400 research outputs found
Inert strength measurement on silica soaked at 250°C in liquid water and water vapour
The effect of water soaking and heat-treatment in saturated water vapour at
250°C for 192 h on the strength of silica glass is studied. Bending strength
meaurements in liquid nitrogen showed a clear increase of the inert strength
for heat-treated specimens over that of the untreated material. The increase
in strength is interpreted as the consequence of water diffusion into exposed
surfaces of the test specimen, which results in swelling of the glass and
shielding of cracks, present in the surface of the glass. Experimental results
are compared with theoretical predictions
Breakdown of the few-level approximation in collective systems
The validity of the few-level approximation in dipole-dipole interacting
collective systems is discussed. As example system, we study the archetype case
of two dipole-dipole interacting atoms, each modelled by two complete sets of
angular momentum multiplets. We establish the breakdown of the few-level
approximation by first proving the intuitive result that the dipole-dipole
induced energy shifts between collective two-atom states depend on the length
of the vector connecting the atoms, but not on its orientation, if complete and
degenerate multiplets are considered. A careful analysis of our findings
reveals that the simplification of the atomic level scheme by artificially
omitting Zeeman sublevels in a few-level approximation generally leads to
incorrect predictions. We find that this breakdown can be traced back to the
dipole-dipole coupling of transitions with orthogonal dipole moments. Our
interpretation enables us to identify special geometries in which partial
few-level approximations to two- or three-level systems are valid
Evaluation of crack-terminating angles in heat-treated silica DCDC-specimens
Cracks terminating at free surfaces are affected by local stresses in the surface region. Under residual compression, the crack front must retard and under residual tensile stresses advance, both compared with the crack contour in the absence of stresses. This effect can be used for an estimation of residual surface stresses in silica generated during the silica/water reaction and caused by volume swelling. A strong shielding stress intensity factor of about -2.5 MPa was found for DCDC specimen heat-treated for 192h at 250°C in water. This result is a clear indication for compressive stresses developing in the water diffusion zone at the surface
Lifetimes of Confined Acoustic Phonons in Ultra-Thin Silicon Membranes
We study the relaxation of coherent acoustic phonon modes with frequencies up
to 500 GHz in ultra-thin free-standing silicon membranes. Using an ultrafast
pump-probe technique of asynchronous optical sampling, we observe that the
decay time of the first-order dilatational mode decreases significantly from
\sim 4.7 ns to 5 ps with decreasing membrane thickness from \sim 194 to 8 nm.
The experimental results are compared with theories considering both intrinsic
phonon-phonon interactions and extrinsic surface roughness scattering including
a wavelength-dependent specularity. Our results provide insight to understand
some of the limits of nanomechanical resonators and thermal transport in
nanostructures
Primary stability of a press-fit cup in combination with impaction grafting in an acetabular defect model
The objectives of this study were to (a) assess primary stability of a press-fit cup in a simplified acetabular defect model, filled with compacted cancellous bone chips, and (b) to compare the results with primary stability of a press-fit cup combined with two different types of bone graft substitute in the same defect model. A previously developed acetabular test model made of polyurethane foam was used, in which a mainly medial contained defect was implemented. Three test groups (N = 6 each) were prepared: Cancellous bone chips (bone chips), tricalciumphosphate tetrapods + collagen matrix (tetrapods + coll), bioactive glass S53P4 + polyethylene glycol-glycerol matrix (b.a.glass + PEG). Each material was compacted into the acetabulum and a press-fit cup was implanted. The specimens were loaded dynamically in the direction of the maximum resultant force during level walking. Relative motion between cup and test model was assessed with an optical measurement system. At the last load step (3000 N), inducible displacement was highest for bone chips with median [25th percentile; 75th percentile] value of 113 [110; 114] µm and lowest for b.a.glass + PEG with 91 [89; 93] µm. Migration at this load step was highest for b.a.glass + PEG with 868 [845; 936] µm and lowest for tetrapods + coll with 491 [487; 497] µm. The results show a comparable behavior under load of tetrapods + coll and bone chips and suggest that tetrapods + coll could be an attractive alternative to bone chips. However, so far, this was found for one specific defect type and primary stability should be further investigated in additional/more severe defects
Measuring the quantum efficiency of single radiating dipoles using a scanning mirror
