Suitability of Blends from Virgin and Reprocessed Polylactide: Performance and Energy Valorization Kinetics

A blending strategy of virgin and reprocessed polylactide may be postulated as an alternative to reduce the material cost at industrial level, and as a valorization route to plastic waste management of production scraps. The performance of blends prepared from virgin polylactide and polylactide mechanically reprocessed up to two cycles (PLA-V/R) was assessed in terms of thermo-oxidative stability, morphology, viscoelasticity and thermal kinetics for energetic valorization. PLA-V/R blends showed appropriate thermo-oxidative stability. The amorphous nature of polylactide was preserved after blending. The viscoelastic properties showed an increment of the mechanical blend effectiveness, which suggested the feasibility of using PLA-V/R blends under similar mechanical conditions to those of virgin PLA goods. Finally, it was shown that the energetic valorization of PLA-V/R blends would result in a more feasible process, due to the lower required activation energy, thus highlighting the advantages of the energetic demand for the process. In conclusion, PLA-V/R blends showed similar processability, service performance and valorization routes as virgin PLA and therefore could be relevant in the sustainable circular industry of bioplastics

Long-term properties and end-of-life of polymers from renewable resources

The long-term properties and end-of-life of polymers are not antagonist issues. They actually are inherently linked by the duality between durability and degradation. The control of the service-todisposal pathway at useful performance, along with low-impact disposal represents an added-value. Therefore, the routes of design, production, and discarding of bio-based polymers must be carefully strategized. In this sense, the combination of proper valorisation techniques, i.e. material, energetic and/ or biological at the most appropriate stage should be targeted. Thus, the consideration of the end-of-life of a material for a specific application, instead of the end-of-life of a material should be the fundamental focus. This review covers the key aspects of lab-scale techniques to infer the potential of performance and valorisation of polymers from renewable resources as a key gear for sustainability

Robust h-adaptive meshing strategy considering exact arbitrary CAD geometries in a Cartesian grid framework

[EN] Geometry plays a key role in contact and shape optimization problems in which the accurate representation of the exact geometry and the use of adaptive analysis techniques are crucial to obtaining accurate computationally-efficient Finite Element (FE) simulations. We propose a novel algorithm to generate 3D h-adaptive meshes for an Immersed Boundary Method (IBM) based on Cartesian grids and the so-called NEFEM (NURBS-Enhanced FE Method) integration techniques. To increase the accuracy of the results at the minimum computational cost we seek to keep the efficient Cartesian structure of the mesh during the whole analysis process while considering the exact boundary representation of domains given by NURBS or T-Splines. Within the framework of Cartesian grids, the two significant contributions of this paper are: (a) the methodology used for the mesh-geometry intersection, which represents a considerable challenge due to their independence; and (b) the robust procedure used to generate the integration subdomains that exactly represent the CAD model. The numerical examples given show the proper convergence of the method, its capacity to mesh complex 3D geometries and that Cartesian grid-based IBM can be considered a robust and reliable tool in terms of accuracy and computational cost.The authors wish to thank the Spanish Ministerio de Economia y Competitividad for the financial support received through Project DPI2013-46317-R and the FPI program (BES-2011-044080), also the Generalitat Valenciana for the assistance received through Project PROMETEO/2016/007.Marco, O.; Ródenas, J.; Navarro-Jiménez, J.; Tur Valiente, M. (2017). Robust h-adaptive meshing strategy considering exact arbitrary CAD geometries in a Cartesian grid framework. Computers & Structures. 193:87-109. doi:10.1016/j.compstruc.2017.08.004S8710919

Dermanyssus gallinae in layer farms in Kosovo: a high risk for salmonella prevalence

Background The poultry red mite (PRM), Dermanyssus gallinae (D.g.) is a serious ectoparasitic pest of poultry and potential pathogen vector. The prevalence of D. g. and the prevalence of Salmonella spp. within mites on infested laying poultry farms were investigated in Kosovo. Findings In total, 14 populated layer farms located in the Southern Kosovo were assessed for D. g. presence. Another two farms in this region were investigated 6 months after depopulation. Investigated flocks were all maintained in cages, a common housing system in Kosovo. A total of eight farms were found to be infested with D. g. (50%) at varying levels, including the two depopulated farms. The detection of Salmonella spp. from D. g. was carried out using PCR. Out of the eight layer farms infested with D. g., Salmonella spp. was present in mites on three farms (37.5%). Conclusions This study confirms the high prevalence of D. g. in layer flocks in Kosovo and demonstrates the link between this mite and the presence of Salmonella spp. on infested farms

Information-based view initialization in visual SLAM with a single omnidirectional camera

