Oligomer formation within secondary organic aerosols: equilibrium and dynamic considerations

We present a model based on the volatility basis set to consider the potential influence of oligomer content on volatility driven secondary organic aerosol (SOA) yields. The implications for aerosol evaporation studies, including dilution, chamber thermo-equilibration, and thermodenuder studies, are also considered. A simplified description of oligomer formation reproduces essentially all of the broad classes of equilibrium and dynamical observations related to SOA formation and evaporation: significant oligomer content may be consistent with mass yields that increase with organic aerosol mass concentration; reversible oligomerization can explain the hysteresis between the rate of SOA formation and its evaporation rate upon dilution; and the model is consistent with both chamber thermo-equilibration studies and thermodenuder studies of SOA evaporation

C IV BAL disappearance in a large SDSS QSO sample

Broad absorption lines (BALs) in the spectra of quasi-stellar objects (QSOs) originate from outflowing winds along our line of sight; winds are thought to originate from the inner regions of the QSO accretion disk, close to the central supermassive black hole (SMBH). Winds likely play a role in galaxy evolution and aid the accretion mechanism onto the SMBH. BAL equivalent widths can change on typical timescales from months to years; such variability is generally attributed to changes in the covering factor and/or in the ionization level of the gas. We investigate BAL variability, focusing on BAL disappearance. We analyze multi-epoch spectra of more than 1500 QSOs -the largest sample ever used for such a study- observed by different programs from the Sloan Digital Sky Survey-I/II/III (SDSS), and search for disappearing C IV BALs. The spectra rest-frame time baseline ranges from 0.28 to 4.9 yr; the source redshifts range from 1.68 to 4.27. We detect 73 disappearing BALs in the spectra of 67 sources. This corresponds to 3.9% of disappearing BALs, and 5.1% of our BAL QSOs exhibit at least one disappearing BAL. We estimate the average lifetime of a BAL along our line of sight (~ 80-100 yr), which appears consistent with the accretion disk orbital time at distances where winds are thought to originate. We inspect properties of the disappearing BALs and compare them to the properties of our main sample. We also investigate the existence of a correlation in the variability of multiple troughs in the same spectrum, and find it persistent at large velocity offsets between BAL pairs, suggesting that a mechanism extending on a global scale is necessary to explain the phenomenon. We select a more reliable sample of disappearing BALs following Filiz Ak et al. (2012), where a subset of our sample was analyzed, and compare the findings from the two works, obtaining generally consistent results.Comment: 22 pages, 9 figures. Accepted for publication in A&

Ballistic magnon heat conduction and possible Poiseuille flow in the helimagnetic insulator Cu2_2OSeO3_3

We report on the observation of magnon thermal conductivity $\kappa_m\sim$ 70 W/mK near 5 K in the helimagnetic insulator Cu$_2$OSeO$_3$, exceeding that measured in any other ferromagnet by almost two orders of magnitude. Ballistic, boundary-limited transport for both magnons and phonons is established below 1 K, and Poiseuille flow of magnons is proposed to explain a magnon mean-free path substantially exceeding the specimen width for the least defective specimens in the range 2 K $<T<$ 10 K. These observations establish Cu$_2$OSeO$_3$ as a model system for studying long-wavelength magnon dynamics.Comment: 10pp, 9 figures, accepted PRB (Editor's Suggestion

The Sloan Digital Sky Survey Reverberation Mapping Project: Post-Starburst Signatures in Quasar Host Galaxies at z < 1