Using scanning probe techniques, we show the controlled manipulation of the
radiation from single dipoles. In one experiment we study the modification of
the fluorescence lifetime of a single molecular dipole in front of a movable
silver mirror. A second experiment demonstrates the changing plasmon spectrum
of a gold nanoparticle in front of a dielectric mirror. Comparison of our data
with theoretical models allows determination of the quantum efficiency of each
radiating dipole.Comment: 4 pages, 4 figure
An ultra-sensitive pulsed balanced homodyne detector: Application to time-domain quantum measurements
A pulsed balanced homodyne detector has been developed for precise
measurements of electric field quadratures of pulsed optical quantum states. A
high level of common mode suppression (> 85 dB) and low electronic noise (730
electrons per pulse) provide a signal to noise ratio of 14 dB for the
measurement of the quantum noise of individual pulses. Measurements at
repetition rates up to 1 MHz are possible. As a test, quantum tomography of the
coherent state is performed and the Wigner function and the density matrix are
reconstructed with a 99.5% fidelity. The detection system can also be used for
ultrasensitive balanced detection in cw mode, e.g. for weak absorption
measurements.Comment: 3 pages, submitted to Optics Letter
Methane-Fueled Syntrophy through Extracellular Electron Transfer: Uncovering the Genomic Traits Conserved within Diverse Bacterial Partners of Anaerobic Methanotrophic Archaea
The anaerobic oxidation of methane by anaerobic methanotrophic (ANME) archaea in syntrophic partnership with deltaproteobacterial sulfate-reducing bacteria (SRB) is the primary mechanism for methane removal in ocean sediments. The mechanism of their syntrophy has been the subject of much research as traditional intermediate compounds, such as hydrogen and formate, failed to decouple the partners. Recent findings have indicated the potential for extracellular electron transfer from ANME archaea to SRB, though it is unclear how extracellular electrons are integrated into the metabolism of the SRB partner. We used metagenomics to reconstruct eight genomes from the globally distributed SEEP-SRB1 clade of ANME partner bacteria to determine what genomic features are required for syntrophy. The SEEP-SRB1 genomes contain large multiheme cytochromes that were not found in previously described free-living SRB and also lack periplasmic hydrogenases that may prevent an independent lifestyle without an extracellular source of electrons from ANME archaea. Metaproteomics revealed the expression of these cytochromes at in situ methane seep sediments from three sites along the Pacific coast of the United States. Phylogenetic analysis showed that these cytochromes appear to have been horizontally transferred from metal-respiring members of the Deltaproteobacteria such as Geobacter and may allow these syntrophic SRB to accept extracellular electrons in place of other chemical/organic electron donors
Estimation of swelling stresses from crack-terminating angles
Cracks terminating at free surfaces are affected by local stresses in the surface region. The crack front retards under residual compressive stresses compared with the crack contour in the absence of stresses. This effect had been used in [1] for identifying compression in the surface of chemically toughened and ion-exchanged soda-lime glass surfaces. In [2] the same effect was proven for swelling stresses due to the silica/water reaction. In the present report, the stresses in the surface layers are predicted based on results for soda-lime glass. For silica heattreated in humid environments, compressive stresses in the order of about -130 MPa to -170 MPa are obtained
Maternal consumption of fish oil programs reduced adiposity in broiler chicks
Maternal intake of eicosapentaenoic acid (EPA; 20:5 n-3) and docosahexaenoic acid (22:6 n-3) has been associated with reduced adiposity in children, suggesting the possibility to program adipose development through dietary fatty acids before birth. This study determined if enriching the maternal diet in fish oil, the primary source of EPA and DHA, affected adipose development in offspring. Broiler chickens were used because they are obesity-prone, and because fatty acids provided to the embryo can be manipulated through the hen diet. Hens were fed diets supplemented (2.8% wt:wt) with corn oil (CO; n-6) or fish oil (FO; n-3) for 28 d. Chicks from both maternal diet groups were fed the same diet after hatch. Maternal FO consumption enriched chick adipose tissue in EPA and DHA and reduced adiposity by promoting more, but smaller, adipocytes. This adipocyte profile was paralleled by upregulated expression of the adipogenic regulator PPARGand its co-activator PPARGC1B, and reduced expression of LPL. Proteomics identified 95 differentially abundant proteins between FO and CO adipose tissue, including components of glucose metabolism, lipid droplet trafficking, and cytoskeletal organization. These results demonstrate that the maternal dietary fatty acid profile programs offspring adipose development
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