© 2015 Elsevier B.V. All rights reserved. This paper presents a novel mechanism to initiate new views within the map building process for an EKF-based visual SLAM (Simultaneous Localization and Mapping) approach using omnidirectional images. In presence of non-linearities, the EKF is very likely to compromise the final estimation. Particularly, the omnidirectional observation model induces non-linear errors, thus it becomes a potential source of uncertainty. To deal with this issue we propose a novel mechanism for view initialization which accounts for information gain and losses more efficiently. The main outcome of this contribution is the reduction of the map uncertainty and thus the higher consistency of the final estimation. Its basis relies on a Gaussian Process to infer an information distribution model from sensor data. This model represents feature points existence probabilities and their information content analysis leads to the proposed view initialization scheme. To demonstrate the suitability and effectiveness of the approach we present a series of real data experiments conducted with a robot equipped with a camera sensor and map model solely based on omnidirectional views. The results reveal a beneficial reduction on the uncertainty but also on the error in the pose and the map estimate

Performance of polyester-based electrospun scaffolds under in vitro hydrolytic conditions: From short-term to long-term applications

The evaluation of the performance of polyesters under in vitro physiologic conditions is essential to design scaffolds with an adequate lifespan for a given application. In this line, the degradation-durability patterns of poly(lactide-co-glycolide) (PLGA), polydioxanone (PDO), polycaprolactone (PCL) and polyhydroxybutyrate (PHB) scaffolds were monitored and compared giving, as a result, a basis for the specific design of scaffolds from short-term to long-term applications. For this purpose, they were immersed in ultra-pure water and phosphate buffer solution (PBS) at 37 °C. The scaffolds for short-time applications were PLGA and PDO, in which the molar mass diminished down to 20% in a 20-30 days lifespan. While PDO developed crystallinity that prevented the geometry of the fibres, those of PLGA coalesced and collapsed. The scaffolds for long-term applications were PCL and PHB, in which the molar mass followed a progressive decrease, reaching values of 10% for PCL and almost 50% for PHB after 650 days of immersion. This resistant pattern was mainly ascribed to the stability of the crystalline domains of the fibres, in which the diameters remained almost unaffected. From the perspective of an adequate balance between the durability and degradation, this study may serve technologists as a reference point to design polyester-based scaffolds for biomedical applications

Efecto de la suplementación sobre el peso del ternero y la preñez y condición corporal de vacas del Bajo Chaco Paraguayo

The objective of the study was to evaluate the effect of concentrate supplementation of suckling calves on their weight gain, as well as the pregnancy percentage and body condition of the cows, which was carried out in an establishment located in the Department of Presidente Hayes, Lower Paraguayan Chaco. Thirty unweaned calves from multiparous cows between 2 and 3 months of age, were used. They were grouped into two treatments (T) of 15 calves and 15 cows for each treatment (T1: calves not supplemented and T2: calves supplemented), which grazed on a native pasture during the assay. The supplement consisted of a concentrate with 20% crude protein and 3 Mcal/kg of metabolizable energy, which was offered for 120 days. On each T, a Brangus bull was assigned to service the cows for 70 days. The average daily weight gain of the calves was 0.464 and 0.708 kg for T1 and T2, respectively, the difference being statistically significant (p<0.05). On the other hand, the pregnancy percentage was identical in both groups (7%). However, the number of cows with the highest final body condition (FBC3) increased in T2. It can be concluded that the most important effect was the improvement in the daily weight gain of the calves that received the supplementation and the increase in the number of cows with FBC3.El objetivo del estudio fue evaluar el efecto de la suplementación de terneros lactantes sobre su ganancia de peso, así como el porcentaje de preñez y condición corporal de las vacas. La investigación fue realizada en un establecimiento ubicado en el Departamento Presidente Hayes, en el Bajo Chaco Paraguayo. Se utilizaron treinta terneros de 2 a 3 meses de edad, crías de vacas adultas multíparas, que se agruparon en dos tratamientos (T) de 15 terneros y 15 vacas por cada uno (T1: terneros no suplementados y T2: terneros suplementados, ambos pastando sobre una pradera nativa en forma continua). El suplemento utilizado fue un concentrado con 20% de proteína bruta y 3 Mcal/kg de energía metabolizable, que se ofertó durante 120 días. En cada T se asignó un toro tipo Brangus para el servicio de las vacas, por 70 días. La ganancia diaria promedio de peso de los terneros fue de 0,464 y 0,708 kg para T1 y T2 respectivamente, siendo la diferencia estadísticamente significativa (p<0,05); no así el porcentaje de preñez, que fue idéntico en ambos grupos (7%). Sin embargo, en T2 aumentó la cantidad de vacas con la condición corporal final más alta (CCF3), diferencia que fue estadísticamente significativa (p<0,05). Se concluye que los efectos más importantes fueron la mejoría en la ganancia diaria de peso de los terneros que recibieron la suplementación y el aumento de la cantidad de vacas con CCF3

