405 research outputs found
Spin and lattice excitations of a BiFeO3 thin film and ceramics
We present a comprehensive study of polar and magnetic excitations in BiFeO3
ceramics and a thin film epitaxially grown on an orthorhombic (110) TbScO3
substrate. Infrared reflectivity spectroscopy was performed at temperatures
from 5 to 900 K for the ceramics and below room temperature for the thin film.
All 13 polar phonons allowed by the factor-group analysis were observed in
theceramic samples. The thin-film spectra revealed 12 phonon modes only and an
additional weak excitation, probably of spin origin. On heating towards the
ferroelectric phase transition near 1100 K, some phonons soften, leading to an
increase in the static permittivity. In the ceramics, terahertz transmission
spectra show five low-energy magnetic excitations including two which were not
previously known to be infrared active; at 5 K, their frequencies are 53 and 56
cm-1. Heating induces softening of all magnetic modes. At a temperature of 5 K,
applying an external magnetic field of up to 7 T irreversibly alters the
intensities of some of these modes. The frequencies of the observed spin
excitations provide support for the recently developed complex model of
magnetic interactions in BiFeO3 (R.S. Fishman, Phys. Rev. B 87, 224419 (2013)).
The simultaneous infrared and Raman activity of the spin excitations is
consistent with their assignment to electromagnons
Time-Domain Finite Elements for Virtual Testing of Electromagnetic Compatibility
The paper presents a time-domain finite-element solver developed for simulations related to solving electromagnetic compatibility issues. The software is applied as a module integrated into a computational framework developed within a FP7 European project High Intensity Radiated Field – Synthetic Environment (HIRF SE) able to simulate a large class of problems. In the paper, the mathematical formulation is briefly presented, and special emphasis is put on the user point of view on the simulation tool-chain. The functionality is demonstrated on the computation of shielding effectiveness of two composite materials. Results are validated through experimental measurements and agreement is confirmed by automatic feature selective algorithms
From Sensor Readings to Predictions: On the Process of Developing Practical Soft Sensors.
Automatic data acquisition systems provide large amounts of streaming data generated by physical sensors. This data forms an input to computational models (soft sensors) routinely used for monitoring and control of industrial processes, traffic patterns, environment and natural hazards, and many more. The majority of these models assume that the data comes in a cleaned and pre-processed form, ready to be fed directly into a predictive model. In practice, to ensure appropriate data quality, most of the modelling efforts concentrate on preparing data from raw sensor readings to be used as model inputs. This study analyzes the process of data preparation for predictive models with streaming sensor data. We present the challenges of data preparation as a four-step process, identify the key challenges in each step, and provide recommendations for handling these issues. The discussion is focused on the approaches that are less commonly used, while, based on our experience, may contribute particularly well to solving practical soft sensor tasks. Our arguments are illustrated with a case study in the chemical production industry
Magnetic and dielectric properties of multiferroic Eu0.5Ba0.25Sr0.25TiO3 ceramics
Dielectric and magnetic properties of Eu0.5Ba0.25Sr0.25TiO3 are investigated
between 10 K and 300 K in the frequency range from 10 Hz to 100 THz. A peak in
permittivity revealed near 130 K and observed ferroelectric hysteresis loops
prove the ferroelectric order below thistemperature. The peak in permittivity
is given mainly by softening of the lowest frequency polar phonon (soft mode
revealed in THz and IR spectra) that demonstrates displacive character of the
phase transition. Room-temperature X-ray diffraction analysis reveals cubic
structure, but the IR reflectivity spectra give evidence of a lower crystal
structure, presumably tetragonal I4/mcm with tilted oxygen octahedra as it has
been observed in EuTiO3. The magnetic measurements show that the
antiferromagnetic order occurs below 1.8 K. Eu0.5Ba0.25Sr0.25TiO3 has three
times lower coercive field than Eu0.5Ba0.5TiO3, therefore we propose this
system for measurements of electric dipole moment of electron.Comment: Phase Transitions, in pres
Terahertz and infrared spectroscopic evidence of phonon-paramagnon coupling in hexagonal piezomagnetic YMnO3
Terahertz and far-infrared electric and magnetic responses of hexagonal
piezomagnetic YMnO3 single crystals are investigated. Antiferromagnetic
resonance is observed in the spectra of magnetic permeability mu_a [H(omega)
oriented within the hexagonal plane] below the Neel temperature T_N. This
excitation softens from 41 to 32 cm-1 on heating and finally disappears above
T_N. An additional weak and heavily-damped excitation is seen in the spectra of
complex dielectric permittivity epsilon_c within the same frequency range. This
excitation contributes to the dielectric spectra in both antiferromagnetic and
paramagnetic phases. Its oscillator strength significantly increases on heating
towards room temperature thus providing evidence of piezomagnetic or
higher-order couplings to polar phonons. Other heavily-damped dielectric
excitations are detected near 100 cm-1 in the paramagnetic phase in both
epsilon_c and epsilon_a spectra and they exhibit similar temperature behavior.
