429 research outputs found
Correlation of N2O and ozone in the Southern Polar vortex during the airborne Antarctic ozone experiment
In situ N20 mixing ratios, measured by an airborne laser spectrometer (ATLAS), have been used along with in situ ozone measurements to determine the correlation of N2O and ozone in the Antarctic stratosphere during the late austral winter. During the 1987 Airborne Antarctic Ozone Experiment (AAOE), N2O data were collected by a laser absorption spectrometer on board the ER-2 on five ferry flights between Ames Research Center (37 deg N) and Punta Arenas, Chile (53 deg S), and on twelve flights over Antarctica (53 S to 72 S). Of all the trace gas species measured by instruments on board the ER-2, only one showed a relationship to the N2O/O3 correlations in the vortex. With few exceptions, positive N20/O3 correlations coincided with total water mixing ratios of greater than 2.9 ppmv, and total water mixing ratios of less than 2.9 ppmv corresponded to negative correlations. The lower water mixing ratios, or dehydrated regions, are colocated with the negative correlations within the vortex, while the wetter regions always occur near the vortex edge
On the Stratospheric Chemistry of Midlatitude Wildfire Smoke
Massive Australian wildfires lofted smoke directly into the stratosphere in the austral summer of 2019/20. The smoke led to increases in optical extinction throughout the midlatitudes of the southern hemisphere that rivalled substantial volcanic perturbations. Previous studies have assumed that the smoke became coated with sulfuric acid and water and would deplete the ozone layer through heterogeneous chemistry on those surfaces, as is routinely observed following volcanic enhancements of the stratospheric sulfate layer. Here, observations of extinction and reactive nitrogen species from multiple independent satellites that sampled the smoke region are compared to one another and to model calculations. The data display a strong decrease in reactive nitrogen concentrations with increased aerosol extinction in the stratosphere, which is a known fingerprint for key heterogeneous chemistry on sulfate/H2O particles (specifically the hydrolysis of N2O5 to form HNO3). This chemical shift affects not only reactive nitrogen but also chlorine and reactive hydrogen species and is expected to cause midlatitude ozone layer depletion. Comparison of the model ozone to observations suggests that N2O5 hydrolysis contributed to reduced ozone, but additional chemical and/or dynamical processes are also important. These findings suggest that if wildfire smoke injection into the stratosphere increases sufficiently in frequency and magnitude as the world warms due to climate change, ozone recovery under the Montreal Protocol could be impeded, at least sporadically. Modeled austral midlatitude total ozone loss was about 1% in March 2020, which is significant compared to expected ozone recovery of about 1% per decade
Large-scale transport into the Arctic: the roles of the midlatitude jet and the Hadley Cell
Transport from the Northern Hemisphere (NH) midlatitudes to the
Arctic plays a crucial role in determining the abundance of trace gases and
aerosols that are important to Arctic climate via impacts on radiation and
chemistry. Here we examine this transport using an idealized tracer with a
fixed lifetime and predominantly midlatitude land-based sources in models
participating in the Chemistry Climate Model Initiative (CCMI). We show that
there is a 25 %–45 % difference in the Arctic concentrations of this tracer
among the models. This spread is correlated with the spread in the location
of the Pacific jet, as well as the spread in the location of the Hadley Cell
(HC) edge, which varies consistently with jet latitude. Our results suggest
that it is likely that the HC-related zonal-mean meridional transport rather
than the jet-related eddy mixing is the major contributor to the inter-model
spread in the transport of land-based tracers into the Arctic. Specifically,
in models with a more northern jet, the HC generally extends further north
and the tracer source region is mostly covered by surface southward flow
associated with the lower branch of the HC, resulting in less efficient
transport poleward to the Arctic. During boreal summer, there are poleward
biases in jet location in free-running models, and these models likely
underestimate the rate of transport into the Arctic. Models using specified
dynamics do not have biases in the jet location, but do have biases in the
