667 research outputs found
Catalytic Effects of Aminated-β-Cyclodextrin Derivatives for the Decarboxylation of Oxalacetate
Efficient microwave-assisted synthetic protocols and in silico behaviour prediction of per-substituted β-cyclodextrins
Doping Dependence of the Chemical Potential in Cuprate High- Superconductors I: LaSrCuO
The names of the authors, which were inadvertedly lacking in the tex-file
submitted two days ago, have been added.Comment: 10 pages, figures on request. Revtex, version 2, Materials Science
Center Internal Report Number VSGD.94.6.
Coherent-incoherent transition in the sub-Ohmic spin-boson model
We study the spin-boson model with a sub-Ohmic bath using a variational
method. The transition from coherent dynamics to incoherent tunneling is found
to be abrupt as a function of the coupling strength and to exist for
any power , where the bath coupling is described by . We find non-monotonic temperature dependence of the
two-level gap and a re-entrance regime close to the transition due
to non-adiabatic low-frequency bath modes. Differences between thermodynamic
and dynamic conditions for the transition as well as the limitations of the
simplified bath description are discussed.Comment: 12 pages, 4 figure
Environmental dependence of 8 μm luminosity functions of galaxies at z ~ 0.8: Comparison between RXJ1716.4+6708 and the AKARI NEP-deep field
Aims. We aim to reveal environmental dependence of infrared luminosity functions (IR LFs) of galaxies at z ~ 0.8 using the AKARI
satellite. AKARI’s wide field of view and unique mid-IR filters help us to construct restframe 8 μm LFs directly without relying on
SED models.
Methods. We construct restframe 8 μm IR LFs in the cluster region RXJ1716.4+6708 at z = 0.81, and compare them with a blank
field using the AKARI north ecliptic pole deep field data at the same redshift. AKARI’s wide field of view (10' × 10') is suitable to
investigate wide range of galaxy environments. AKARI’s 15 μm filter is advantageous here since it directly probes restframe 8 μm at
z ~ 0.8, without relying on a large extrapolation based on a SED fit, which was the largest uncertainty in previous work.
Results. We have found that cluster IR LFs at restframe 8 μm have a factor of 2.4 smaller L^∗ and a steeper faint-end slope than that
of the field. Confirming this trend, we also found that faint-end slopes of the cluster LFs becomes flatter and flatter with decreasing
local galaxy density. These changes in LFs cannot be explained by a simple infall of field galaxy population into a cluster. Physics
that can preferentially suppress IR luminous galaxies in high density regions is required to explain the observed results
Van Hove Excitons and High-T Superconductivity: VIIIC Dynamic Jahn-Teller Effects vs Spin-Orbit Coupling in the LTO Phase of LaSrCuO
The possible role of the van Hove singularity (vHs) in stabilizing the
low-temperature orthorhombic (LTO) phase transition in
La\-Sr\-CuO (LSCO) is discussed. It is found that the vHs can
drive a structural distortion in two different ways, either due to spin-orbit
coupling or to dynamic Jahn-Teller (JT) effects. This paper discusses the
latter effect in some detail. It is shown that a model Hamiltonian introduced
earlier to describe the coupled electron -- octahedral tilt motions (`cageons')
has a series of phase transitions, from a high-temperature disordered JT phase
(similar to the high-temperature tetragonal phase of LSCO) to an intermediate
temperature dynamic JT phase, of average orthorhombic symmetry (the LTO phase)
to a low temperature static JT phase (the low temperature tetragonal phase).
