Tackling Challenges in Seebeck Coefficient Measurement of Ultra-High Resistance Samples with an AC Technique

Seebeck coefficient is a widely studied semiconductor property. Conventional Seebeck coefficient measurements are based on DC voltage measurement. Normally this is performed on samples with moderate resistances (e.g., below a few MΩ level). Certain semiconductors are intrinsic and highly resistive. Many examples can be found in optical and photovoltaic materials. The hybrid halide perovskites that have gained extensive attention recently are a good example. Despite great attention from the materials and physics communities, few successful studies exist of the Seebeck coefficient of these compounds, for example CH3NH3PbI3. An AC-technique-based Seebeck coefficient measurement is reported, which makes high-quality Seebeck voltage measurements on samples with resistances up to the 100 GΩ level. This is achieved through a specifically designed setup to enhance sample isolation and increase capacitive impedance. As a demonstration, Seebeck coefficient measurement of a CH3NH3PbI3 thin film is performed at dark, with sample resistance 150 GΩ, and found S = +550 µV K−1. The strategy reported could be applied to the studies of fundamental transport parameters of all intrinsic semiconductors that have not been feasible

TDC Chip and Readout Driver Developments for COMPASS and LHC-Experiments

A new TDC-chip is under development for the COMPASS experiment at CERN. The ASIC, which exploits the 0.6 micrometer CMOS sea-of-gate technology, will allow high resolution time measurements with digitization of 75 ps, and an unprecedented degree of flexibility accompanied by high rate capability and low power consumption. Preliminary specifications of this new TDC chip are presented. Furthermore a FPGA based readout-driver and buffer-module as an interface between the front-end of the COMPASS detector systems and an optical S-LINK is in development. The same module serves also as remote fan-out for the COMPASS trigger distribution and time synchronization system. This readout-driver monitors the trigger and data flow to and from front-ends. In addition, a specific data buffer structure and sophisticated data flow control is used to pursue local pre-event building. At start-up the module controls all necessary front-end initializations.Comment: 5 pages, 4 figure

Sustaining Collection Value: Managing Collection/Item Metadata Relationships

Many aspects of managing collection/item metadata relationships are critical to sustaining collection value over time. Metadata at the collection-level not only provides context for finding, understanding, and using the items in the collection, but is often essential to the particular research and scholarly activities the collection is designed to support. Contemporary retrieval systems, which search across collections, usually ignore collection level metadata. Alternative approaches, informed by collection-level information, will require an understanding of the various kinds of relationships that can obtain between collection-level and item-level metadata. This paper outlines the problem and describes a project that is developing a logic-based framework for classifying collection-level/item-level metadata relationships. This framework will support (i) metadata specification developers defining metadata elements, (ii) metadata librarians describing objects, and (iii) system designers implementing systems that help users take advantage of collection-level metadata.Institute for Museum and Libary Services (Grant #LG06070020)published or submitted for publicationis peer reviewe

Do Lognormal Column-Density Distributions in Molecular Clouds Imply Supersonic Turbulence?

Recent observations of column densities in molecular clouds find lognormal distributions with power-law high-density tails. These results are often interpreted as indications that supersonic turbulence dominates the dynamics of the observed clouds. We calculate and present the column-density distributions of three clouds, modeled with very different techniques, none of which is dominated by supersonic turbulence. The first star-forming cloud is simulated using smoothed particle hydrodynamics (SPH); in this case gravity, opposed only by thermal-pressure forces, drives the evolution. The second cloud is magnetically subcritical with subsonic turbulence, simulated using nonideal MHD; in this case the evolution is due to gravitationally-driven ambipolar diffusion. The third cloud is isothermal, self-gravitating, and has a smooth density distribution analytically approximated with a uniform inner region and an r^-2 profile at larger radii. We show that in all three cases the column-density distributions are lognormal. Power-law tails develop only at late times (or, in the case of the smooth analytic profile, for strongly centrally concentrated configurations), when gravity dominates all opposing forces. It therefore follows that lognormal column-density distributions are generic features of diverse model clouds, and should not be interpreted as being a consequence of supersonic turbulence.Comment: 6 pages, 6 figures, accepted for publication in MNRA

Tunable dynamical channel blockade in double-dot Aharonov-Bohm interferometers

We study electronic transport through an Aharonov-Bohm interferometer with single-level quantum dots embedded in the two arms. The full counting statistics in the shot-noise regime is calculated to first order in the tunnel-coupling strength. The interplay of interference and charging energy in the dots leads to a dynamical channel blockade that is tunable by the magnetic flux penetrating the Aharonov-Bohm ring. We find super-Poissonian behavior with diverging second and higher cumulants when the Aharonov-Bohm flux approaches an integer multiple of the flux quantum.Comment: published version, 10 pages, 10 figure

Jahn-Teller Distortions and the Supershell Effect in Metal Nanowires

A stability analysis of metal nanowires shows that a Jahn-Teller deformation breaking cylindrical symmetry can be energetically favorable, leading to stable nanowires with elliptic cross sections. The sequence of stable cylindrical and elliptical nanowires allows for a consistent interpretation of experimental conductance histograms for alkali metals, including both the shell and supershell structures. It is predicted that for gold, elliptical nanowires are even more likely to form since their eccentricity is smaller than for alkali metals. The existence of certain metastable ``superdeformed'' nanowires is also predicted

Electronic and atomic shell structure in aluminum nanowires

We report experiments on aluminum nanowires in ultra-high vacuum at room temperature that reveal a periodic spectrum of exceptionally stable structures. Two "magic" series of stable structures are observed: At low conductance, the formation of stable nanowires is governed by electronic shell effects whereas for larger contacts atomic packing dominates. The crossover between the two regimes is found to be smooth. A detailed comparison of the experimental results to a theoretical stability analysis indicates that while the main features of the observed electron-shell structure are similar to those of alkali and noble metals, a sequence of extremely stable wires plays a unique role in Aluminum. This series appears isolated in conductance histograms and can be attributed to "superdeformed" non-axisymmetric nanowires.Comment: 15 pages, 9 figure

Engineering study to determine feasible methods of simulating planetary albedo and radiation effects upon the thermal balance of spacecraft Final report

Planetary radiation and albedo effects on thermal balance of spacecraft orbiting Mars and Venu