1,839 research outputs found

    The Effect of Mentoring on Interns in a Cross-Cultural Setting to Produce Incrteased Missional Engagement

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    the purpose of writing The Effect of Mentoring on Interns in a Cross- Cultural Setting to Produce Increased Missional Engagement is to examine the relationship between mentoring and mission. this is accomplished through interviewing interns who have served with c&Ma/Envision in a cross-cultural setting for a minimum of two months. for a minimum of 45 minutes, 17 interns were interviewed, and the results show a strong correlation between high mentoring and high missional engagement

    Experimental realization of catalytic CH_4 hydroxylation predicted for an iridium NNC pincer complex, demonstrating thermal, protic, and oxidant stability

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    A discrete, air, protic, and thermally stable (NNC)Ir(III) pincer complex was synthesized that catalytically activates the CH bond of methane in trifluoroacetic acid; functionalization using NaIO_4 and KIO_3 gives the oxy-ester

    Down but not out: properties of the molecular gas in the stripped Virgo Cluster early-type galaxy NGC4526

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    We present ALMA data on the 3mm continuum emission, CO isotopologues (12CO, 13CO, C18O), and high-density molecular tracers (HCN, HCO+, HNC, HNCO, CS, CN, and CH3OH) in NGC4526. These data enable a detailed study of the physical properties of the molecular gas in a longtime resident of the Virgo Cluster; comparisons to more commonly-studied spiral galaxies offer intriguing hints into the processing of molecular gas in the cluster environment. Many molecular line ratios in NGC4526, along with our inferred abundances and CO/H2 conversion factors, are similar to those found in nearby spirals. One striking exception is the very low observed 12CO/13CO(1-0) line ratio, 3.4±0.33.4\pm0.3, which is unusually low for spirals though not for Virgo Cluster early-type galaxies. We carry out radiative transfer modeling of the CO isotopologues with some archival (2-1) data, and we use Bayesian analysis with Markov chain Monte Carlo techniques to infer the physical properties of the CO-emitting gas. We find surprisingly low [12CO/13CO] abundance ratios of 7.81.5+2.77.8^{+2.7}_{-1.5} and 6.51.3+3.06.5^{+3.0}_{-1.3} at radii of 0.4 kpc and 1 kpc. The emission from the high-density tracers HCN, HCO+, HNC, CS and CN is also relatively bright, and CN is unusually optically thick in the inner parts of NGC4526. These features hint that processing in the cluster environment may have removed much of the galaxy's relatively diffuse, optically thinner molecular gas along with its atomic gas. Angular momentum transfer to the surrounding intracluster medium may also have caused contraction of the disk, magnifying radial gradients such as we find in [13CO/C18O]. More detailed chemical evolution modeling would be interesting in order to explore whether the unusual [12CO/13CO] abundance ratio is entirely an environmental effect or whether it also reflects the relatively old stellar population in this early-type galaxy.Comment: Submitted to ApJ. Comments are welcome

    Quantifying Activity Levels After Sport-Related Concussion Using Actigraph and Mobile (mHealth) Technologies