For some parameter values, the static JT phase is absent.Comment: 28 pages plain TeX, 14 figures available upon request,
NU-MARKIEWIC-93-0
Re-weighting of somatosensory inputs from the foot and the ankle for controlling posture during quiet standing following trunk extensor muscles fatigue
The present study focused on the effects of trunk extensor muscles fatigue on
postural control during quiet standing under different somatosensory conditions
from the foot and the ankle. With this aim, 20 young healthy adults were asked
to stand as immobile as possible in two conditions of No fatigue and Fatigue of
trunk extensor muscles. In Experiment 1 (n = 10), somatosensation from the foot
and the ankle was degraded by standing on a foam surface. In Experiment 2 (n =
10), somatosensation from the foot and ankle was facilitated through the
increased cutaneous feedback at the foot and ankle provided by strips of
athletic tape applied across both ankle joints. The centre of foot pressure
displacements (CoP) were recorded using a force platform. The results showed
that (1) trunk extensor muscles fatigue increased CoP displacements under
normal somatosensatory conditions (Experiment 1 and Experiment 2), (2) this
destabilizing effect was exacerbated when somatosensation from the foot and the
ankle was degraded (Experiment 1), and (3) this destabilizing effect was
mitigated when somatosensation from the foot and the ankle was facilitated
(Experiment 2). Altogether, the present findings evidenced re-weighting of
sensory cues for controlling posture during quiet standing following trunk
extensor muscles fatigue by increasing the reliance on the somatosensory inputs
from the foot and the ankle. This could have implications in clinical and
rehabilitative areas
Adenosine-5′-phosphosulfate - a multifaceted modulator of bifunctional 3′-phospho-adenosine-5′-phosphosulfate synthases and related enzymes
All sulfation reactions rely on active sulfate in the form of 3′-phosphoadenosine-5′-phosphosulfate (PAPS). In fungi, bacteria, and plants, the enzymes responsible for PAPS synthesis, ATP sulfurylase and adenosine-5′-phosphosulfate (APS) kinase, reside on separate polypeptide chains. In metazoans, however, bifunctional PAPS synthases catalyze the consecutive steps of sulfate activation by converting sulfate to PAPS via the intermediate APS. This intricate molecule and the related nucleotides PAPS and 3′-phospho-adenosine-5′-phosphate modulate the function of various enzymes from sulfation pathways, and these effects are summarized in this review. On the ATP sulfurylase domain that initially produces APS from sulfate and ATP, APS acts as a potent product inhibitor, being competitive with both ATP and sulfate. For the APS kinase domain that phosphorylates APS to PAPS, APS is an uncompetitive substrate inhibitor that can bind both at the ATP/ADP binding site and the PAPS/APS-binding site. For human PAPS synthase 1, the steady-state concentration of APS has been modelled to be 1.6 lM, but this may increase up to 60 lM under conditions of sulfate excess. It is noteworthy that the APS concentration for maximal APS kinase activity is 15 lM. Finally, we recognized APS as a highly specific stabilizer of bifunctional PAPS synthases. APS most likely stabilizes the APS kinase part of these proteins by forming a dead-end enzyme–ADP–APS complex at APS concentrations between 0.5 and 5 lM; at higher concentrations, APS may bind to the catalytic centers of ATP sulfurylase. Based on the assumption that cellular concentrations of APS fluctuate within this range, APS can therefore be regarded as a key modulator of PAPS synthase functions
Van Hove Exciton-Cageons and High-T Superconductivity: VIIID Solitons and Nonlinear Dynamics
The low-temperature orthorhombic (LTO) phase transition in
LaSrCuO can be interpreted as a dynamic Jahn-Teller effect, in
which the degenerate electronic states are associated with the large densities
of states at the two van Hove singularities. The equations describing this
phase are strongly nonlinear. This paper illustrates some consequences of the
nonlinearity, by presenting a rich variety of exact nonlinear wave solutions
for the model.
Of particular interest are soliton lattice solutions: arrays of domain walls
separating regions of local low-temperature tetragonal (LTT) symmetry. These
arrays have a {\it macroscopic} average symmetry higher than LTT. These
lattices can display either orthorhombic (`orthons') or tetragonal (`tetrons')
symmetry, and can serve as models for a microscopic description of the dynamic
JT LTO and high-temperature tetragonal phases, respectively.Comment: 17 pages plain TeX, 14 figures available upon reques
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