Diagenetic processes in a partially dolomitized carbonate reservoir: Casablanca oil field, Mediterranean Sea, offshore Spain

Mesozoic and Neogene carbonates located in the Valencia Trough (offshore Spain, western Mediterranean Sea) are oil reservoirs. This paper investigates the diagenetic evolution of the Upper Jurassic limestones, currently dolomitized, that constitute the main reservoir of the Casablanca oil field. Core samples from Casablanca-1A well have been studied to determine the diagenetic products and their relation with porosity evolution, and to reconstruct the fluid flow history prior to and during oil emplacement. On the basis of petrological observations and geochemical analyses (major, minor and trace element composition and oxygen, carbon and strontium isotope composition), a major dolomitization event is recognized postdating subaerial exposure, erosion and karstification. The dolomitization event originated two replacive dolomites (RD1 and RD2) and two dolomite cements (saddle dolomite cement, SDC, and milky-white dolomite cement, MDC) which are partially cogenetic. RD1, RD2 and SDC precipitated at increasing temperatures (over 60ºC and below 110ºC), probably from meteoric water mixed with marine water. The last dolomite type (milky-white dolomite cement) precipitated with increasing burial conditions and by arrival of hydrothermal fluids during the Miocene. The post-dolomitization sequence comprises precipitation of calcite cement and partial calcitization of all previous dolomites. The oxygen, carbon and strontium isotope compositions suggest that this calcite cementation occurred from meteoric waters mixed with Burdigalian - Langhian marine waters trapped in the sediments and expelled by compaction in the moderate to deep burial realm. Normal faults were the conduits for upward migration of these fluids as well as for later oil expulsion from the Burdigalian - Langhian source rocks. Late corrosion associated with organic acid-enriched fluids took place prior or simultaneously to oil migration during the Pliocene, enhancing porosity and increasing reservoir quality

Formation of chlorite during thrust fault reactivation. Record of fluid origin and P-T conditions in the Monte Perdido thrust fault (southern Pyrenees)

The chemical and isotopic compositions of clay minerals such as illite and chlorite are commonly used to quantify diagenetic and low-grade metamorphic conditions, an approach that is also used in the present study of the Monte Perdido thrust fault from the South Pyrenean fold-and-thrust belt. The Monte Perdido thrust fault is a shallow thrust juxtaposing upper Cretaceous-Paleocene platform carbonates and Lower Eocene marls and turbidites from the Jaca basin. The core zone of the fault, about 6m thick, consists of intensely deformed clay-bearing rocks bounded by major shear surfaces. Illite and chlorite are the main hydrous minerals in the fault zone. Illite is oriented along cleavage planes while chlorite formed along shear veins (<50μm in thickness). Authigenic chlorite provides essential information about the origin of fluids and their temperature. δ18O and δD values of newly formed chlorite support equilibration with sedimentary interstitial water, directly derived from the local hanging wall and footwall during deformation. Given the absence of large-scale fluid flow, the mineralization observed in the thrust faults records the P-T conditions of thrust activity. Temperatures of chlorite formation of about 240°C are obtained via two independent methods: chlorite compositional thermometers and oxygen isotope fractionation between cogenetic chlorite and quartz. Burial depth conditions of 7km are determined for the Monte Perdido thrust reactivation, coupling calculated temperature and fluid inclusion isochores. The present study demonstrates that both isotopic and thermodynamic methods applied to clay minerals formed in thrust fault are useful to help constrain diagenetic and low-grade metamorphic condition

An extended chronicle discovery approach to find temporal patterns between sequences

Sequences of events describing the behavior and actions of users or systems can be collected in sev eral domains. An episode is a collection of events that occurs relatively close to each other in a given partial order. Also, chronicles are a special type of temporal patterns, where temporal orders of events are quantified with numerical bounds and reflect the temporal evolution of the system over the time. In this paper, the problem of finding rules for de scribing or predicting the behavior of the sequences with the intention of characterizing some interest ing tasks is considered. Obtaining these patterns is the main objective of this work, where an automatic method to learn relevant and discriminating chron icles is proposed. The method extends existing al gorithms that have been proposed to find frequent episodes/chronicles in a single event sequence to the case of multiple sequences.Ministerio de Economía y Competitividad TIN2009-14378-C02-01 (ARTEMISA)Junta de Andalucía TIC-8052 (Simon

Comparación del efecto de la concentración de polvo de neumático reciclado y polímeros en el comportamiento de ligantes para mezclas bituminosas

Crumb rubber modified binders are environmental-friendly alternatives to polymer modified bitumens in asphalt mixtures. This paper compares the performance of both types of binders with different modifier contents. Six binders were characterised by conventional tests and analysed using the UCL method. This method evaluates different properties of binders regarding their role in asphalt mixtures (cohesion, water and thermal sensitivity and resistance to ageing). Results showed that i) crumb rubber concentration has to be higher than that of SBS-polymers in order to obtain a similar performance to that of SBS-polymer modified bitumen; ii) crumb rubber modified binders are more stable than SBS-polymer modified binders in terms of modifier concentration; iii) crumb rubber modified binders exhibited less water sensitivity and similar thermal and ageing susceptibility to SBS-polymer modified binders; iv) linear relationships have been found between modifier concentration and the properties studied for both kind of binders.Los betunes modificados con polvo de neumático (PN) son alternativas ambientalmente sostenibles a los betunes modificados con polímeros. Este artículo compara el comportamiento de ambos tipos de betunes con varios contenidos de modificador. Para ello, se caracterizaron seis betunes mediante ensayos convencionales y método UCL. Este método evalúa propiedades de ligantes para su uso en mezclas bituminosas (cohesión, sensibilidad al agua, térmica y al envejecimiento). Los resultados muestran que i) la concentración de PN ha de ser más elevada que la de polímeros para obtener comportamiento semejante; ii) los betunes con PN son más estables ante cambios en la concentración de modificador que los betunes con polímeros; iii) los betunes con PN presentan menor sensibilidad al agua y equivalente susceptibilidad térmica y al envejecimiento que los betunes con polímeros; iv) se encontraron buenos ajustes lineales entre la concentración de modificadores y la evolución de las propiedades estudiadas