Quasar host galaxies are key for understanding the relation between galaxies and the supermassive black holes (SMBHs) at their centers. We present a study of 191 broad-line quasars and their host galaxies at z < 1, using high signal-to-noise ratio (SNR) spectra produced by the Sloan Digital Sky Survey Reverberation Mapping project. Clear detection of stellar absorption lines allows a reliable decomposition of the observed spectra into nuclear and host components, using spectral models of quasar and stellar radiations as well as emission lines from the interstellar medium. We estimate age, mass (M*), and velocity dispersion (sigma*) of the host stars, the star formation rate (SFR), quasar luminosity, and SMBH mass (Mbh), for each object. The quasars are preferentially hosted by massive galaxies with M* ~ 10^{11} Msun characterized by stellar ages around a billion years, which coincides with the transition phase of normal galaxies from the blue cloud to the red sequence. The host galaxies have relatively low SFRs and fall below the main sequence of star-forming galaxies at similar redshifts. These facts suggest that the hosts have experienced an episode of major star formation sometime in the past billion years, which was subsequently quenched or suppressed. The derived Mbh - sigma* and Mbh - M* relations agree with our past measurements and are consistent with no evolution from the local Universe. The present analysis demonstrates that reliable measurements of stellar properties of quasar host galaxies are possible with high-SNR fiber spectra, which will be acquired in large numbers with future powerful instruments such as the Subaru Prime Focus Spectrograph.Comment: ApJ in pres

An Extension of a Volumetric Method for Aluminum to the Determination of Milligram Quantities

Snyder (3) has given a rapid and precise titrimetric procedure for the determination of aluminum in the presence of moderate amounts of other substances. The original method was applied to samples containing from 0.025 to 0.13 gram of aluminum. In the present work it was found that, with certain modifications, the same procedure could also be used for the determination of alumim1m in the range of 5 to 25 milligrams. The precision of the modified method was found to correspond to a standard deviation of about 0.1 milligram throughout this range

Stellar X-ray sources in the Chandra COSMOS survey

We present an analysis of the X-ray properties of a sample of solar- and late-type field stars identified in the Chandra Cosmic Evolution Survey (COSMOS), a deep (160ks) and wide (0.9 deg2) extragalactic survey. The sample of 60 sources was identified using both morphological and photometric star/galaxy separation methods. We determine X-ray count rates, extract spectra and light curves and perform spectral fits to determine fluxes and plasma temperatures. Complementary optical and near-IR photometry is also presented and combined with spectroscopy for 48 of the sources to determine spectral types and distances for the sample. We find distances ranging from 30pc to ~12kpc, including a number of the most distant and highly active stellar X-ray sources ever detected. This stellar sample extends the known coverage of the L_X-distance plane to greater distances and higher luminosities, but we do not detect as many intrinsically faint X-ray sources compared to previous surveys. Overall the sample is typically more luminous than the active Sun, representing the high-luminosity end of the disk and halo X-ray luminosity functions. The halo population appears to include both low-activity spectrally hard sources that may be emitting through thermal bremsstrahlung, as well as a number of highly active sources in close binaries.Comment: 13 pages, 5 figures, accepted for publication in Ap

Observational Constraints on the Dependence of Radio-Quiet Quasar X-ray Emission on Black Hole Mass and Accretion Rate

In this work we use a sample of 318 radio-quiet quasars (RQQ) to investigate the dependence of the ratio of optical/UV flux to X-ray flux, alpha_ox, and the X-ray photon index, Gamma_X, on black hole mass, UV luminosity relative to Eddington, and X-ray luminosity relative to Eddington. Our sample is drawn from the SDSS, with X-ray data from ROSAT and Chandra, and optical data mostly from the SDSS; 153 of these sources have estimates of Gamma_X from Chandra. We estimate M_BH using standard estimates derived from the Hbeta, Mg II, and C IV broad emission lines. Our sample spans a broad range in black hole mass (10^6 < M_BH / M_Sun < 10^10) and redshift (z < 4.8). We find that alpha_ox increases with increasing M_BH and L_UV / L_Edd, and decreases with increasing L_X / L_Edd. In addition, we confirm the correlation seen in previous studies between Gamma_X and M_BH and both L_UV / L_Edd and L_X / L_Edd; however, we also find evidence that the dependence of Gamma_X of these quantities is not monotonic, changing sign at M_BH ~ 3 x 10^8 M_Sun. We argue that the alpha_ox correlations imply that the fraction of bolometric luminosity emitted by the accretion disk, as compared to the corona, increases with increasing accretion rate relative to Eddington. In addition, we argue that the Gamma_X trends are caused by a dependence of X-ray spectral index on accretion rate. We discuss our results within the context of accretion models with comptonizing corona, and discuss the implications of the alpha_ox correlations for quasar feedback. To date, this is the largest study of the dependence of RQQ X-ray parameters on black hole mass and related quantities, and the first to attempt to correct for the large statistical uncertainty in the broad line mass estimates.Comment: Accepted by ApJ, 23 pages, 15 figures, emulateapj styl

