π\pi-Electron Ferromagnetism in Metal Free Carbon Probed by Soft X-Ray Dichroism

Elemental carbon represents a fundamental building block of matter and the possibility of ferromagnetic order in carbon attracted widespread attention. However, the origin of magnetic order in such a light element is only poorly understood and has puzzled researchers. We present a spectromicroscopy study at room temperature of proton irradiated metal free carbon using the elemental and chemical specificity of x-ray magnetic circular dichroism (XMCD). We demonstrate that the magnetic order in the investigated system originates only from the carbon $\pi$-electron system.Comment: 10 pages 3 color figure

The role of hydrogen in room-temperature ferromagnetism at graphite surfaces

We present a x-ray dichroism study of graphite surfaces that addresses the origin and magnitude of ferromagnetism in metal-free carbon. We find that, in addition to carbon $\pi$ states, also hydrogen-mediated electronic states exhibit a net spin polarization with significant magnetic remanence at room temperature. The observed magnetism is restricted to the top $\approx$10 nm of the irradiated sample where the actual magnetization reaches $\simeq 15$ emu/g at room temperature. We prove that the ferromagnetism found in metal-free untreated graphite is intrinsic and has a similar origin as the one found in proton bombarded graphite.Comment: 10 pages, 5 figures, 1 table, submitted to New Journal of Physic

Temporal dissipative solitons in the Morris-Lecar model with time-delayed feedback

We study the dynamics and bifurcations of temporal dissipative solitons in an excitable system under time-delayed feedback. As a prototypical model displaying different types of excitability, we use the Morris-Lecar model. In the limit of large delay, soliton like solutions of delay-differential equations can be treated as homoclinic solutions of an equation with an advanced argument. Based on this, we use concepts of classical homoclinic bifurcation theory to study different types of pulse solutions and to explain their dependence on the system parameters. In particular, we show how a homoclinic orbit flip of a single-pulse soliton leads to the destabilization of equidistant multi-pulse solutions and to the emergence of stable pulse packages. It turns out that this transition is induced by a heteroclinic orbit flip in the system without feedback, which is related to the excitability properties of the Morris-Lecar model

Gradient-based estimation of local parameters for flow and transport in heterogeneous porous media

We present the application of the gradient‐based total least squares (TLS) method to the local estimation of parameters for flow and transport in porous media. The concept is based on the evaluation of partial derivatives of spatially and temporally resolved data using TLS as a maximum likelihood estimator. While ordinary inverse modeling approaches are often complicated by the spatially varying properties of porous media, the present approach can directly localize the estimation to an arbitrary range in space and time. The estimation of the local parameters can be achieved without requiring any explicit solution of the respective transport equation. First the basic ideas and the formalism of TLS are introduced with a simple example of a straight line fit. Then the ideas of the gradient‐based approach and its application to the parameter estimation for a large class of dynamic processes are presented. We further discuss relevant computational issues such as the calculation of the derivatives, choice of the local neighborhood and the determination of a measure of confidence. The performance of the method is then exemplified by the estimation of local velocities and dispersion coefficients from numerical solutions of the convection‐dispersion equation

Band selection and disentanglement using maximally-localized Wannier functions: the cases of Co impurities in bulk copper and the Cu (111) surface

We have adapted the maximally-localized Wannier function approach of [I. Souza, N. Marzari and D. Vanderbilt, Phys. Rev. B 65, 035109 (2002)] to the density functional theory based Siesta method [J. M. Soler et al., J. Phys.: Cond. Mat. 14, 2745 (2002)] and applied it to the study of Co substitutional impurities in bulk copper as well as to the Cu (111) surface. In the Co impurity case, we have reduced the problem to the Co d-electrons and the Cu sp-band, permitting us to obtain an Anderson-like Hamiltonian from well defined density functional parameters in a fully orthonormal basis set. In order to test the quality of the Wannier approach to surfaces, we have studied the electronic structure of the Cu (111) surface by again transforming the density functional problem into the Wannier representation. An excellent description of the Shockley surface state is attained, permitting us to be confident in the application of this method to future studies of magnetic adsorbates in the presence of an extended surface state

Visualization of gas-liquid mass transfer and wake structure of rising bubbles using pH-sensitive PLIF

A planar laser-induced fluorescence (PLIF) technique for visualizing gas–liquid mass transfer and wake structure of rising gas bubbles is described. The method uses an aqueous solution of the pH-sensitive dye Naphthofluorescein and CO2 as a tracer gas. It features a high spatial resolution and frame rates of up to 500 Hz, providing the ability to capture cinematographic image sequences. By steering the laser beam with a set of two programmable scanning mirrors, sequences of three-dimensional LIF images can be recorded. The technique is applied to freely rising bubbles with diameters between 0.5 and 5 mm, which perform rectilinear, oscillatory or irregular motions. The resulting PLIF image sequences reveal the evolution of characteristic patterns in the near and far wake of the bubbles and prove the potential of the technique to provide new and detailed insights into the spatio-temporal dynamics of mass transfer of rising gas bubbles. The image sequences further allow the estimation of bubble size and rise velocity. The analysis of bubble rise velocities in the Naphthofluorescein solution indicates that surfactant-contaminated conditions are encountered

Intercalation of graphene on SiC(0001) via ion-implantation

Electronic devices based on graphene technology are catching on rapidly and the ability to engineer graphene properties at the nanoscale is becoming, more than ever, indispensable. Here, we present a new procedure of graphene functionalization on SiC(0001) that paves the way towards the fabrication of complex graphene electronic chips. The procedure resides on the well-known ion-implantation technique. The efficiency of the working principle is demonstrated by the intercalation of the epitaxial graphene layer on SiC(0001) with Bi atoms, which was not possible following standard procedures. Our results put forward the ion-beam lithography to nanostructure and functionalize desired graphene chips