5,546 research outputs found
Harold A. Kahn (1920–2009): A Remembrance of a Life Devoted to Public Health
This is an Open Access article distributed under the terms of the Creative Commons Attribution Non-Commercial Licens
The Chandra Iron-L X-Ray Line Spectrum of Capella
An analysis of the iron L-shell emission in the publicly available spectrum
of the Capella binary system, as obtained by the High Energy Transmission
Grating Spectrometer on board the Chandra X-ray Observatory, is presented. The
atomic-state model, based on the HULLAC code, is shown to be especially
adequate for analyzing high-resolution x-ray spectra of this sort. Almost all
of the spectral lines in the 10 - 18 Angstrom wavelength range are identified.
It is shown that, for the most part, these lines can be attributed to emission
from L-shell iron ions in the Capella coronae. Possibilities for electron
temperature diagnostics using line ratios of Fe16+ are demonstrated. It is
shown that the observed iron-L spectrum can be reproduced almost entirely by
assuming a single electron temperature of kTe= 600 eV. This temperature is
consistent with both the measured fractional ion abundances of iron and with
the temperature derived from ratios of Fe16+ lines. A volume emission measure
of 1053 cm-3 is calculated for the iron L-shell emitting regions of the Capella
coronae indicating a rather small volume of 1029 cm3 for the emitting plasma if
an electron density of 1012 cm-3 is assumed.Comment: Accepted to Ap
Electronic structure of the molecule based magnet Cu PM(NO3)2 (H2O)2
We present density functional calculations on the molecule based S=1/2
antiferromagnetic chain compound Cu PM(NO3)2 (H2O)2; PM = pyrimidine. The
properties of the ferro- and antiferromagnetic state are investigated at the
level of the local density approximation and with the hybrid functional B3LYP.
Spin density maps illustrate the exchange path via the pyrimidine molecule
which mediates the magnetism in the one-dimensional chain. The computed
exchange coupling is antiferromagnetic and in reasonable agreement with the
experiment. It is suggested that the antiferromagnetic coupling is due to the
possibility of stronger delocalization of the charges on the nitrogen atoms,
compared to the ferromagnetic case. In addition, computed isotropic and
anisotropic hyperfine interaction parameters are compared with recent NMR
experiments
Machine Assisted Proofs for Generic Semantics to Compiler Transformation Correctness Theorems
This thesis investigates the issues involved in the creation of a "general theory of operational semantics" in LEGO, a type-theoretic theorem proving environment implementing a constructionist logic. Such a general theory permits the ability to manipulate and reason about operational semantics both individually and as a class. The motivation for this lies in the studies of semantics directed compiler generation in which a set of generic semantics transforming functions can help convert arbitrary semantic definitions to abstract machines. Such transformations require correctness theorems that quantify over the class of operational semantics. In implementation terms this indicates the need to ensure both the class of operational semantics and the means of inferring results thereon remain at the theorem prover level. The endeavour of this thesis can be seen as assessing both the requirements that general theories of semantics impose on proof assistants and the efficacy of proof assistants in modelling such theories
Psychometric evaluation of the German version of a social support scale of FAFHES (family functioning, family health and social support)
This is the peer reviewed version which has been published in final form at https://doi.org/10.1111/scs.12700. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions.BACKGROUND:
Family members often need to be supported in informal care of the elderly and desire to be involved into care planning and decision-making. Valid and reliable instruments are needed to measure how family members perceive the care and support they receive from nurses for older family members living at home.
AIM:
The purpose of this study was to translate the 20-item social support scale of the Family Functioning, Family Health and Social Support (FAFHES) questionnaire from English to German and test the validity and reliability of the scale among Swiss-German-speaking family caregivers of home-dwelling elderly people who receive home healthcare services.
METHODS:
A cross-sectional study was conducted to test the empirical and psychometric properties of the translated and culturally adapted version of the social support questionnaire. A factor analysis with the principal component analysis PCA was used to test construct validity. The internal consistency of items was measured with the Cronbach`s alpha coefficient.
