Nanoscale roughness and morphology affect the IsoElectric Point of titania surfaces

We report on the systematic investigation of the role of surface nanoscale roughness and morphology on the charging behaviour of nanostructured titania (TiO2) surfaces in aqueous solutions. IsoElectric Points (IEPs) of surfaces have been characterized by direct measurement of the electrostatic double layer interactions between titania surfaces and the micrometer-sized spherical silica probe of an atomic force microscope in NaCl aqueous electrolyte. The use of a colloidal probe provides well-defined interaction geometry and allows effectively probing the overall effect of nanoscale morphology. By using supersonic cluster beam deposition to fabricate nanostructured titania films, we achieved a quantitative control over the surface morphological parameters. We performed a systematical exploration of the electrical double layer properties in different interaction regimes characterized by different ratios of characteristic nanometric lengths of the system: the surface rms roughness Rq, the correlation length {\xi} and the Debye length {\lambda}D. We observed a remarkable reduction by several pH units of IEP on rough nanostructured surfaces, with respect to flat crystalline rutile TiO2. In order to explain the observed behavior of IEP, we consider the roughness-induced self-overlap of the electrical double layers as a potential source of deviation from the trend expected for flat surfaces.Comment: 63 pages, including 7 figures and Supporting Informatio

Spin-String Interaction in QCD Strings

I consider the question of the interaction between a QCD string and the spin of a quark or an antiquark on whose worldline the string terminates. The problem is analysed from the point of view of a string representation for the expectation value of a Wilson loop for a spin-half particle. A string representation of the super Wilson loop is obtained starting from an effective string representation of a Wilson Loop. The action obtained in this manner is invariant under a worldline supersymmetry and has a boundary term which contains the spin-string interaction. For rectangular loops the spin-string interaction vanishes and there is no spin-spin term in the resulting heavy quark potential. On the other hand if an allowance is made for the finite intrinsic thickness of the flux-tube, by assuming that the spin-string interaction takes place not just at the boundary of the string world-sheet but extends to a distance of the order of the intrinsic thickness of the flux tube, then we do obtain a spin-spin interaction which falls as the fifth power of the distance. Such a term was previously suggested by Kogut and Parisi in the context of a flux-tube model of confinement.Comment: 19 pages, 1 figure; Published version with added discussion and references in section

Feature Extraction Technique of PCA for Face Recognition With Accuracy Enhancement

Face recognition is a very complex task in the area of image processing and computer vision. This becomes important because it applies on many real life applications like Security, identification, crowd surveillance, Video surveillance etc. This paper is proposed the PCA based Face recognition. PCA is a holistic based Statistical method which is used to extract the feature from face image and to decrease the large dimensionality of the data to the smaller dimensionality of feature space, then classification is done using Euclidian distance classifier to recognize the face. The proposed method is worked on Yale Database and evaluate under varying conditions like Illumination variant for Center, Left and Right, Different Facial Expression like Happy, Sad, Normal, Wink , Surprised and Sleepy , Wearing spectacles and without it for Frontal Face View. The proposed work demonstrates the recognition rate for given Dataset

Carbon Nanotube Interconnects for End-of-Roadmap Semiconductor Technology Nodes

Advances in semiconductor technology due to aggressive downward scaling of on-chip feature sizes have led to rapid rises in resistivity and current density of interconnect conductors. As a result, current interconnect materials, Cu and W, are subject to performance and reliability constraints approaching or exceeding their physical limits. Therefore, alternative materials such as nanocarbons, metal silicides, and Ag nanowires are actively considered as potential replacements to meet such constraints. Among nanocarbons, carbon nanotube (CNT) is among the leading replacement candidate for on-chip interconnect vias due to its high aspect-ratio nanostructure and superior currentcarrying capacity to those of Cu, W, and other potential candidates. However, contact resistance of CNT with metal is a major bottleneck in device functionalization. To meet the challenge posed by contact resistance, several techniques are designed and implemented. First, the via fabrication and CNT growth processes are developed to increase the CNT packing density inside via and to ensure no CNT growth on via sidewalls. CNT vias with cross-sections down to 40 nm 40 nm are fabricated, which have linewidths similar to those used for on-chip interconnects in current integrated circuit manufacturing technology nodes. Then the via top contact is metallized to increase the total CNT area interfacing with the contact metal and to improve the contact quality and reproducibility. Current-voltage characteristics of individual fabricated CNT vias are measured using a nanoprober and contact resistance is extracted with a first-reported contact resistance extraction scheme for 40 nm linewidth. Based on results for 40 nm and 60 nm top-contact metallized CNT vias, we demonstrate that not only are their current-carrying capacities two orders of magnitude higher than their Cu and W counterparts, they are enhanced by reduced via resistance due to contact engineering. While the current-carrying capacities well exceed those projected for end-of-roadmap technology nodes, the via resistances remain a challenge to replace Cu and W, though our results suggest that further innovations in contact engineering could begin to overcome such challenge

Thickness Dependent Structural, Magnetic and Transport Properties of of Cu / Co Thin Film and Multilayer Structures

Structural, magnetic and transport properties of electron beam evaporated Co/Cu thin film and multilayer structures (MLS) having different layer thicknesses have been characterized using XRD, MOKE and resistivity techniques. The structural studies show different crystal structures for different sub-layer thicknesses. The Co (300 Ǻ) single layer film is amorphous, while Cu (300 Ǻ) film is microcrystalline in nature. The particle size is found to decrease as the number of interfaces increase. The corresponding magnetic and resistivity measurements show an increase in saturation field and resistivity. However, coercivity decreases with decrease in particle size. The results conclude that these properties are greatly influenced by various micro structural parameters such as layer thickness, number of bilayers and the quality of interfaces formed under different growth conditions

Seeking sustainability on service learning projects

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Emergence of best security systems for libraries: RFID

The state-of-art technology for library theft detection is RFID which is now mostly introduced and used by many library and information centres. It is a combination of radio-frequency-based technology and microchip technology to be utilized. It uses radio waves to identify individual items automatically and can be used any where that needed a unique identification. In this paper we present about various components of RFID, operations, advantages and essential requirements

Aortic arch tortuosity with PHACE syndrome : a rare case scenario

PHACE syndrome is a rare neurocutaneous disorder characterised by an association of infantile haemangiomas with structural anomalies of brain, cerebral vasculature, eye, aorta and chest wall.1 Coarctation of aorta (COA) is most the common cardiac anomaly reported in PHACE syndrome. COA or interrupted aortic arch in PHACE is unique and complex both in location and character compared to the typical coarctation anatomy. Arterial tortuosity of the cerebral vasculature has been well described in literature in PHACE syndrome. We present a rare case of tortuous aortic arch continuing as descending aorta in an infant with PHACE syndrome.peer-reviewe

Geotechnical Problems and Treatments of Weathered Rock Seams Occurring in the Foundation of Karjan Dam, Western India

The Karjan dam is located on the Deccan Basalt flows of Cretaceous - Eocene age in the Narmada valley in Gujarat state. A characteristic feature of the basalt flows in this area is conspicuous presence of a number of sub-horizontal weathered rock seams posing the foundation problems of settlement, sliding and seepage. Concrete shear keys have been provided to increase the sliding stability of dam blocks besides other remedial measures. Additional curtain grouting has been done after completion of the dam to reduce seepage