Primary arm spacing in chill block melt spun Ni-Mo alloys

Chill block melt spun ribbons of Ni-Mo binary alloys containing 8.0 to 41.8 wt % Mo have been prepared under carefully controlled processing conditions. The growth velocity has been determined as a function of distance from the quench surface from the observed ribbon thickness dependence on the melt puddle residence time. Primary arm spacings measured at the midribbon thickness locations show a dependence on growth velocity and alloy composition which is expected from dendritic growth models for binary alloys directionally solidified in a positive temperature gradient

Angle-resolved photoemission spectra in the cuprates from the d-density wave theory

Angle-resolved photoemission spectra present two challenges for the d-density wave (DDW) theory of the pseudogap state of the cuprates: (1) hole pockets near $(\pi/2,\pi/2)$ are not observed, in apparent contradiction with the assumption of translational symmetry breaking, and (2) there are no well-defined quasiparticles at the {\it antinodal} points, in contradiction with the predictions of mean-field theory of this broken symmetry state. Here, we show how these puzzles can be resolved.Comment: 4 pages, 3 eps figures, RevTex

Dissipate locally, couple globally: a sharp transition from decoupling to infinite range coupling in Josephson arrays with on-site dissipation

We study the T=0 normal to superconducting transition of Josephson arrays with {\it on-site} dissipation. A perturbative renormalization group solution is given. Like the previously studied case of {\it bond} dissipation (BD), this is a "floating" to coupled (FC) phase transition. {\it Unlike} the BD transition, at which {\it only} nearest-neighbor couplings become relevant, here {\it all} inter-grain couplings, out to {\it infinitely} large distances, do so simultaneously. We predict, for the first time in an FC transition, a diverging spatial correlation length. Our results show the robustness of floating phases in dissipative quantum systems.Comment: 7+ pages, 3 eps figures, Europhysics Letters preprint format, as publishe

Microstructures in rapidly solidified Ni-Mo alloys

Ni-Mo alloys of compositions ranging from pure Ni to Ni-40 at % Mo were rapidly solidified by Chill Block Melt Spinning in vacuum and were examined by optical metallography, X-ray diffraction and transmission electron microscopy. Rapid solidification resulted in an extension of molybdenum solubility in nickel from 28 to 37.5 at %. A number of different phases and microstructures were seen at different depths (solidification conditions) from the quenched surface of the melt spun ribbons

The nature and boundary of the floating phase in a dissipative Josephson junction array

We study the nature of correlations within, and the transition into, the floating phase of dissipative Josephson junction arrays. Order parameter correlations in this phase are long-ranged in time, but only short-ranged in space. A perturbative RG analysis shows that, in {\it arbitrary} spatial dimension, the transition is controlled by a continuous locus of critical fixed points determined entirely by the \textit{local} topology of the lattice. This may be the most natural example of a line of critical points existing in arbitrary dimensions.Comment: Parts rewritten, typos correcte

Synthesis of Some New 2,4,6-Triarylsubstituted Pyridines via Pyridinium Ylides

Some new 2,4,6-triarylsubstituted pyridines, which are expected to possess marked biological activities we~e synthesized via 4- -methylphenacylpyridinium ylide and 4-chlorophenacylpyridinium ylide. Ammonium acetate in acetic acid was used as the cyclization agent. The structures of the products were confirmed either by NMR or by IR spectrum analysis

A Socio-Clinical Profile Of Cases Of Laparoscopic Sterilization Performed At Institution And Camps

Research Question: What is the socio-clinical profile of cases of laparoscopic sterilization performed at the insti­tution and camps. Objectives: To study the (1) socio-clinical aspect of laparoscopic ligations. (2) complications and the failure rate. Study Design: Longitudinal study. Setting: Females coming for sterilization at the O-.P.D. and post-partum centre. Participants: 9088 females of reproductive age group. Study Variables: Age group, social class, residence, education, number of living children. Outcome Variables: Proportion of women who came for sterilization, ligations performed at hospital. Results: Demographic characteristics showed that 5658 (62.2%) and 3430 (37.8%) were from rural and urban areas respectively. Socio-economically , 80% cases be­longed to low socio-enonomic class. As regards the literacy status, 5500 (60.5%) of the patients were illiterate and 2600 (28.6%) of them had received only primary education. The age group which commonly accepted sterilization in 5056 cases (55.6%) was 31-35 years. The parity in our study showing highest incidence of laparoligation. i.e. 36.17% was 5. Our complication rate was 0.5% and failure rate 0.6%. Conclusions: Our experience of about 15 years shows that laparoscopic sterilization is a simple, safe, easy method and acceptable to the rural and even illiterate masses in this region. In the event of pregnancy, this permanent method is more acceptabl

