6 research outputs found
Analysis of organic compounds in Mars soil analog samples using SuperCam-Raman of Mars2020
One of the main objectives of the Perseverance rover is to find signs of ancient life in the Martian surface, seeking biosignatures and signs of past habitable conditions. This could be achieved with the finding of organic compounds related to life. Raman spectroscopy is among the techniques that the rover is capable of performing, which is able to detect and discern organic molecules. Perseverance carries in its payload two instruments that are able to use this technique, SuperCam for remote sensing and SHERLOC for proximity measurements. SuperCam is a long-distance instrument capable of performing several techniques (Raman, LIBS, luminescence, VISIR, microphone) in order to assess the chemical and molecular composition of rocks (mineral phases and organic molecules) from a distance up to 7 m. Therefore, it could detect organics, or traces of them, from a distance before the rover gets closer.In this work, a set of Mars soil analog samples were analyzed using the Flying Model-Body Unit / Engineering Qualification Model-Mast Unit (FM-BU/EQM-MU) setup of SuperCam. Specifically, the samples were prepared in the laboratory by adsorbing adenosine 5"-monophosphate, L-glutamic acid, L-phenylalanine, and phthalic acid with different known concentrations (5 wt%, 1 wt% and 0.1 wt%) on the clay mineral montmorillonite doped with 1 wt% of Mg-perchlorate. The preparation and characterization of those samples can be found in literature [1]. The analyses were carried out at a 2 m distance from the targets, with a laser spot size of around 300 ”m at that distance. SuperCam showed excellent results for the pure compounds, before adsorption on the clay mineral. At 5 wt% concentration, the Raman signals of the organics were barely visible and at 1 wt% they were no longer visible. This fact means that if the laser of SuperCam hits an organic "hotspot" in a rock from a distance, it will be able to detect it as long as it has a concentration around 5 wt% or greater in the analyzed area, allowing SHERLOC to do further contact analysis afterwards. In addition, the SuperCam results were compared with those obtained with a commercial laboratory instrument (Renishaw inVia), obtaining the same main signals and only missing some minor secondary bands.[1] T. Fornaro, J. R. Brucato, G. Poggiali, M. A. Corazzi, M. Biczysko, M. Jaber, D. I. Foustoukos, R. M. Hazen, A. Steele, UV irradiation and Near Infrared characterization of laboratory Mars soil analog samples, Frontiers in Astronomy and Space Sciences, 2020, 7, 1-2
ExoMars Raman Laser Spectrometer RLS, a tool for the potential recognition of wet target craters on Mars
In the present work, NIR, LIBS, Raman and XRD techniques have been
complementarily used to carry out a comprehensive characterization of a
terrestrial analogue selected from the Chesapeake Bay Impact Structure (CBIS).
The obtained data clearly highlight the key role of Raman spectroscopy in the
detection of minor and trace compounds, through which inferences about
geological processes occurred in the CBIS can be extrapolated. Beside the use
of commercial systems, further Raman analyses were performed by the Raman Laser
Spectrometer (RLS) ExoMars Simulator. This instrument represents the most
reliable tool to effectively predict the scientific capabilities of the
ExoMars/Raman system that will be deployed on Mars in 2021. By emulating the
analytical procedures and operational restrictions established by the ExoMars
mission rover design, it was proved that the RLS ExoMars Simulator is able to
detect the amorphization of quartz, which constitutes an analytical clue of the
impact origin of craters. On the other hand, the detection of barite and
siderite, compounds crystallizing under hydrothermal conditions, helps to
indirectly confirm the presence of water in impact targets. Furthermore, the
RLS ExoMars Simulator capability of performing smart molecular mappings was
also evaluated. According to the obtained results, the algorithms developed for
its operation provide a great analytical advantage over most of the automatic
analysis systems employed by commercial Raman instruments, encouraging its
application for many additional scientific and commercial purposes
The SuperCam Instrument Suite on the NASA Mars 2020 Rover: Body Unit and Combined System Tests
TheSuperCaminstrumentsuiteprovidestheMars2020rover,Perseverance,with a number of versatile remote-sensing techniques that can be used at long distance as well as within the robotic-arm workspace. These include laser-induced breakdown spectroscopy (LIBS), remote time-resolved Raman and luminescence spectroscopies, and visible and in- frared (VISIR; separately referred to as VIS and IR) reflectance spectroscopy. A remote micro-imager (RMI) provides high-resolution color context imaging, and a microphone can be used as a stand-alone tool for environmental studies or to determine physical properties of rocks and soils from shock waves of laser-produced plasmas. SuperCam is built in three parts: The mast unit (MU), consisting of the laser, telescope, RMI, IR spectrometer, and associated electronics, is described in a companion paper. The on-board calibration targets are described in another companion paper. Here we describe SuperCamâs body unit (BU) and testing of the integrated instrument.The BU, mounted inside the rover body, receives light from the MU via a 5.8 m opti- cal fiber. The light is split into three wavelength bands by a demultiplexer, and is routed via fiber bundles to three optical spectrometers, two of which (UV and violet; 245â340 and 385â465 nm) are crossed Czerny-Turner reflection spectrometers, nearly identical to their counterparts on ChemCam. The third is a high-efficiency transmission spectrometer contain- ing an optical intensifier capable of gating exposures to 100 ns or longer, with variable delay times relative to the laser pulse. This spectrometer covers 535â853 nm (105â7070 cmâ1 Ra- man shift relative to the 532 nm green laser beam) with 12 cmâ1 full-width at half-maximum peak resolution in the Raman fingerprint region. The BU electronics boards interface with the rover and control the instrument, returning data to the rover. Thermal systems maintain a warm temperature during cruise to Mars to avoid contamination on the optics, and cool the detectors during operations on Mars.Results obtained with the integrated instrument demonstrate its capabilities for LIBS, for which a library of 332 standards was developed. Examples of Raman and VISIR spec- troscopy are shown, demonstrating clear mineral identification with both techniques. Lumi- nescence spectra demonstrate the utility of having both spectral and temporal dimensions. Finally, RMI and microphone tests on the rover demonstrate the capabilities of these sub- systems as well