Another method to maintain positive-pressure ventilation through the Montgomery® T tube

We describe airway management in a patient who had a Montgomery® T tube in situ. The main concern pertaining to these patients is the inadequate depth of anaesthesia and ventilation, in view of loss of volume of air and gases, as well as dilution through the proximal end of the Montgomery®  T tube. To circumvent these problems, we describe another method of providing ventilation, through the extraluminal horizontal limb of the Montgomery®  T tube by introducing an uncuffed endotracheal tube and minimising the loss of carrier gases to the larynx, together with a review of literature for the same.Keywords: Montgomery® T tube, positive-pressure ventilationSouth Afr J Anaesth Analg 2013;19(5):274-27

Study of line shape and angular variation of ESR spectra in two smectic a liquid crystals

Electron spin-resonance (ESR) measurement of the androstane nitroxide spin-probe is reported in isotropic, nematic and smectic A phases of the liquid crystals N(p-Octyloxy-benzylidine)-p-toludine [OBT] and p-nitrophenyl-p-n-octyloxy benzoate [NPOB]. Mono-domain samples in flat quartz tube were formed for the study of the angular variation of the spectra in smectic A phase. The analysis of the spectra using the theory of Polnaszek, Bruno and Freed (PBF) has resulted in the determination of the order parameter S, the rotational correlation time TR, and the anisotropic diffusion parameter N at different temperatures. The comparison between the two samples shows that the molecular geometry of the liquid crystals play important role in determining the value of the order parameter. The entire smectic A phase in OBT is characteristic of slow tumbling region (TR > 10-9 sec) and the anisotropic parameter N shows an anomalous increase in this phase. This indicates that the slowly relaxing local structure (SRLS) mechanism plays important role in the slow tumbling region. In NPOB the incipient slow tumbling region is almost at the end of smectic A phase and the SRLS mechanism does not seem to play as important role as in OBT

ESR line shape study of two nematic liquid crystals

Electron spin-resonance (ESR) measurements of the spin-probe17β-hydroxy-4,4'-dimethyl spiro[5α-androstane-3,2-oxazolidine]-3'-yloxyl in the liquid crystals 4-n-Amylacetophenon O-(4-n-heptyl benzoyl)-oxime [AAHBO] and 4-n-Butoxyphenyl hexyl benzoate [BPHB] are reported in isotropic and nematic phases. On the basis of the temperature variation of ESR line width, an extra, solid to solid, phase transition is observed in BPHB. The theory of Polnaszek, Bruno and Freed (PBF) appropriate for anisotropic viscosity diffusion is used to analyze the ESR spectra and thereby to determine the values of the order parameter, the rotational diffusion tensor and the correlation time at different temperatures for the two liquid crystals. The analysis shows that the slowly relaxing local structure mechanisms (SRLS) is active in slow tumbling region specially in AAHBO

Computer simulation of defects and oxygen transport in yttria-stabilized zirconia

We have used molecular dynamics simulations and energy minimization calculations to examine defect energetics and oxygen diffusion in yttria-stabilized zirconia (YSZ). Oxygen vacancies prefer to be second nearest neighbors to yttrium dopants. The oxygen diffusion coefficient shows a peak at 8 mol% yttria consistent with experimental findings. The activation energy for oxygen diffusion varies from 0.6 to 1.0 eV depending on the yttria content. The YZr' VO YZr' complex with a binding energy of -0.85 eV may play an important role in any conductivity degradation of YSZ

Investigation of bandwidth optimization hybrid scheduling algorithm for hybrid WDM/TDM passive optical system

Hybrid WDM/TDM optical access network has evolved as a cost-effective solution to the higher requirements of bandwidth in the access network. Bandwidth allocation and scheduling mechanism have become critical issues in the optical access networks. In this paper, a novel upstream bandwidth optimization hybrid scheduling algorithm has been proposed in which optical network units can employ tunable wavelength for upstream transmission with a single optical source. Resources allocations have been done utilizing multi point control protocol and for wavelength scheduling the shortest length of channels have been computed. Investigation of the proposed algorithm for providing improved channel utilization has been performed and a comparative analysis has been done for validation

Electronic structure of Pr0.67_{0.67}Ca0.33_{0.33}MnO3_3 near the Fermi level studied by ultraviolet photoelectron and x-ray absorption spectroscopy

We have investigated the temperature-dependent changes in the near-$E$$_F$ occupied and unoccupied states of Pr$_{0.67}$Ca$_{0.33}$MnO$_3$ which shows the presence of ferromagnetic and antiferromagnetic phases. The temperature-dependent changes in the charge and orbital degrees of freedom and associated changes in the Mn 3$d$ - O 2$p$ hybridization result in varied O 2$p$ contributions to the valence band. A quantitative estimate of the charge transfer energy ($E$$_{CT}$) shows a larger value compared to the earlier reported estimates. The charge localization causing the large $E$$_{CT}$ is discussed in terms of different models including the electronic phase separation.Comment: 19 pages, 7 figures, To be published in Phy. Rev.

Initial Filling of Tehri Reservoir — Analysis of Seepage Data

Initial Filling of reservoirs in dams, particularly the embankment type, is a very important phase as unusual behaviour / accidents of many dams have been reported during this period. A regular observation / analysis of quantum of seepage vis-à-vis the reservoir level is a significant activity so that any serious development inside the body of dam and foundation / abutments rocks are revealed in advance and remedial measures are taken up timely to prevent catastrophic failures. At Tehri, a 260.5m high earth & rockfill dam has been constructed across river Bhagirathi, a tributary of mighty river Ganga in India. Seepage discharge data of first two years of Initial Filling of Tehri reservoir has been analysed, which has led to a few important conclusions. The Analysis of Seepage data for the Initial Filling of Tehri reservoir is presented in the paper