Research Report - October 2009. Elaboration of the Module: Definition of the Programme

Alternative innovative didactic methodology is needed to reduce premature school drop out,particularly of young people at risk of exclusion, such as migrants, ethnic groups and children/teenagers from difficult socio-economic background). The key point is to modify the way to deliver learning. Cultural enrichment through young interestas such as music and art, use of technologies, social competencies, problem-solving skills incomputer science, autonomy and sense of purpose may help childhood and adolescence to achieve an improved engagement in school and a sense of educational accomplishmen

Characterization of the field saturated hydraulic conductivity on a hillslope: measurement techniques, data sensitivity analysis and spatial correlation modelling

International audienceIn the context of studies aiming at the estimation of effective parameters for unsaturated zone modelling, this work tackles the problem of experimental data quality, considering the large collection of data gathered at an experimental site equipped for unsaturated zone hydraulic monitoring in the alluvial basin of a Calabrian river, in the South of Italy. Focusing attention on field saturated hydraulic conductivity, the in-site measurement techniques by tension disc and pressure ring infiltrometers are considered, pointing out the main indications for the correct use of each measuring approach; laboratory techniques are also considered. Statistical data analysis showed that the measurements performed by tension disc infiltrometer supplied values of hydraulic conductivity which are on average lower and more homogeneous than the values provided by the other measurement techniques considered. Sensitivity analysis was then carried out by Monte Carlo simulation on the parameter sampling achieved by field measurement techniques in order to evaluate the influence of any possible small measurement errors on the data. Sensitivity analysis showed that both ring and disc infiltrometer are tools reliable enough for the in situ measurements of field saturated hydraulic conductivity. Finally, after a data merging procedure giving origin to different sets of data, the spatial correlation structure of field saturated hydraulic conductivity is investigated, using well-known geostatistical techniques

Comparison of three measurement methods of saturated hydraulic condutivity

International audienceAfter pointing out the importance of the saturated hydraulic conductivity (ks) measurements and the difficulties and uncertainties that are present, and after recalling salient aspects of three well-known measurement methods of this parameter (i.e. constant-head tension infiltrometer (TI) method, constant-head pressure infiltrometer (PI) method and soil core (SC) estimates method), the results of an investigation on data which were obtained during a measurement campaign on an area of 800 m2, on a sandy loam hillslope, located in Southern Italy, were carried out again here. Three sets of values of ks, obtained with these measurement methods, were analyzed statistically, verifying that the log-normal distribution describes these better than the normal one; moreover, the more significant statistical parameters of each set were compared (average value , amplitude A, coefficient of variation CV and standard deviation SD), individualizing the more significant differences. The greatest value of hydraulic conductivity was found with method (PI), while the smallest with (SC) and the intermediate with (TI); these differences were translated into macroporosity and into the influence of the single measurement method. Moreover, referring to the possible factors affecting the results, the importance can be noted of the structure, the texture and the soil events, in terms of utilization, which can affect the measure of ks leading often to very different values even for similar soils, but with a different history, independently of the coincidence of the measurement points and they can be determining to explain the differences affecting the results obtained in analogous investigations by other researchers. Having confirmed that generalization is not possible, the need was emphasized to adopt the necessary devices relating to the specific measurement method, case by case, and to carefully explain the obtained results, in the light of the peculiarities and the limits of each situation. Finally, the results of similar statistical analysis carried out on a greater number of ks values, measured through the (TI) and (PI) methods are shown in this paper, with some statistical considerations on the increasing of the measurements number

Continuum and atomistic description of excess electrons in TiO2

The modelling of an excess electron in a semiconductor in a prototypical dye sensitised solar cell is carried out using two complementary approaches: atomistic simulation of the TiO2 nanoparticle surface is complemented by a dielectric continuum model of the solvent–semiconductor interface. The two methods are employed to characterise the bound (excitonic) states formed by the interaction of the electron in the semiconductor with a positive charge opposite the interface. Density-functional theory (DFT) calculations show that the excess electron in TiO2 in the presence of a counterion is not fully localised but extends laterally over a large region, larger than system sizes accessible to DFT calculations. The numerical description of the excess electron at the semiconductor–electrolyte interface based on the continuum model shows that the exciton is also delocalised over a large area: the exciton radius can have values from tens to hundreds of Ångströms, depending on the nature of the semiconductor (characterised by the dielectric constant and the electron effective mass in our model)

One-loop f(R) Gravitational Modified Models

The one-loop quantisation of a general class of modified gravity models around a classical de Sitter background is presented. Application to the stability of the models is addressed.Comment: Latex, 8 pages, no figures. To appear in Journal of Physics A. Two references adde

Two-level system with a thermally fluctuating transfer matrix element: Application to the problem of DNA charge transfer