surface meridional flow, which may result in differences in transport into
the Arctic. In addition to the land-based tracer, the midlatitude-to-Arctic
transport is further examined by another idealized tracer with zonally
uniform sources. With equal sources from both land and ocean, the inter-model
spread of this zonally uniform tracer is more related to variations in
parameterized convection over oceans rather than variations in HC extent,
particularly during boreal winter. This suggests that transport of land-based
and oceanic tracers or aerosols towards the Arctic differs in pathways and
therefore their corresponding inter-model variabilities result from different
physical processes.</p
A New Retrieval Algorithm for OMI NO2: Tropospheric Results and Comparisons with Measurements and Models
Nitrogen oxides (NOx =NO+NO2) are important atmospheric trace constituents that impact tropospheric air pollution chemistry and air quality. We have developed a new NASA algorithm for the retrieval of stratospheric and tropospheric NO2 vertical column densities using measurements from the nadir-viewing Ozone Monitoring Instrument (OMI) on NASA's Aura satellite. The new products rely on an improved approach to stratospheric NO2 column estimation and stratosphere-troposphere separation and a new monthly NO2 climatology based on the NASA Global Modeling Initiative chemistry-transport model. The retrieval does not rely on daily model profiles, minimizing the influence of a priori information. We evaluate the retrieved tropospheric NO2 columns using surface in situ (e.g., AQS/EPA), ground-based (e.g., DOAS), and airborne measurements (e.g., DISCOVER-AQ). The new, improved OMI tropospheric NO2 product is available at high spatial resolution for the years 200S-present. We believe that this product is valuable for the evaluation of chemistry-transport models, examining the spatial and temporal patterns of NOx emissions, constraining top-down NOx inventories, and for the estimation of NOx lifetimes
Memories of being injured and patients' care trajectory after physical trauma
<p>Abstract</p> <p>Background</p> <p>The purpose of this study was to acquire a deeper understanding of patients' memories of being injured and the trajectory of care before, during and after their Intensive Care Unit (ICU) stay.</p> <p>Methods</p> <p>Interviews were conducted with eighteen informants who after physical trauma had been cared for in the ICU. The interviews were analyzed by using a phenomenological hermeneutical method.</p> <p>Results</p> <p>The memories of injury during the trajectory of care are illustrated in a figure in which the injured informants have memories from five scenes; the scene of the accident, emergency unit, ICU, nursing ward and of coming home. Twelve subthemes were abstracted and four themes emerged; a surrealistic world, an injured body, care, and gratitude for life. After the accident, a "surrealistic world" appeared along with bad memories of being in a floating existence where plans had to be changed. This world was unfamiliar, sometimes including delusional and fragmentary memories from the ICU, and it was experienced as uncontrollable. They felt connected to an "injured body", experiencing bad memories from the ICU of being injured, from the nursing ward of simply enduring and of being in a No Man's Land when coming home; their lives had become limited. At the same time they were "connected to care" with good memories of receiving attention from others at the scene of the accident, being taken cared of at the emergency unit and cared for in the ICU. This care made them realise that people are responsible for each other, and they felt comforted but also vulnerable. Finally, they experienced "gratitude for life". This included good memories of being loved together with support from their families at the ICU, wanting to win life back at the nursing ward and acceptance when returning home. The support from their families made them realise that they fit in just as they are.</p> <p>Conclusion</p> <p>When bad memories of a surrealistic world and of being injured are balanced by good ones of care and love with a gratitude for life, there are more possibilities to move on despite an uncertain future following the injury.</p
Herschel/HIFI observations of interstellar OH+ and H2O+ towards W49N: a probe of diffuse clouds with a small molecular fraction
We report the detection of absorption by interstellar hydroxyl cations and