These excitations appearing in the frequency range of magnon branches well
below polar phonons could remind electromagnons; however, their temperature
dependence is quite different. We have used density functional theory for
calculating phonon dispersion branches in the whole Brillouin zone. A detailed
analysis of these results and of previously published magnon dispersion
branches brought us to the conclusion that the observed absorption bands stem
from phonon-phonon and phonon- paramagnon differential absorption processes.
The latter is enabled by a strong short-range in-plane spin correlations in the
paramagnetic phase.Comment: subm. to PR
Systematic study of Mn-doping trends in optical properties of (Ga,Mn)As
We report on a systematic study of optical properties of (Ga,Mn)As epilayers
spanning the wide range of accessible substitutional Mn_Ga dopings. The growth
and post-growth annealing procedures were optimized for each nominal Mn doping
in order to obtain films which are as close as possible to uniform
uncompensated (Ga,Mn)As mixed crystals. We observe a broad maximum in the
mid-infrared absorption spectra whose position exhibits a prevailing blue-shift
for increasing Mn-doping. In the visible range, a peak in the magnetic circular
dichroism blue shifts with increasing Mn-doping. These observed trends confirm
that disorder-broadened valence band states provide a better one-particle
representation for the electronic structure of high-doped (Ga,Mn)As with
metallic conduction than an energy spectrum assuming the Fermi level pinned in
a narrow impurity band.Comment: 22 pages, 14 figure
Evaluation of the Test Temperature Effect on Failure Mechanisms and Notched Impact Strength Characteristics of Ultra-Hard Low Alloy Steels
На основании данных фрактографического анализа оценено изменение механизмов разрушения высокопрочных малолегированных сталей ARMOX 500T и ARMOX 600T в зависимости оттемпературы испытаний. В экспериментально исследованномтемпературном диапазоне
-80...100°C была установлена высокая вероятность достижения предельного состояния этих материалов.На основі даних фрактографічного аналізу оцінено зміну механізмів руйнування високоміцних малолегованих сталейARMOX 500T та ARMOX 600T у залежності від температури випробувань. В експериментально дослідженому температурному інтервалі-80...100°C установлено високу імовірність досягнення граничного стану цих матеріалів
Shock pressure induced by 0.44 [mu]m laser radiation on aluminum targets
Shock pressure generated in aluminum targets due to the interaction
of 0.44 μm (3 ω of iodine laser) laser radiation has been
studied. The laser intensity profile was smoothed using phase zone
plates. Aluminum step targets were irradiated at an intensity
I ≈ 1014 W/cm2. Shock velocity in
the aluminum target was estimated by detecting the shock luminosity
from the target rear using a streak camera to infer the shock pressure.
Experimental results show a good agreement with the theoretical model
based on the delocalized laser absorption approximation. In the present
report, we explicitly discuss the importance of target thickness on the
shock pressure scaling
Magnetic record associated with tree ring density: Possible climate proxy
A magnetic signature of tree rings was tested as a potential paleo-climatic indicator. We examined wood from sequoia tree, located in Mountain Home State Forest, California, whose tree ring record spans over the period 600 – 1700 A.D. We measured low and high-field magnetic susceptibility, the natural remanent magnetization (NRM), saturation isothermal remanent magnetization (SIRM), and stability against thermal and alternating field (AF) demagnetization. Magnetic investigation of the 200 mm long sequoia material suggests that magnetic efficiency of natural remanence may be a sensitive paleoclimate indicator because it is substantially higher (in average >1%) during the Medieval Warm Epoch (700–1300 A.D.) than during the Little Ice Age (1300–1850 A.D.) where it is <1%. Diamagnetic behavior has been noted to be prevalent in regions with higher tree ring density. The mineralogical nature of the remanence carrier was not directly detected but maghemite is suggested due to low coercivity and absence of Verwey transition. Tree ring density, along with the wood's magnetic remanence efficiency, records the Little Ice Age (LIA) well documented in Europe. Such a record suggests that the European LIA was a global phenomenon. Magnetic analysis of the thermal stability reveals the blocking temperatures near 200 degree C. This phenomenon suggests that the remanent component in this tree may be thermal in origin and was controlled by local thermal condition
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