1,359 research outputs found
Gradient-based estimation of local parameters for flow and transport in heterogeneous porous media
We present the application of the gradientâbased total least squares (TLS) method to the local estimation of parameters for flow and transport in porous media. The concept is based on the evaluation of partial derivatives of spatially and temporally resolved data using TLS as a maximum likelihood estimator. While ordinary inverse modeling approaches are often complicated by the spatially varying properties of porous media, the present approach can directly localize the estimation to an arbitrary range in space and time. The estimation of the local parameters can be achieved without requiring any explicit solution of the respective transport equation. First the basic ideas and the formalism of TLS are introduced with a simple example of a straight line fit. Then the ideas of the gradientâbased approach and its application to the parameter estimation for a large class of dynamic processes are presented. We further discuss relevant computational issues such as the calculation of the derivatives, choice of the local neighborhood and the determination of a measure of confidence. The performance of the method is then exemplified by the estimation of local velocities and dispersion coefficients from numerical solutions of the convectionâdispersion equation
Selective spin transport through a quantum heterostructure: Transfer matrix method
In the present work we propose that a one-dimensional quantum heterostructure
composed of magnetic and non-magnetic atomic sites can be utilized as a spin
filter for a wide range of applied bias voltage. A simple tight-binding
framework is given to describe the conducting junction where the
heterostructure is coupled to two semi-infinite one-dimensional non-magnetic
electrodes. Based on transfer matrix method all the calculations are performed
numerically which describe two-terminal spin dependent transmission probability
along with junction current through the wire. Our detailed analysis may provide
fundamental aspects of selective spin transport phenomena in one-dimensional
heterostructures at nano-scale level.Comment: 12 pages, 15 figures (Accepted for Publication in: International
Journal of Modern Physics B
Intercalation of graphene on SiC(0001) via ion-implantation
Electronic devices based on graphene technology are catching on rapidly and
the ability to engineer graphene properties at the nanoscale is becoming, more
than ever, indispensable. Here, we present a new procedure of graphene
functionalization on SiC(0001) that paves the way towards the fabrication of
complex graphene electronic chips. The procedure resides on the well-known
ion-implantation technique. The efficiency of the working principle is
demonstrated by the intercalation of the epitaxial graphene layer on SiC(0001)
with Bi atoms, which was not possible following standard procedures. Our
results put forward the ion-beam lithography to nanostructure and functionalize
desired graphene chips
Multiplet ligand-field theory using Wannier orbitals
We demonstrate how ab initio cluster calculations including the full Coulomb
vertex can be done in the basis of the localized, generalized Wannier orbitals
which describe the low-energy density functional (LDA) band structure of the
infinite crystal, e.g. the transition metal 3d and oxygen 2p orbitals. The
spatial extend of our 3d Wannier orbitals (orthonormalized Nth order muffin-tin
orbitals) is close to that found for atomic Hartree-Fock orbitals. We define
Ligand orbitals as those linear combinations of the O 2p Wannier orbitals which
couple to the 3d orbitals for the chosen cluster. The use of ligand orbitals
allows for a minimal Hilbert space in multiplet ligand-field theory
calculations, thus reducing the computational costs substantially. The result
is a fast and simple ab initio theory, which can provide useful information
about local properties of correlated insulators. We compare results for NiO,
MnO and SrTiO3 with x-ray absorption, inelastic x-ray scattering, and
photoemission experiments. The multiplet ligand field theory parameters found
by our ab initio method agree within ~10% to known experimental values
On rationality of the intersection points of a line with a plane quartic
We study the rationality of the intersection points of certain lines and
smooth plane quartics C defined over F_q. For q \geq 127, we prove the
existence of a line such that the intersection points with C are all rational.
Using another approach, we further prove the existence of a tangent line with
the same property as soon as the characteristic of F_q is different from 2 and
q \geq 66^2+1. Finally, we study the probability of the existence of a rational
flex on C and exhibit a curious behavior when the characteristic of F_q is
equal to 3.Comment: 17 pages. Theorem 2 now includes the characteristic 2 case;
Conjecture 1 from the previous version is proved wron
Trichostatin A induced histone acetylation causes decondensation of interphase chromatin.