Charge transfer along the base-pair stack in DNA is modeled in terms of thermally-assisted tunneling between adjacent base pairs. Central to our approach is the notion that tunneling between fluctuating pairs is rate-limited by the requirement of their optimal alignment. We focus on this aspect of the process by modeling two adjacent base pairs in terms of a classical damped oscillator subject to thermal fluctuations as described by a Fokker-Planck equation. We find that the process is characterized by two time scales, a result that is in accord with experimental findings.Comment: original file is revtex4, 10 pages, three eps figure

The Adiabatic Instability on Cosmology's Dark Side

We consider theories with a nontrivial coupling between the matter and dark energy sectors. We describe a small scale instability that can occur in such models when the coupling is strong compared to gravity, generalizing and correcting earlier treatments. The instability is characterized by a negative sound speed squared of an effective coupled dark matter/dark energy fluid. Our results are general, and applicable to a wide class of coupled models and provide a powerful, redshift-dependent tool, complementary to other constraints, with which to rule many of them out. A detailed analysis and applications to a range of models are presented in a longer companion paper.Comment: 4 pages, 1 figur

Observational signatures of Jordan-Brans-Dicke theories of gravity

We analyze the Jordan-Brans-Dicke model (JBD) of gravity, where deviations from General Relativity (GR) are described by a scalar field non-minimally coupled to gravity. The theory is characterized by a constant coupling parameter, $\omega_{\rm JBD}$; GR is recovered in the limit $\omega_{\rm JBD} \to \infty$. In such theories, gravity modifications manifest at early times, so that one cannot rely on the usual approach of looking for inconsistencies in the expansion history and perturbations growth in order to discriminate between JBD and GR. However, we show that a similar technique can be successfully applied to early and late times observables instead. Cosmological parameters inferred extrapolating early-time observations to the present will match those recovered from direct late-time observations only if the correct gravity theory is used. We use the primary CMB, as will be seen by the Planck satellite, as the early-time observable; and forthcoming and planned Supernov{\ae}, Baryonic Acoustic Oscillations and Weak Lensing experiments as late-time observables. We find that detection of values of $\omega_{\rm JBD}$ as large as 500 and 1000 is within reach of the upcoming (2010) and next-generation (2020) experiments, respectively.Comment: minor revision, references added, matching version published in JCA

Secondary Sex Ratio among Women Exposed to Diethylstilbestrol in Utero

BACKGROUND. Diethylstilbestrol (DES), a synthetic estrogen widely prescribed to pregnant women during the mid-1900s, is a potent endocrine disruptor. Previous studies have suggested an association between endocrine-disrupting compounds and secondary sex ratio. METHODS. Data were provided by women participating in the National Cancer Institute (NCI) DES Combined Cohort Study. We used generalized estimating equations to estimate odds ratios (ORs) and 95% confidence intervals (CIs) for the relation of in utero DES exposure to sex ratio (proportion of male births). Models were adjusted for maternal age, child's birth year, parity, and cohort, and accounted for clustering among women with multiple pregnancies. RESULTS. The OR for having a male birth comparing DES-exposed to unexposed women was 1.05 (95% CI, 0.95-1.17). For exposed women with complete data on cumulative DES dose and timing (33%), those first exposed to DES earlier in gestation and to higher doses had the highest odds of having a male birth. The ORs were 0.91 (95% C, 0.65-1.27) for first exposure at ≥ 13 weeks gestation to < 5 g DES; 0.95 (95% CI, 0.71-1.27) for first exposure at ≥ 13 weeks to ≥ 5 g; 1.16 (95% CI, 0.96-1.41) for first exposure at < 13 weeks to < 5 g; and 1.24 (95% CI, 1.04-1.48) for first exposure at < 13 weeks to ≥ 5 g compared with no exposure. Results did not vary appreciably by maternal age, parity, cohort, or infertility history. CONCLUSIONS. Overall, no association was observed between in utero DES exposure and secondary sex ratio, but a significant increase in the proportion of male births was found among women first exposed to DES earlier in gestation and to a higher cumulative dose.National Cancer Institute (N01-CP-21168, N01-CP-51017, N01-CP-01289

Acceleration of the universe in the Einstein frame of a metric-affine f(R) gravity

We show that inflation and current cosmic acceleration can be generated by a metric-affine f(R) gravity formulated in the Einstein conformal frame, if the gravitational Lagrangian L(R) contains both positive and negative powers of the curvature scalar R. In this frame, we give the equations for the expansion of the homogeneous and isotropic matter-dominated universe in the case L(R)=R+{R^3}/{\beta^2}-{\alpha^2}/{3R}, where \alpha and \beta are constants. We also show that gravitational effects of matter in such a universe at very late stages of its expansion are weakened by a factor that tends to 3/4, and the energy density of matter \epsilon scales the same way as in the \Lambda-CDM model only when \kappa*\epsilon<<\alpha.Comment: 12 pages; published versio