water cations, along the sight-line to the bright continuum source W49N. We
have used Herschel's HIFI instrument, in dual beam switch mode, to observe the
972 GHz N = 1 - 0 transition of OH+ and the 1115 GHz 1(11) - 0(00) transition
of ortho-H2O+. The resultant spectra show absorption by ortho-H2O+, and strong
absorption by OH+, in foreground material at velocities in the range 0 to 70
km/s with respect to the local standard of rest. The inferred OH+/H2O+
abundance ratio ranges from ~ 3 to ~ 15, implying that the observed OH+ arises
in clouds of small molecular fraction, in the 2 - 8% range. This conclusion is
confirmed by the distribution of OH+ and H2O+ in Doppler velocity space, which
is similar to that of atomic hydrogen, as observed by means of 21 cm absorption
measurements, and dissimilar from that typical of other molecular tracers. The
observed OH+/H abundance ratio of a few E-8 suggests a cosmic ray ionization
rate for atomic hydrogen of (0.6 - 2.4) E-16 s-1, in good agreement with
estimates inferred previously for diffuse clouds in the Galactic disk from
observations of interstellar H3+ and other species.Comment: Accepted for publication in A&A Letter
Interstellar OH+, H2O+ and H3O+ along the sight-line to G10.6-0.4
We report the detection of absorption lines by the reactive ions OH+, H2O+
and H3O+ along the line of sight to the submillimeter continuum source
G10.60.4 (W31C). We used the Herschel HIFI instrument in dual beam switch
mode to observe the ground state rotational transitions of OH+ at 971 GHz, H2O+
at 1115 and 607 GHz, and H3O+ at 984 GHz. The resultant spectra show deep
absorption over a broad velocity range that originates in the interstellar
matter along the line of sight to G10.60.4 as well as in the molecular gas
directly associated with that source. The OH+ spectrum reaches saturation over
most velocities corresponding to the foreground gas, while the opacity of the
H2O+ lines remains lower than 1 in the same velocity range, and the H3O+ line
shows only weak absorption. For LSR velocities between 7 and 50 kms we
estimate total column densities of (OH+) cm,
(H2O+) cm and (H3O+) cm. These detections confirm the role of O and OH in
initiating the oxygen chemistry in diffuse molecular gas and strengthen our
understanding of the gas phase production of water. The high ratio of the OH+
by the H2O+ column density implies that these species predominantly trace
low-density gas with a small fraction of hydrogen in molecular form
Howard's War on Terror: A Conceivable, Communicable and Coercive Foreign Policy Discourse
This article explores the relationship between language and political possibility. It is argued that John Howard’s language from 11 September 2001 to mid 2003 helped to enable the ‘War on Terror’ in an Australian context in three principal ways. Firstly, through contingent and contestable constructions of Australia, the world and their relationship, Howard’s language made interventionism conceivable. Secondly, emphasising shared values, mateship and mutual sacrifice in war, Howard embedded his foreign policy discourse in the cultural terrain of ‘mainstream Australia’, specifically framing a foreign policy discourse that was communicable to ‘battlers’ and disillusioned ‘Hansonites’. Thirdly, positioning alternatives as ‘un-Australian’, Howard’s language was particularly coercive, silencing potential oppositional voices
Assessing the Effects of Personal Characteristics and Context on U.S. House Speakers’ Leadership Styles, 1789-2006
Research on congressional leadership has been dominated in recent decades by contextual interpretations that see leaders’ behavior as best explained by the environment in which they seek to exercise leadership—particularly, the preference homogeneity and size of their party caucus. The role of agency is thus discounted, and leaders’ personal characteristics and leadership styles are underplayed. Focusing specifically on the speakers of the U.S. House of Representatives from the first to the 110th Congress, we construct measures of each speaker’s commitment to comity and leadership assertiveness. We find the scores reliable and then test the extent to which a speaker’s style is the product of both political context and personal characteristics. Regression estimates on speakers’ personal assertiveness scores provide robust support for a context-plus-personal characteristics explanation, whereas estimates of their comity scores show that speakers’ personal backgrounds trump context
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