likely younger and more enriched in species initially formed in interstellar
ices, such as OCS, and recently sputtered into the shock gas. In contrast, the longer and likely older outflow triggered by IRAS4A2 is
more enriched in species that have a gas phase origin, such as SO2
Seeds of Life in Space (SOLIS): VI. Chemical evolution of sulfuretted species along the outflows driven by the low-mass protostellar binary NGC 1333-IRAS4A
Context. Low-mass protostars drive powerful molecular outflows that can be observed with millimetre and submillimetre telescopes. Various sulfuretted species are known to be bright in shocks and could be used to infer the physical and chemical conditions throughout the observed outflows. Aims. The evolution of sulfur chemistry is studied along the outflows driven by the NGC 1333-IRAS4A protobinary system located in the Perseus cloud to constrain the physical and chemical processes at work in shocks. Methods. We observed various transitions from OCS, CS, SO, and SO2 towards NGC 1333-IRAS4A in the 1.3, 2, and 3 mm bands using the IRAM NOrthern Extended Millimeter Array and we interpreted the observations through the use of the Paris-Durham shock model. Results. The targeted species clearly show different spatial emission along the two outflows driven by IRAS4A. OCS is brighter on small and large scales along the south outflow driven by IRAS4A1, whereas SO2 is detected rather along the outflow driven by IRAS4A2 that is extended along the north east-south west direction. SO is detected at extremely high radial velocity up to + 25 km s-1 relative to the source velocity, clearly allowing us to distinguish the two outflows on small scales. Column density ratio maps estimated from a rotational diagram analysis allowed us to confirm a clear gradient of the OCS/SO2 column density ratio between the IRAS4A1 and IRAS4A2 outflows. Analysis assuming non Local Thermodynamic Equilibrium of four SO2 transitions towards several SiO emission peaks suggests that the observed gas should be associated with densities higher than 105 cm-3 and relatively warm (T > 100 K) temperatures in most cases. Conclusions. The observed chemical differentiation between the two outflows of the IRAS4A system could be explained by a different chemical history. The outflow driven by IRAS4A1 is likely younger and more enriched in species initially formed in interstellar ices, such as OCS, and recently sputtered into the shock gas. In contrast, the longer and likely older outflow triggered by IRAS4A2 is more enriched in species that have a gas phase origin, such as SO2. © ESO 2020.V.T. is grateful to Sylvie Cabrit and Guillaume Pineau des Forêts for stimulating discussions on the chemistry in shocks. The authors acknowledge the CALYPSO consortium for the use of the CALYPSO dataset. This work is based on observations carried out with the IRAM PdBI/NOEMA Interferometer under project numbers V05B and V010 (PI: M.V. Persson), U003 (PI: V. Taquet), and L15AA (PI: C. Ceccarelli and P. Caselli). IRAM is supported by INSU/CNRS (France), MPG (Germany) and IGN (Spain). V.T. acknowledges the financial support from the European Union’s Horizon 2020 research and innovation programme under the Marie Sklodowska-Curie grant agreement n. 664931. This work was supported by (i) the PRIN-INAF 2016 “The Cradle of Life – GENESIS-SKA (General Conditions in Early Planetary Systems for the rise of life with SKA)”, (ii) the European Research Council (ERC) under the European Union’s Horizon 2020 research and innovation programme, for the Project “The Dawn of Organic Chemistry” (DOC), grant agreement No 741002, and (iii) the European MARIE SKŁODOWSKA-CURIE ACTIONS under the European Union’s Horizon 2020 research and innovation programme, for the Project “Astro-Chemistry Origins” (ACO), Grant No 811312. C.F. acknowledges support from the French National Research Agency in the framework of the Investissements d’Avenir program (ANR-15-IDEX-02), through the funding of the “Origin of Life” project of the Université Grenoble-Alpes
VizieR Online Data Catalog: SOLIS. II. L1157-B1 NH2CHO image (Codella+, 2017)
Datacube in fits format of the NH2CHO(41,4-31,3) towards L1157-B1 using the IRAM-NOEMA interferometer (see Fig. 1). The L1157-B1 shock was observed at 3mm with the IRAM NOEMA seven-element array during several tracks in July, October, and November 2015 using both the C and D configurations. The shortest and longest baselines are 19m and 237m, respectively, allowing us to recover emission at scales up to ~17". (2 data files)