593 research outputs found
Generalized Lorentz model description-Caputo-Fabrizio fractional derivative approach, of electrical, dielectric, conductive and magnetic processes in materials
In this study, generalized Lorentz model is basic one-particle model in the framework of dielectric, conductive and/or magnetic responses of materials.
AC conductivity studies of various BaTiO3 or similar ceramics produced equivalent circuits with impedance spectra, usually within the framework of RCPE elements serial connection (CPE - constant phase element) or Cole element. This element, in the generalized Lorentz model, corresponds to Caputo fractional derivative, who, as operator, contains a singular integral kernel in itself. However, in the literature, fractional derivatives with a non singular integral kernels have recently emerged. One of them is a Caputo-Fabrizio fractional derivative. In this work, physical basics and all three behaviors (dielectric, conductive and magnetic) of materials and their relationships are considered in the case of electric or magnetic alternate fields, which are the tools for experimental measurements
Variations on the Deuteron
We consider few problems which are related to the deuteron and have simple
analytical solution. Relation is found between the deuteron electric quadrupole
moment and the -scattering amplitude. The degree of circular polarization
of photons is calculated for the radiative capture of longitudinally polarized
thermal neutrons. The anapole, electric dipole and magnetic quadrupole moments
of the deuteron are calculated.Comment: 14 pages, late
Topological network alignment uncovers biological function and phylogeny
Sequence comparison and alignment has had an enormous impact on our
understanding of evolution, biology, and disease. Comparison and alignment of
biological networks will likely have a similar impact. Existing network
alignments use information external to the networks, such as sequence, because
no good algorithm for purely topological alignment has yet been devised. In
this paper, we present a novel algorithm based solely on network topology, that
can be used to align any two networks. We apply it to biological networks to
produce by far the most complete topological alignments of biological networks
to date. We demonstrate that both species phylogeny and detailed biological
function of individual proteins can be extracted from our alignments.
Topology-based alignments have the potential to provide a completely new,
independent source of phylogenetic information. Our alignment of the
protein-protein interaction networks of two very different species--yeast and
human--indicate that even distant species share a surprising amount of network
topology with each other, suggesting broad similarities in internal cellular
wiring across all life on Earth.Comment: Algorithm explained in more details. Additional analysis adde
Primena reaktivnih siloksanskih pretpolimera za sintezu poli(ester-siloksana) i poli(ester-etar-siloksana)
Thermoplastic poly(ester-siloxane)s (TPES) and poly(ester-ether-siloxane)s, (TPEES), based on poly(butylene terephthalate) (PBT) as the hard segment and different siloxane-prepolymers as the soft segments, were prepared. The TPES and TPEES were synthesized by catalyzed two-step transesterification from dimethyl terephthalate, (DMT), 1,4-butanediol, (BD) and a siloxane-prepolymer. Incorporation of dicarboxypropyl- or disilanol-terminated poly(dimethylsiloxane) s (PDMS) into the polar poly(butylene terephthalate) chains resulted in rather inhomogeneous TPES copolymers, which was a consequence of a prononuced phase separation of the polar and non-polar reactants during synthesis. Two concepts were employed to avoid or reduce phase separation: 1) the use of siloxane-containing triblock prepolymers with hydrophilic terminal blocks, such as ethylene oxide (EO), poly(propylene oxide) (PPO) or poly(caprolactone) (PLC) when the terminal blocks serve as a compatibilizer between the extremely non-polar PDMS and the polar DMT and BD, and 2) the use of a high-boiling solvent (1,2,4-trichlorobenzene) during the first phase of the reaction. Homogeneity was significantly improved in the case of copolymers based on PCL-PDMS-PCL.U okviru ovog rada su sintetisani termoplastiÄni poli(estarâsiloksani) (TPES)
i poli(estarâetarâsiloksani) (TPEES), sa tvrdim segmentima na bazi poli(butilentereftalata)
(PBT) i mekim segmentima na bazi razliÄitih siloksanskih pretpolimera.
TPES i TPEES su sintetisani katalizovanom reakcijom dvostepene transesterifikacije,
iz dimetilterftalata (DMT), 1,4-butandiola (BD) i odgovarajuÄeg siloksanskog
pretpolimera. Pri ugradnji dikarboksipropil- ili disilanol-terminiranih
poli(dimetilsiloksana) (PDMS) u polarne poli(butilentereftalatne) lance dobijeni
su priliÄno nehomogeni TPES kopolimeri, ĆĄto je bila posledica loĆĄe menjivosti
reaktanata tokom odigravanja reakcije. Primenjena su dva koncepta da bi se izbeglo
ili smanjilo fazno razdvajanje reakcione smene tokom sinteze organoâsiloksanskih
kopolimera: 1) primena siloksanskih triblok-pretpolimera kod kojih su
hidrofilni terminalni blokovi, izgraÄeni od etilenoksida (EO), poli(propilenoksida)
(PPO) ili poli(kaprolaktona) (PLC), imali funkciju kompatibilizatora izmeÄu
nepolarnog PDMS-a i polarnih reaktanata, DMT-a i BD-a i 2) primena rastvaranja
visoke temperature kljuÄanja (1,2,4-trihlorbenzena) za vreme izvoÄenja prve
faze reakcije. ZnaÄajno poveÄanje homogenosti postignuto je kod kopolimera na bazi
PCLâPDMSâPCL segmenata
Synthesis and Application of Domestic Glassy Carbon TiO2 Nanocomposite for Electrocatalytic Triclosan Detection