The XMM-Newton wide-field survey in the COSMOS field. IV: X-ray spectral properties of Active Galactic Nuclei

We present a detailed spectral analysis of point-like X-ray sources in the XMM-COSMOS field. Our sample of 135 sources only includes those that have more than 100 net counts in the 0.3-10 keV energy band and have been identified through optical spectroscopy. The majority of the sources are well described by a simple power-law model with either no absorption (76%) or a significant intrinsic, absorbing column (20%).As expected, the distribution of intrinsic absorbing column densities is markedly different between AGN with or without broad optical emission lines. We find within our sample four Type-2 QSOs candidates (L_X > 10^44 erg/s, N_H > 10^22 cm^-2), with a spectral energy distribution well reproduced by a composite Seyfert-2 spectrum, that demonstrates the strength of the wide field XMM/COSMOS survey to detect these rare and underrepresented sources.Comment: 16 pages, ApJS COSMOS Special Issue, 2007 in press. The full-resolution version is available at http://www.mpe.mpg.de/XMMCosmos/PAPERS/mainieri_cosmos.ps.g

The Chandra COSMOS Survey: III. Optical and Infrared Identification of X-ray Point Sources

The Chandra COSMOS Survey (C-COSMOS) is a large, 1.8 Ms, Chandra program that has imaged the central 0.9 deg^2 of the COSMOS field down to limiting depths of 1.9 10^-16 erg cm^-2 s-1 in the 0.5-2 keV band, 7.3 10^-16 erg cm^-2 s^-1 in the 2-10 keV band, and 5.7 10^-16 erg cm^-2 s-1 in the 0.5-10 keV band. In this paper we report the i, K and 3.6micron identifications of the 1761 X-ray point sources. We use the likelihood ratio technique to derive the association of optical/infrared counterparts for 97% of the X-ray sources. For most of the remaining 3%, the presence of multiple counterparts or the faintness of the possible counterpart prevented a unique association. For only 10 X-ray sources we were not able to associate a counterpart, mostly due to the presence of a very bright field source close by. Only 2 sources are truly empty fields. Making use of the large number of X-ray sources, we update the "classic locus" of AGN and define a new locus containing 90% of the AGN in the survey with full band luminosity >10^42 erg/s. We present the linear fit between the total i band magnitude and the X-ray flux in the soft and hard band, drawn over 2 orders of magnitude in X-ray flux, obtained using the combined C-COSMOS and XMM-COSMOS samples. We focus on the X-ray to optical flux ratio (X/O) and we test its known correlation with redshift and luminosity, and a recently introduced anti-correlation with the concentration index (C). We find a strong anti-correlation (though the dispersion is of the order of 0.5 dex) between C and X/O, computed in the hard band, and that 90% of the obscured AGN in the sample with morphological information live in galaxies with regular morphology (bulgy and disky/spiral), suggesting that secular processes govern a significant fraction of the BH growth at X-ray luminosities of 10^43- 10^44.5 erg/s.Comment: 21 pages, 17 figures, 4 tables; accepted for publication in ApJS. The catalog is available at the urls listed in the pape