Effect of the dissolution time into an acid hydrolytic solvent to taylor electrospun nanofibrous polycaprolactone scaffolds

The hydrolysis of the polycaprolactone (PCL) as a function of the dissolution time in a formic/ acetic acid mixture was considered as a method for tailoring the morphology of nanofibrous PCL scaffolds. Hence, the aim of this research was to establish a correlation between the dissolution time of the polymer in the acid solvent with the physicochemical properties of the electrospun nanofibrous scaffolds and their further service life behaviour. The physico-chemical properties of the scaffolds were assessed in terms of fibre morphology, molar mass and thermal behaviour. A reduction of the molar mass and the lamellar thickness as well as an increase of the crystallinity degree were observed as a function of dissolution time. Bead-free fibres were found after 24 and 48 h of dissolution time, with similar diameter distributions. The decrease of the fibre diameter distributions along with the apparition of beads was especially significant for scaffolds prepared after 72 h and 120 h of dissolution time in the acid mixture. The service life of the obtained devices was evaluated by means of in vitro validation under abiotic physiological conditions. All the scaffolds maintained the nanofibrous structure after 100 days of immersion in water and PBS. The molar mass was barely affected and the crystallinity degree and the lamellar thickness increased along immersion, preventing scaffolds from degradation. Scaffolds prepared after 24 h and 48 h kept their fibre diameters, whereas those prepared after 72 h and 120 h showed a significant reduction. This PCL tailoring procedure to obtain scaffolds that maintain the nanoscaled structure after such long in vitro evaluation will bring new opportunities in the design of longterm biomedical patches

Neuregulin 3 Mediates Cortical Plate Invasion and Laminar Allocation of GABAergic Interneurons

Neural circuits in the cerebral cortex consist of excitatory pyramidal cells and inhibitory interneurons. These two main classes of cortical neurons follow largely different genetic programs, yet they assemble into highly specialized circuits during development following a very precise choreography. Previous studies have shown that signals produced by pyramidal cells influence the migration of cortical interneurons, but the molecular nature of these factors has remained elusive. Here, we identified Neuregulin 3 (Nrg3) as a chemoattractive factor expressed by developing pyramidal cells that guides the allocation of cortical interneurons in the developing cortical plate. Gain- and loss-of-function approaches reveal that Nrg3 modulates the migration of interneurons into the cortical plate in a process that is dependent on the tyrosine kinase receptor ErbB4. Perturbation of Nrg3 signaling in conditional mutants leads to abnormal lamination of cortical interneurons. Nrg3 is therefore a critical mediator in the assembly of cortical inhibitory circuits

Transient Analysis of Fresnel Zone Plates for Ultrasound Focusing Applications

[EN] Fresnel Zone Plates are planar lenses that can be used to focus ultrasound beams. This kind of acoustic lenses can play a key role in the resolution of ultrasonic NDT systems. In this type of pulse-echo applications, the pulse duration is an important parameter that specifies the axial resolution, and thus, shorter ultrasound pulses provide higher resolutions. However, acoustic lenses exhibit a transient response that should be considered when setting the pulse duration, as pulses shorter than the transient state duration result in degradation in the response of acoustic lenses in terms of focal intensity, focal displacement, and lateral and axial resolutions. In this work, a thorough analysis of the transient response of Fresnel Zone Plates is discussed, demonstrating that the transient state should be considered in order to achieve optimal focusing performance. Theoretical and numerical results are presented, showing very good agreement.This work has been supported by Spanish MICINN RTI2018-100792-B-I00 project, Generalitat Valenciana AICO/2020/139 and the Russian Governmental program "Science" project FSWW-2020-0014. The research is carried out within the framework of Tomsk Polytechnic University Competitiveness Enhancement Program grant VIU-MNOL NK 187/2020. S.P.-L. acknowledges financial support from Universitat Politècnica de València grant program PAID-01-18. D.T.-S. acknowledges financial support from MICINN BES-2016-07713 project.Pérez-López, S.; Tarrazó-Serrano, D.; Dolmatov, DO.; Rubio Michavila, C.; Candelas Valiente, P. (2020). Transient Analysis of Fresnel Zone Plates for Ultrasound Focusing Applications. Sensors. 20(23):1-9. https://doi.org/10.3390/s20236824S192023Albu, S., Joyce, E., Paniwnyk, L., Lorimer, J. P., & Mason, T. J. (2004). 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