The effect of trichostatin A (TSA)-induced histone
acetylation on the interphase chromatin structure was
visualized in vivo with a HeLa cell line stably expressing
histone H2A, which was fused to enhanced yellow
fluorescent protein. The globally increased histone
acetylation caused a reversible decondensation of dense
chromatin regions and led to a more homogeneous
distribution. These structural changes were quantified by
image correlation spectroscopy and by spatially resolved
scaling analysis. The image analysis revealed that a
chromatin reorganization on a length scale from 200 nm to
>1 mm was induced consistent with the opening of
condensed chromatin domains containing several Mb of DNA. The observed conformation changes could be
assigned to the folding of chromatin during G1 phase by
characterizing the effect of TSA on cell cycle progression
and developing a protocol that allowed the identification of
G1 phase cells on microscope coverslips. An analysis by
flow cytometry showed that the addition of TSA led to a
significant arrest of cells in S phase and induced apoptosis.
The concentration dependence of both processes was
studied
Observation of Spin-glass-like Behavior in SrRuO3 Epitaxial Thin Films
We report the observation of spin-glass-like behavior and strong magnetic
anisotropy in extremely smooth (~1-3 \AA) roughness) epitaxial (110) and (010)
SrRuO3 thin films. The easy axis of magnetization is always perpendicular to
the plane of the film (unidirectional) irrespective of crystallographic
orientation. An attempt has been made to understand the nature and origin of
spin-glass behavior, which fits well with Heisenberg model.Comment: 5 pages, 5 Figure
Ultrafast optical control of magnetization in EuO thin films
All-optical pump-probe detection of magnetization precession has been
performed for ferromagnetic EuO thin films at 10 K. We demonstrate that the
circularly-polarized light can be used to control the magnetization precession
on an ultrafast time scale. This takes place within the 100 fs duration of a
single laser pulse, through combined contribution from two nonthermal
photomagnetic effects, i.e., enhancement of the magnetization and an inverse
Faraday effect. From the magnetic field dependences of the frequency and the
Gilbert damping parameter, the intrinsic Gilbert damping coefficient is
evaluated to be {\alpha} \approx 3\times10^-3.Comment: 5 pages, 3 figures, accepted for publication in Phys. Rev.
Atomic and itinerant effects at the transition metal x-ray absorption K-pre-edge exemplified in the case of VO
X-ray absorption spectroscopy is a well established tool for obtaining
information about orbital and spin degrees of freedom in transition metal- and
rare earth-compounds. For this purpose usually the dipole transitions of the L-
(2p to 3d) and M- (3d to 4f) edges are employed, whereas higher order
transitions such as quadrupolar 1s to 3d in the K-edge are rarely studied in
that respect. This is due to the fact that usually such quadrupolar transitions
are overshadowed by dipole allowed 1s to 4p transitions and, hence, are visible
only as minor features in the pre-edge region. Nonetheless, these features
carry a lot of valuable information, similar to the dipole L-edge transition,
which is not accessible in experiments under pressure due to the absorption of
the diamond anvil pressurecell. We recently performed a theoretical and
experimental analysis of such a situation for the metal insulator transition of
(V(1-x)Crx)2O3. Since the importance of the orbital degrees of freedom in this
transition is widely accepted, a thorough understanding of quadrupole
transitions of the vanadium K-pre-edge provides crucial information about the
underlying physics. Moreover, the lack of inversion symetry at the vanadium
site leads to onsite mixing of vanadium 3d- and 4p- states and related quantum
mechanical interferences between dipole and quadrupole transitions. Here we
present a theoretical analysis of experimental high resolution x-ray absorption
spectroscopy at the V pre-K edge measured in partial fluorescence yield mode
for single crystals. We carried out density functional as well as configuration
interaction calculations in order to capture effects coming from both,
itinerant and atomic limits
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