1,097 research outputs found
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Double layer charging driven carbon dioxide adsorption limits the rate of electrochemical carbon dioxide reduction on Gold.
Electrochemical CO[Formula: see text] reduction is a potential route to the sustainable production of valuable fuels and chemicals. Here, we perform CO[Formula: see text] reduction experiments on Gold at neutral to acidic pH values to elucidate the long-standing controversy surrounding the rate-limiting step. We find the CO production rate to be invariant with pH on a Standard Hydrogen Electrode scale and conclude that it is limited by the CO[Formula: see text] adsorption step. We present a new multi-scale modeling scheme that integrates ab initio reaction kinetics with mass transport simulations, explicitly considering the charged electric double layer. The model reproduces the experimental CO polarization curve and reveals the rate-limiting step to be *COOH to *CO at low overpotentials, CO[Formula: see text] adsorption at intermediate ones, and CO[Formula: see text] mass transport at high overpotentials. Finally, we show the Tafel slope to arise from the electrostatic interaction between the dipole of *CO[Formula: see text] and the interfacial field. This work highlights the importance of surface charging for electrochemical kinetics and mass transport
The Minimal Phantom Sector of the Standard Model: Higgs Phenomenology and Dirac Leptogenesis
We propose the minimal, lepton-number conserving, SU(3)xSU(2)xU(1)
gauge-singlet, or phantom, extension of the Standard Model. The extension is
natural in the sense that all couplings are of O(1) or forbidden due to a
phantom sector global U(1)_D symmetry, and basically imitates the standard
Majorana see-saw mechanism. Spontaneous breaking of the U(1)_D symmetry
triggers consistent electroweak gauge symmetry breaking only if it occurs at a
scale compatible with small Dirac neutrino masses and baryogenesis through
Dirac leptogenesis. Dirac leptogenesis proceeds through the usual
out-of-equilibrium decay scenario, leading to left and right-handed neutrino
asymmetries that do not fully equilibrate after they are produced. The model
contains two physical Higgs bosons and a massless Goldstone boson. The
existence of the Goldstone boson suppresses the Higgs to bb branching ratio and
instead the Higgs bosons will mainly decay to invisible Goldstone and/or to
visible vector boson pairs. In a representative scenario, we estimate that with
30 fb^-1 integrated luminosity, the LHC could discover this invisibly decaying
Higgs, with mass ~120 GeV. At the same time a significantly heavier, partner
Higgs boson with mass ~210 GeV could be found through its vector boson decays.
Electroweak constraints as well as astrophysical and cosmological implications
are analysed and discussed.Comment: 21 pages, 4 figures. Corrected typos and added references. To appear
in JHE
Measurement of Analyzing Power for Proton-Carbon Elastic Scattering in the Coulomb-Nuclear Interference Region with a 22-GeV/c Polarized Proton Beam
The analyzing power for proton-carbon elastic scattering in the
coulomb-nuclear interference region of momentum transfer,
(GeV/, was measured with a 21.7
GeV/ polarized proton beam at the Alternating Gradient Synchrotron of
Brookhaven National Laboratory. The ratio of hadronic spin-flip to non-flip
amplitude, , was obtained from the analyzing power to be and .Comment: 4 pages, 4 figures and 1 table. Accepted by Physical Review Letter
Variational Mass Perturbation Theory for Light-Front Bound-State Equations
We investigate the mesonic light-front bound-state equations of the 't Hooft
and Schwinger model in the two-particle, i.e. valence sector, for small fermion
mass. We perform a high precision determination of the mass and light-cone wave
function of the lowest lying meson by combining fermion mass perturbation
theory with a variational approach. All calculations are done entirely in the
fermionic representation without using any bosonization scheme. In a
step-by-step procedure we enlarge the space of variational parameters. For the
first two steps, the results are obtained analytically. Beyond that we use
computer algebraic and numerical methods. We achieve good convergence so that
the calculation of the meson mass squared can be extended to third order in the
fermion mass. Within the numerical treatment we include higher Fock states up
to six particles. Our results are consistent with all previous numerical
investigations, in particular lattice calculations. For the massive Schwinger
model, we find a small discrepancy (less than 2 percent) in comparison with
known bosonization results. Possible resolutions of this discrepancy are
discussed.Comment: some points clarified, representation straightened, to appear in
Phys. Rev. D, 31 pages, Latex, REVTeX, epsfig, 3 postscript figures include
A novel satellite mission concept for upper air water vapour, aerosol and cloud observations using integrated path differential absorption LiDAR limb sounding