Activation of stylolites as conduits for overpressured fluid flow in dolomitized platform carbonates

This research was developed with funding provided by the Spanish Government I+D+I Research Projects CGL2015-69805-P and CGL2015-66335-C2-1-R, and the Generalitat de Catalunya (2014SGR251). The research also benefited from a grant of the Geological Society of London (Elspeth Matthews Fund 2015) to EGR. The authors would like to thank M. Aston and O. P. Wennberg for the editorial work, and F. Laponi and an anonymous reviewer for their critical and constructive comments.Peer reviewedPostprin

Quantifying deformation processes in the SE Pyrenees using U-Pb dating of fracture-filling calcites

It is difficult to quantify the timing of the deformation processes in brittle fold-thrust belts because minerals suitable for dating and well-preserved growth strata sediments are scarce or absent. Here, we quantify the duration of thrust sheet emplacement and shortening rates in the SE Pyrenean thrust sequence using U-Pb dating of fracture-filling calcites. The obtained U-Pb dates reveal a minimum duration for the emplacement of each thrust unit (18.7 Ma for the Bóixols-Upper Pedraforca, 11.6 Ma for the Lower Pedraforca and 14.3 Ma for the Cadí thrust sheets) and show that piggy-back thrusting was accompanied by post-emplacement deformation of the upper thrust sheets above the lower sheets during their south-directed tectonic transport. We calculated shortening rates of 0.6, 3.1 and 1.1 mm a−1 from the older to younger emplaced thrust sheets. Our results also reveal the formation of local normal faults during the late Oligocene as a result of the late stages of compression and exhumation in the SE Pyrenees. We observed that temperatures >110 °C could be a limiting factor when applying the U-Pb dating method

Fluvial sedimentation and its reservoir potential at foreland basin margins: A case study of the Puig-reig anticline (South-eastern Pyrenees)

Fluvial fans represent one of the dominant sedimentary systems at the active margins of non-marine foreland basins. The Puig-reig anticline at the north-eastern margin of the Ebro Foreland Basin (SE Pyrenees, Spain) exposes continuous outcrops of Late Eocene-Early Oligocene fluvial deposits, from proximal to medial fluvial fan environments. The proximal deposits are found in the north limb of the anticline, especially in the northwest zone. These deposits are characterised by conglomerates with minor interbedded sandstones, with thick and wide sheet-like geometries with unscoured or variably scoured basal surfaces. These are interpreted to be the deposits of unconfined flash floods and wide-shallow channel streams. The medial deposits, covering the rest of the anticline, consist of interbedded conglomerates, sandstones and claystones. These are interpreted to have been deposited from braided to meandering channel streams and overbank areas. Distal deposits are found towards the south, beyond the anticline, and are characterised by sandstone and clay deposits of terminal lobes and lacustrine deltas. This study assesses the impact of the primary depositional characteristics, diagenesis and deformation of the most heterolithic portion of the system, with implications for increasing our understanding of folded fluvial reservoirs. Diagenetic processes, mainly mechanical compaction and calcite cementation, resulted in overall low intergranular porosity, with limited relatively high porosity developed in sandstone lithofacies in the medial deposits. Deformation associated with thrusting and fold growth resulted in the formation of abundant fractures, with relatively high fracture intensities observed in sandstone lithofacies in the anticline crest. This study shows that post-depositional processes can both improve and diminish the reservoir potential of basin proximal fluvial deposits, through the development of fracture networks and by compaction-cementation. The comparison of the Puig-reig anticline with other similar settings worldwide indicates that foreland basin margin locations may be potential areas for effective reservoirs, even in the case of low intergranular porosity

Permian-Triassic red-stained albitized profiles in the granitic basement of the NE Spain: evidence for deep alteration related to the Triassic Palaeosurface

Extensive areas of the Variscan granitic basement in NE Spain display profiles of red-stained albitized facies characterized by albitization of Ca-plagioclase, chloritization of biotite and microclinization of orthoclase, along with the alteration of igneous quartz to secondary CL-dark quartz. These profiles have a geopetal structure beneath the Triassic unconformity, with a very intense and pervasive alteration in the upper part that progressively decreases with depth to 150-200 m where the alteration is restricted to the walls of fractures. The red albitized facies contains secondary maghemite and hematite that indicate oxidizing conditions. Dating of microclinized orthoclase and secondary monazite that have formed in the red-stained albitized facies yielded K-Ar and U-Th-Pbtotal ages of 240 and 250 Ma, respectively, suggesting that the alteration developed during the Permian-Triassic period. The geopetal disposition of the red albitized profile with respect to the Triassic unconformity, its large regional extent, and the fracture-controlled alteration in the lower part of the profile indicate groundwater interaction. The δ18O values of albitized plagioclase (+ 11¿), microclinized orthoclase (+ 13¿), and secondary CL-dark quartz (+ 12¿) suggest that the alteration temperature was about 55 °C. This 'low' temperature suggests that the alteration occurred during interaction of the granitic rocks with Na-rich fluids below a surficial weathering mantle on the Permian-Triassic palaeosurface. The latter is possibly related to Triassic evaporitic environments in long-lasting, stable landscapes in which Na-rich solutions infiltrated deep regional groundwaters