RESULTS:
After a rigorous translation process the original 20-item questionnaire was adapted into a 19-item version and tested with family caregivers (n = 207) of home-dwelling elderly. Psychometric testing of the German version of the social support questionnaire revealed that the three factors - affirmation, affect and concrete aid - were congruent with the original questionnaire. The accounted variance was 79.5% and the internal consistency determined by the Cronbach's alpha was 0.973.
CONCLUSION:
The German version of the social support scale of the FAFHES questionnaire is a valid and reliable instrument to assess family perceived support on three dimensions - affirmation, affect and concrete aid - received from nursing professionals. The questionnaire should be tested further in other German-speaking population
State estimation in quantum homodyne tomography with noisy data
In the framework of noisy quantum homodyne tomography with efficiency
parameter , we propose two estimators of a quantum state whose
density matrix elements decrease like , for
fixed known and . The first procedure estimates the matrix
coefficients by a projection method on the pattern functions (that we introduce
here for ), the second procedure is a kernel estimator of the
associated Wigner function. We compute the convergence rates of these
estimators, in risk
Exchange Interactions and High-Energy Spin States in Mn_12-acetate
We perform inelastic neutron scattering measurements on the molecular
nanomagnet Mn_12-acetate to measure the excitation spectrum up to 45meV (500K).
We isolate magnetic excitations in two groups at 5-6.5meV (60-75K) and
8-10.5meV (95-120K), with higher levels appearing only at 27meV (310K) and
31meV (360K). From a detailed characterization of the transition peaks we show
that all of the low-energy modes appear to be separate S = 9 excitations above
the S = 10 ground state, with the peak at 27meV (310K) corresponding to the
first S = 11 excitation. We consider a general model for the four exchange
interaction parameters of the molecule. The static susceptibility is computed
by high-temperature series expansion and the energy spectrum, matrix elements
and ground-state spin configuration by exact diagonalization. The theoretical
results are matched with experimental observation by inclusion of cluster
anisotropy parameters, revealing strong constraints on possible parameter sets.
We conclude that only a model with dominant exchange couplings J_1 ~ J_2 ~
5.5meV (65K) and small couplings J_3 ~ J_4 ~ 0.6meV (7K) is consistent with the
experimental data.Comment: 17 pages, 12 figure
Butterfly Hysteresis and Slow Relaxation of the Magnetization in (Et4N)3Fe2F9: Manifestations of a Single-Molecule Magnet
(Et4N)3Fe2F9 exhibits a butterfly--shaped hysteresis below 5 K when the
magnetic field is parallel to the threefold axis, in accordance with a very
slow magnetization relaxation in the timescale of minutes. This is attributed
to an energy barrier Delta=2.40 K resulting from the S=5 dimer ground state of
[Fe2F9]^{3-} and a negative axial anisotropy. The relaxation partly occurs via
thermally assisted quantum tunneling. These features of a single-molecule
magnet are observable at temperatures comparable to the barrier height, due to
an extremely inefficient energy exchange between the spin system and the
phonons. The butterfly shape of the hysteresis arises from a phonon avalanche
effect.Comment: 18 pages, 5 eps figures, latex (elsart
Particle creation in a colliding plane wave spacetime: wave packet quantization
We use wave packet mode quantization to compute the creation of massless
scalar quantum particles in a colliding plane wave spacetime. The background
spacetime represents the collision of two gravitational shock waves followed by
trailing gravitational radiation which focus into a Killing-Cauchy horizon. The
use of wave packet modes simplifies the problem of mode propagation through the
different spacetime regions which was previously studied with the use of
monocromatic modes. It is found that the number of particles created in a given
wave packet mode has a thermal spectrum with a temperature which is inversely
proportional to the focusing time of the plane waves and which depends on the
mode trajectory.Comment: 23, latex, figures available by fa
Scenario planning for the Edinburgh city region
This paper examines the application of scenario planning techniques to the detailed and daunting challenge of city re-positioning when policy makers are faced with a heavy history and a complex future context. It reviews a process of scenario planning undertaken in the Edinburgh city region, exploring the scenario process and its contribution to strategies and policies for city repositioning. Strongly rooted in the recent literature on urban and regional economic development, the text outlines how key individuals and organisations involved in the process participated in far-reaching analyses of the possible future worlds in which the Edinburgh city region might find itself
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