Enhancing thermoelectric properties of graphene quantum rings

We study the thermoelectric properties of rectangular graphene rings connected symmetrically or asymmetrically to the leads. A side-gate voltage applied across the ring allows for the precise control of the electric current flowing through the system. The transmission coefficient of the rings manifests Breit-Wigner line-shapes and/or Fano line-shapes, depending on the connection configuration, the width of nanoribbons forming the ring and the side-gate voltage. We find that the thermopower and the figure of merit are greatly enhanced when the chemical potential is tuned close to resonances. Such enhancement is even more pronounced in the vicinity of Fano like anti-resonances which can be induced by a side-gate voltage independently of the geometry. This opens a possibility to use the proposed device as a tunable thermoelectric generator.Comment: 6 pages, 5 figures, accepted for publication in Physical Review

Lattice thermal conductivity of graphene nanostructures

Non-equilibrium molecular dynamics is used to investigate the heat current due to the atomic lattice vibrations in graphene nanoribbons and nanorings under a thermal gradient. We consider a wide range of temperature, nanoribbon widths up to 6nm and the effect of moderate edge disorder. We find that narrow graphene nanorings can efficiently suppress the lattice thermal conductivity at low temperatures (~100K), as compared to nanoribbons of the same width. Remarkably, rough edges do not appear to have a large impact on lattice energy transport through graphene nanorings while nanoribbons seem more affected by imperfections. Furthermore, we demonstrate that the effects of hydrogen-saturated edges can be neglected in these graphene nanostructures

Bruno and P-element Transposition: Positive regulator or cellular responder?

Transposable elements are harmful genetic entities that can confer serious negative effects on host organisms. We are studying possible natural means of tolerance to these elements, specifically P-elements, through 3 assays.Biology and Biochemistry, Department ofHonors Colleg

Quantum nanoconstrictions fabricated by cryo-etching in encapsulated graphene

More than a decade after the discovery of graphene, ballistic transport in nanostructures based on this intriguing material still represents a challenging field of research in two-dimensional electronics. The presence of rough edges in nanostructures based on this material prevents the appearance of truly ballistic electron transport as theo\-re\-tically predicted and, therefore, not well-developed plateaus of conductance have been revealed to date. In this work we report on a novel implementation of the cryo-etching method, which enabled us to fabricate graphene nanoconstrictions encapsulated between hexagonal boron nitride thin films with unprecedented control of the structure edges. High quality smooth nanometer-rough edges are characterized by atomic force microscopy and a clear correlation between low roughness and the existence of well-developed quantized conductance steps with the concomitant occurrence of ballistic transport is found at low temperature. In par\-ti\-cu\-lar, we come upon exact 2$e^{2}/h$ quantization steps of conductance at zero magnetic field due to size quantization, as it has been theoretically predicted for truly ballistic electron transport through graphene nanoconstrictions

Biodeterioration of Roman tombs: The role of pigmented actinobacteria

Etruscan and Roman necropolises are cemeteries with different types of burial practices, which are remarkable for their magnificent mural paintings. The conservation of these paintings is difficult, mainly derived from environmental factors and the opening of the tombs to public visits. One of the most complex phenomena observed on these sites is biodeterioration. The Circular Mausoleum tomb (Roman Necropolis of Carmona, Seville, Spain) is characterized by a heavy colonization of phototrophic microorganisms on the walls and ceiling. In addition, some areas near the ceiling exhibited an important number of violet stains of unknown origin. Previously, Agarossi (1994) found similar violet stains, attributed to streptomycetes, in two Etruscan tombs. However, no data on the species involved or the chemical structure of the pigments were reported. Here we show that the violet stains observed in the Circular Mausoleum are produced by a strain of the actinobacterium Streptomyces isolated from the mortar walls, and able to synthesize the same violet pigment in the laboratory. Streptomyces parvus MC05 was identified after whole genome study by means of Next Generation Sequencing methods. Pairwise comparisons carried out for genomes of the type strain of S. parvus DSM40348T and the MC05 strain were performed using Jspecies service. While results observed for ANIb, ANIm and Tetra indexes indicated that both strains belong to the same species, the S. parvus MC05 strain differs from the DSM20348T type strain in genome size and secondary metabolites production. AntiSMASH analysis implemented for both strains showed that the S. parvus MC05, isolated from the tomb, presents the capacity of synthesize bioactive compounds which were absents in the type strain. HPLC-MS of the culture extracts from S. parvus MC05 showed the production of three main granaticin derivatives (dihydrogranaticin A, granaticin A and granaticin B) in addition to minor products of other granaticin analogues. Granaticin pigments exhibited antibacterial activity, which justified the low number of clones of Gram positive bacteria found in the whole microbial community study. Gram negative bacteria were not affected (Dominguez-Moñino et al. 2017). To conclude, the origin of the violet stains in the walls of the Circular Mausoleum is the presence of S. parvus MC05, a member of the complex microbial community thriving on the tomb. In growing periods (rainy season) the bacterium excretes the soluble violet granaticins, compounds with a benzoisochromanequinone structure, which diffuses to the mortar and surrounding substrata in wetting periods

Monitoring of Engineering Applications

This paper presents a license monitoring system implemented at CERN in the Computing for Engineering (CE) group of the Information Technology (IT) division. The system gathers statistics on the use of the different software products supported by the group on both Windows and Unix platforms. The web is used for all aspects of the project; data presentation and associated interfaces. The system is completely automated. Manual intervention is required only when there are new products to be monitored. Certain technical details of this work have been reported elsewhere

Global modeling of tropospheric iodine aerosol

Natural aerosols play a central role in the Earth system. The conversion of dimethyl sulfide to sulfuric acid is the dominant source of oceanic secondary aerosol. Ocean emitted iodine can also produce aerosol. Using a GEOS-Chem model, we present a simulation of iodine aerosol. The simulation compares well with the limited observational data set. Iodine aerosol concentrations are highest in the tropical marine boundary layer (MBL) averaging 5.2 ng (I) m −3 with monthly maximum concentrations of 90 ng (I) m −3. These masses are small compared to sulfate (0.75% of MBL burden, up to 11% regionally) but are more significant compared to dimethyl sulfide sourced sulfate (3% of the MBL burden, up to 101% regionally). In the preindustrial, iodine aerosol makes up 0.88% of the MBL burden sulfate mass and regionally up to 21%. Iodine aerosol may be an important regional mechanism for ocean-atmosphere interaction