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    Context Interest in identifying the effects of physical and mental activity on recovery after sport-related concussion is growing. Clinical studies of concussed athletes\u27 activities require well-validated methods for tracking their intensity and timing. Objective To develop and validate a novel multimodal approach to monitoring activity postconcussion using mobile (mHealth) technologies. Design Cohort study. Setting Translational research unit. Patients or Other Participants A total of 40 high school and collegiate football players were evaluated at preseason and followed longitudinally after either concussion (n = 25; age = 17.88 ± 1.74 years, height = 182.07 ± 8.08 cm, mass = 98.36 ± 21.70 kg) or selection as a nonconcussed control (n = 15; age = 18.27 ± 1.83 years, height = 180.01 ± 7.19 cm, mass = 93.83 ± 24.56 kg). Main Outcome Measure(s) Participants wore a commercial actigraph and completed a daily mobile survey for 2 weeks. Analyses focused on comparisons between groups for actigraph-based physical activity and self-reported physical and mental activity during the follow-up period. Results For the first 2 days postinjury, objective measures showed fewer daily steps in concussed (6663 ± 2667 steps) than in control (11 148 ± 3381 steps) athletes (P \u3c .001), and both objective and self-reported measures indicated less moderate to vigorous physical activity in concussed (27.6 ± 32.6 min/d and 25.0 ± 43.6 min/d, respectively) than in control (57.3 ± 38.6 min/d and 67.5 ± 40.1 min/d, respectively) athletes (both P values \u3c .05). Correlations between objective and self-reported measures of moderate to vigorous physical activity were moderate across select 1-week and 2-week averages. We observed no group differences in self-reported mental activities. Conclusions Physical activity after sport-related concussion varied widely across athletes but on average was reduced during the acute and early subacute postinjury periods for both objective and self-reported measures. The lack of differences in mental activities between groups may reflect limited change in mental exertion postconcussion or difficulty accurately measuring mental activities. Assessing concussed athletes\u27 activities using actigraphy and self-reported scales may help monitor their compliance with activity recommendations and be useful in studies aimed at better understanding the effects of physical activity on concussion recovery

    The Association Between Persistent White-Matter Abnormalities and Repeat Injury After Sport-Related Concussion

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    Objective: A recent systematic review determined that the physiological effects of concussion may persist beyond clinical recovery. Preclinical models suggest that ongoing physiological effects are accompanied by increased cerebral vulnerability that is associated with risk for subsequent, more severe injury. This study examined the association between signal alterations on diffusion tensor imaging following clinical recovery of sport-related concussion in athletes with and without a subsequent second concussion. Methods: Average mean diffusivity (MD) was calculated in a region of interest (ROI) in which concussed athletes (n = 82) showed significantly elevated MD acutely after injury (<48 h), at an asymptomatic time point, 7 days post-return to play (RTP), and 6 months relative to controls (n = 69). The relationship between MD in the identified ROI and likelihood of sustaining a subsequent concussion over a 1-year period was examined with a binary logistic regression (re-injured, yes/no). Results: Eleven of 82 concussed athletes (13.4%) sustained a second concussion within 12 months of initial injury. Mean MD at 7 days post-RTP was significantly higher in those athletes who went on to sustain a repeat concussion within 1 year of initial injury than those who did not (p = 0.048; d = 0.75). In this underpowered sample, the relationship between MD at 7 days post-RTP and likelihood of sustaining a secondary injury approached significance [χ2 (1) = 4.17, p = 0.057; B = 0.03, SE = 0.017; OR = 1.03, CI = 0.99, 1.07]. Conclusions: These preliminary findings raise the hypothesis that persistent signal abnormalities in diffusion imaging metrics at RTP following concussion may be predictive of a repeat concussion. This may reflect a window of cerebral vulnerability or increased susceptibility following concussion, though understanding the clinical significance of these findings requires further study

    Surface oxidation of liquid Sn

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    We report the results of an x-ray scattering study that reveals oxidation kinetics and formation of a previously unreported crystalline phase of SnO at the liquid-vapour interface of Sn. Our experiments reveal that the pure liquid Sn surface does not react with molecular oxygen below an activation pressure of \~5.0*10-6 Torr. Above that pressure a rough solid Sn oxide grows over the liquid metal surface. Once the activation pressure has been exceeded the oxidation proceeds at pressures below the oxidation pressure threshold. The observed diffraction pattern associated with the surface oxidation does not match any of the known Sn oxide phases. The data have an explicit signature of the face-centred cubic structure, however it requires lattice parameters that are about 9% smaller than those reported for cubic structures of high-pressure phases of Sn oxides. Keywords: X-ray scattering, diffraction, and reflection; Oxidation; Surface chemical reaction; Surface structure, morphology, roughness, and topography; Tin; Tin oxides; Liquid surfaces; Polycrystalline thin filmsComment: 18 pages, 6 figures, 1 table; Submitted to Surface Scienc
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