We propose a new satellite mission to deliver high quality measurements of upper air water vapour. The concept centres around a LiDAR in limb sounding by occultation geometry, designed to operate as a very long path system for differential absorption measurements. We present a preliminary performance analysis with a system sized to send 75 mJ pulses at 25 Hz at four wavelengths close to 935 nm, to up to 5 microsatellites in a counter-rotating orbit, carrying retroreflectors characterized by a reflected beam divergence of roughly twice the emitted laser beam divergence of 15 µrad. This provides water vapour profiles with a vertical sampling of 110 m; preliminary calculations suggest that the system could detect concentrations of less than 5 ppm. A secondary payload of a fairly conventional medium resolution multispectral radiometer allows wide-swath cloud and aerosol imaging. The total weight and power of the system are estimated at 3 tons and 2,700 W respectively. This novel concept presents significant challenges, including the performance of the lasers in space, the tracking between the main spacecraft and the retroreflectors, the refractive effects of turbulence, and the design of the telescopes to achieve a high signal-to-noise ratio for the high precision measurements. The mission concept was conceived at the Alpbach Summer School 2010
Search for rare and forbidden decays of charm and charmed-strange mesons to final states h^+- e^-+ e^+
We have searched for flavor-changing neutral current decays and
lepton-number-violating decays of D^+ and D^+_s mesons to final states of the
form h^+- e^-+ e^+, where h is either \pi or K. We use the complete samples of
CLEO-c open-charm data, corresponding to integrated luminosities of 818 pb^-1
at the center-of-mass energy E_CM = 3.774 GeV containing 2.4 x 10^6 D^+D^-
pairs and 602 pb^-1 at E_CM = 4.170 GeV containing 0.6 x 10^6 D^*+-_s D^-+_s
pairs. No signal is observed in any channel, and we obtain 90% confidence level
upper limits on branching fractions B(D^+ --> \pi^+ e^+ e^-) < 5.9 x 10^-6,
B(D^+ --> \pi^- e^+ e^+) K^+ e^+ e^-) < 3.0 x 10^-6,
B(D^+ --> K^- e^+ e^+) \pi^+ e^+ e^-) < 2.2 x 10^-5,
B(D^+_s --> \pi^- e^+ e^+) K^+ e^+ e^-) < 5.2 x
10^-5, and B(D^+_s --> K^- e^+ e^+) < 1.7 x 10^-5.Comment: 9 pages, available through http://www.lns.cornell.edu/public/CLNS
The Majorana experiment: an ultra-low background search for neutrinoless double-beta decay
The observation of neutrinoless double-beta decay would resolve the Majorana
nature of the neutrino and could provide information on the absolute scale of
the neutrino mass. The initial phase of the Majorana experiment, known as the
Demonstrator, will house 40 kg of Ge in an ultra-low background shielded
environment at the 4850' level of the Sanford Underground Laboratory in Lead,
SD. The objective of the Demonstrator is to determine whether a future 1-tonne
experiment can achieve a background goal of one count per tonne-year in a
narrow region of interest around the 76Ge neutrinoless double-beta decay peak.Comment: Presentation for the Rutherford Centennial Conference on Nuclear
Physic
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Measurement of the underground atmospheric muon charge ratio using the MINOS Near Detector
The magnetized MINOS Near Detector, at a depth of 225 mwe, is used to measure the atmospheric muon charge ratio. The ratio of observed positive to negative atmospheric muon rates, using 301 days of data, is measured to be 1.266±0.001(stat)_(-0.014)^(+0.015)(syst). This measurement is consistent with previous results from other shallow underground detectors and is 0.108±0.019(stat+syst) lower than the measurement at the functionally identical MINOS Far Detector at a depth of 2070 mwe. This increase in charge ratio as a function of depth is consistent with an increase in the fraction of muons arising from kaon decay for increasing muon surface energie
The MAJORANA DEMONSTRATOR: A Search for Neutrinoless Double-beta Decay of Germanium-76
The observation of neutrinoless double-beta decay would determine whether the
neutrino is a Majorana particle and provide information on the absolute scale
of neutrino mass. The MAJORANA Collaboration is constructing the DEMONSTRATOR,
an array of germanium detectors, to search for neutrinoless double-beta decay
of 76-Ge. The DEMONSTRATOR will contain 40 kg of germanium; up to 30 kg will be
enriched to 86% in 76-Ge. The DEMONSTRATOR will be deployed deep underground in
an ultra-low-background shielded environment. Operation of the DEMONSTRATOR
aims to determine whether a future tonne-scale germanium experiment can achieve
a background goal of one count per tonne-year in a 4-keV region of interest
around the 76-Ge neutrinoless double-beta decay Q-value of 2039 keV.Comment: Submitted to AIP Conference Proceedings, 19th Particles & Nuclei
International Conference (PANIC 2011), Massachusetts Institute of Technology,
Cambridge, MA, USA, July 24-29, 2011; 3 pages, 1 figur
Higher-order multipole amplitudes in charmonium radiative transitions
Using 24 million decays in CLEO-c, we have searched
for higher multipole admixtures in electric-dipole-dominated radiative
transitions in charmonia. We find good agreement between our data and
theoretical predictions for magnetic quadrupole (M2) amplitudes in the
transitions and ,
in striking contrast to some previous measurements. Let and
denote the normalized M2 amplitudes in the respective aforementioned decays,
where the superscript refers to the angular momentum of the . By
performing unbinned maximum likelihood fits to full five-parameter angular
distributions, we determine the ratios and , where
the theoretical predictions are independent of the charmed quark magnetic
moment and are and .Comment: 32 pages, 7 figures, acceptance updat
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