Nanoparticles of TiO2 are suitable for many catalytic and photocatalytic applications due to their extraordinary properties such as superhydrophobicity, semiconductivity, electron-rich, and environmental compatibility. The main crystalline phases of TiO2, anatase, and rutile possess different crystal structures, crystallinity, crystalline sizes, and specific surface areas, and these characteristics directly affect the catalytic performance of TiO2. In the present study, domestic carbon material enhanced with TiO2 nanoparticles was synthesized and used for the construction of a modified carbon paste electrode. The electrocatalytic activity of the modified electrodes was investigated depending on the TiO2 crystalline phases in the electrode material. Furthermore, the obtained working electrode was utilized for triclosan detection. Under optimized experimental conditions, the developed electrode showed a submicromolar triclosan detection limit of 0.07 ”M and a wide linear range of 0.1 to 15 ”M. The relative standard deviations for repeatability and reproducibility were lower than 4.1%, and with satisfactory selectivity, the proposed system was successfully applied to triclosan monitoring in groundwater. All these results confirm that the sustainable production of new and domestically prepared materials is of great benefit in the field of electrocatalysis and that the morphology of such produced materials is strongly related to their catalytic properties
Folate, Homocysteine, and Arsenic Metabolism in Arsenic-Exposed Individuals in Bangladesh
Chronic exposure to arsenic is occurring throughout South and East Asia due to groundwater contamination of well water. Variability in susceptibility to arsenic toxicity may be related to nutritional status. Arsenic is methylated to monomethylarsonic acid (MMA) and dimethylarsinic acid (DMA) via one-carbon metabolism, a biochemical pathway that is dependent on folate. The majority of one-carbon metabolism methylation reactions are devoted to biosynthesis of creatine, the precursor of creatinine. Our objectives of this cross-sectional study were to characterize the relationships among folate, cobalamin, homocysteine, and arsenic metabolism in Bangladeshi adults. Water arsenic, urinary arsenic, urinary creatinine, plasma folate, cobalamin, and homocysteine were assessed in 1,650 adults; urinary arsenic metabolites were analyzed for a subset of 300 individuals. The percentage of DMA in urine was positively associated with plasma folate (r = 0.14, p = 0.02) and negatively associated with total homocysteine (tHcys; r = â0.14, p = 0.01). Conversely, percent MMA was negatively associated with folate (r = â0.12, p = 0.04) and positively associated with tHcys (r = 0.21, p = 0.0002); percent inorganic arsenic (InAs) was negatively associated with folate (r = â0.12, p = 0.03). Urinary creatinine was positively correlated with percent DMA (r = 0.40 for males, p < 0.0001; 0.25 for females, p = 0.001), and with percent InAs (r = â0.45 for males, p < 0.0001; â0.20 for females, p = 0.01). Collectively, these data suggest that folate, tHcys, and other factors involved in one-carbon metabolism influence arsenic methylation. This may be particularly relevant in Bangladesh, where the prevalence of hyperhomocysteinemia is extremely high
High-Efficiency Resonant RF Spin Rotator with Broad Phase Space Acceptance for Pulsed Polarized Cold Neutron Beams
We have developed a radio-frequency resonant spin rotator to reverse the
neutron polarization in a 9.5 cm x 9.5 cm pulsed cold neutron beam with high
efficiency over a broad cold neutron energy range. The effect of the spin
reversal by the rotator on the neutron beam phase space is compared
qualitatively to RF neutron spin flippers based on adiabatic fast passage. The
spin rotator does not change the kinetic energy of the neutrons and leaves the
neutron beam phase space unchanged to high precision. We discuss the design of
the spin rotator and describe two types of transmission-based neutron spin-flip
efficiency measurements where the neutron beam was both polarized and analyzed
by optically-polarized 3He neutron spin filters. The efficiency of the spin
rotator was measured to be 98.0+/-0.8% on resonance for neutron energies from
3.3 to 18.4 meV over the full phase space of the beam. As an example of the
application of this device to an experiment we describe the integration of the
RF spin rotator into an apparatus to search for the small parity-violating
asymmetry A_gamma in polarized cold neutron capture on para-hydrogen by the
NPDGamma collaboration at LANSCE
X-ray structural analysis and antitumor activity of new salicylic acid derivatives
This Thesis project is going to be situated in my home town Ăstersund, 600 kilometers north from Stockholm.ItÂŽs a small town with 60 000 people and it is the only city of the region JĂ€mtland in Norrland, Sweden.In the city centre of Ăstersund there is one existing bus terminal station where the buses arrive with people from the entire region.The task for this Thesis project is to rebuild the existing bus station in Ăstersund where the actual terminal building is going to be completely demolished and the entire block within the current bus stops is going to be rearranged.The topography of the terminal area is now dividing the regional buses that arrives on the upper level from the city buses that stops at the lower level. Therefore the main challenge of the new proposal is how one would strengthen the junction between these two flows of people and how a new architecture could enable the encounter between the countryside and the urban city.Detta examensprojekt kommer att vara belĂ€gen i min hemstad Ăstersund, 600 kilometer norr om Stockholm. Det Ă€r en liten stad med 60 000 personer och det Ă€r den enda staden i regionen JĂ€mtland, Norrland. I centrum av Ăstersund finns en befintlig bussterminalen dĂ€r bussarna anlĂ€nder med folk frĂ„n hela regionen. Uppgiften för detta projekt Ă€r att bygga om den befintliga busstationen i Ăstersund topografin pĂ„ terminalomrĂ„det i dagslĂ€get separerar de regionala bussarna som anlĂ€nder pĂ„ den övre nivĂ„n frĂ„n stadsbussarna som stannar pĂ„ en lĂ€gre nivĂ„. Den största utmaningen i det nya förslaget Ă€r hur man istĂ€llet skulle kunna stĂ€rka förbindelsen mellan dessa tvĂ„ flöden av mĂ€nniskor och hur en ny arkitektur kan möjliggöra mötet mellan glesbyggd och den urbana staden
- âŠ