Undercooled and rapidly quenched Ni-Mo alloys

Hypoeutectic, eutectic, and hypereutectic nickel-molybdenum alloys were rapidly solidified by both bulk undercooling and melt spinning techniques. Alloys were undercooled in both electromagnetic levitation and differential thermal analysis equipment. The rate of recalescence depended upon the degree of initial undercooling and the nature (faceted or nonfaceted) of the primary nucleating phase. Alloy melts were observed to undercool more in the presence of primary Beta (NiMo intermetallic) phase than in gamma (fcc solid solution) phase. Melt spinning resulted in an extension of molybdenum solid solubility in gamma nickel, from 28 to 37.5 at % Mo. Although the microstructures observed by undercooling and melt spinning were similar the microsegregation pattern across the gamma dendries was different. The range of microstructures evolved was analyzed in terms of the nature of the primary phase to nucleate, its subsequent dendritic growth, coarsening and fragmentation, and final solidification of interfenderitic liquid

Effect of Cross-Section-Change Induced Advective Flow on the Primary Dendrite Array Morphology of Hypoeutectic Pb-Sb Alloys During Directional Solidification

The morphology and distribution of primary dendrites have been examined in Pb-2.2, 5.8 and 10.8 wt. pct. Sb alloy samples directionally solidified (DSed) in ampoules shaped like an hour-glass to examine the influence of cross-section change induced advective flow on the cellular/dendritic interface. This sample design increases the advective flow of the melt towards the array tips, as the liquid-solid interface enters the neck of the ampoule, and then decreases it as the interface exits the neck. The warm solute-rich melt flowing towards the growth front suppresses the extent of side-branching, decreases the primary dendrite spacing, and increases the primary dendrite trunk diameter as observed in the Pb-5.8 and 10.8 Sb alloys. The flow appears to suppress the formation of cells. A cellular interface growing in the Pb-2.2Sb alloy became planar as the solidification front entered the neck, becoming cellular again as it exited the neck

The Plasmodium berghei Ca(2+)/H(+) exchanger, PbCAX, is essential for tolerance to environmental Ca(2+) during sexual development.

Ca(2+) contributes to a myriad of important cellular processes in all organisms, including the apicomplexans, Plasmodium and Toxoplasma. Due to its varied and essential roles, free Ca(2+) is tightly regulated by complex mechanisms. These mechanisms are therefore of interest as putative drug targets. One pathway in Ca(2+) homeostatic control in apicomplexans uses a Ca(2+)/H(+) exchanger (a member of the cation exchanger family, CAX). The P. falciparum CAX (PfCAX) has recently been characterised in asexual blood stage parasites. To determine the physiological importance of apicomplexan CAXs, tagging and knock-out strategies were undertaken in the genetically tractable T. gondii and P. berghei parasites. In addition, a yeast heterologous expression system was used to study the function of apicomplexan CAXs. Tagging of T. gondii and P. berghei CAXs (TgCAX and PbCAX) under control of their endogenous promoters could not demonstrate measureable expression of either CAX in tachyzoites and asexual blood stages, respectively. These results were consistent with the ability of parasites to tolerate knock-outs of the genes for TgCAX and PbCAX at these developmental stages. In contrast, PbCAX expression was detectable during sexual stages of development in female gametocytes/gametes, zygotes and ookinetes, where it was dispersed in membranous networks within the cytosol (with minimal mitochondrial localisation). Furthermore, genetically disrupted parasites failed to develop further from "round" form zygotes, suggesting that PbCAX is essential for ookinete development and differentiation. This impeded phenotype could be rescued by removal of extracellular Ca(2+). Therefore, PbCAX provides a mechanism for free living parasites to multiply within the ionic microenvironment of the mosquito midgut. Ca(2+) homeostasis mediated by PbCAX is critical and suggests plasmodial CAXs may be targeted in approaches designed to block parasite transmission