4,308 research outputs found
Sun shield
A shading device which is capable of compactly storing a flexible shade on a biased, window shade type spring roller is disclosed. It is controlled to deliver the shade selectively to either its operative shading or compact storage orientation
The Gribov horizon and spontaneous BRST symmetry breaking
An equivalent formulation of the Gribov-Zwanziger theory accounting for the
gauge fixing ambiguity in the Landau gauge is presented. The resulting action
is constrained by a Slavnov-Taylor identity stemming from a nilpotent exact
BRST invariance which is spontaneously broken due to the presence of the Gribov
horizon. This spontaneous symmetry breaking can be described in a purely
algebraic way through the introduction of a pair of auxiliary fields which give
rise to a set of linearly broken Ward identities. The Goldstone sector turns
out to be decoupled. The underlying exact nilpotent BRST invariance allows to
employ BRST cohomology tools within the Gribov horizon to identify
renormalizable extensions of gauge invariant operators. Using a simple toy
model and appropriate Dirac bracket quantization, we discuss the time-evolution
invariance of the operator cohomology. We further comment on the unitarity
issue in a confining theory, and stress that BRST cohomology alone is not
sufficient to ensure unitarity, a fact, although well known, frequently
ignored.Comment: 13 pages. v2: corrected typ
Dynamic Algorithms for the Massively Parallel Computation Model
The Massive Parallel Computing (MPC) model gained popularity during the last
decade and it is now seen as the standard model for processing large scale
data. One significant shortcoming of the model is that it assumes to work on
static datasets while, in practice, real-world datasets evolve continuously. To
overcome this issue, in this paper we initiate the study of dynamic algorithms
in the MPC model.
We first discuss the main requirements for a dynamic parallel model and we
show how to adapt the classic MPC model to capture them. Then we analyze the
connection between classic dynamic algorithms and dynamic algorithms in the MPC
model. Finally, we provide new efficient dynamic MPC algorithms for a variety
of fundamental graph problems, including connectivity, minimum spanning tree
and matching.Comment: Accepted to the 31st ACM Symposium on Parallelism in Algorithms and
Architectures (SPAA 2019
Equation of Motion for the Solvent Polarization Apparent Charges in the Polarizable Continuum Model: Application to Time-Dependent CI
The dynamics of the electrons for a molecule in solution is coupled to the
dynamics of its polarizable environment, i.e., the solvent. To theoretically
investigate such electronic dynamics, we have recently developed equations of
motion (EOM) for the apparent solvent polarization charges that generate the
reaction field in the Polarizable Continuum Model (PCM) for solvation and we
have coupled them to a real-time time-dependent density functional theory (RT
TDDFT) description of the solute [Corni et al. J. Phys. Chem. A 119, 5405
(2014)]. Here we present an extension of the EOM-PCM approach to a
Time-Dependent Configuration Interaction (TD CI) description of the solute
dynamics, which is free from the qualitative artifacts of RT TDDFT in the
adiabatic approximation. As tests of the developed approach, we investigate the
solvent Debye relaxation after an electronic excitation of the solute obtained
either by a pulse of light or by assuming the idealized sudden promotion
to the excited state. Moreover, we present EOM for the Onsager solvation model
and we compare the results with PCM. The developed approach provides
qualitatively correct real-time evolutions and is promising as a general tool
to investigate the electron dynamics elicited by external electromagnetic
fields for molecules in solution.Comment: This is the final peer-reviewed manuscript accepted for publication
in The Journal of Chemical Physics. Copyright by AIP, the final published
version can be found at
http://scitation.aip.org/content/aip/journal/jcp/146/6/10.1063/1.497562
Real-Time Description of the Electronic Dynamics for a Molecule close to a Plasmonic Nanoparticle
The optical properties of molecules close to plasmonic nanostructures greatly
differ from their isolated molecule counterparts. To theoretically investigate
such systems in a Quantum Chemistry perspective, one has to take into account
that the plasmonic nanostructure (e.g., a metal nanoparticle - NP) is often too
large to be treated atomistically. Therefore, a multiscale description, where
the molecule is treated by an ab initio approach and the metal NP by a lower
level description, is needed. Here we present an extension of one such
multiscale model [Corni, S.; Tomasi, J. {\it J. Chem. Phys.} {\bf 2001}, {\it
114}, 3739] originally inspired by the Polarizable Continuum Model, to a
real-time description of the electronic dynamics of the molecule and of the NP.
In particular, we adopt a Time-Dependent Configuration Interaction (TD CI)
approach for the molecule, the metal NP is described as a continuous dielectric
of complex shape characterized by a Drude-Lorentz dielectric function and the
molecule- NP electromagnetic coupling is treated by an equation-of-motion (EOM)
extension of the quasi-static Boundary Element Method (BEM). The model includes
the effects of both the mutual molecule- NP time-dependent polarization and the
modification of the probing electromagnetic field due to the plasmonic
resonances of the NP. Finally, such an approach is applied to the investigation
of the light absorption of a model chromophore, LiCN, in the presence of a
metal NP of complex shape.Comment: This is the final peer-reviewed manuscript accepted for publication
of an open access article published under an ACS AuthorChoice License, which
permits copying and redistribution of the article or any adaptations for
non-commercial purposes. Link to the original article:
http://pubs.acs.org/doi/abs/10.1021/acs.jpcc.6b1108
Establishment and production costs for commercial vineyards in Missouri
Cover title.Includes bibliographical references
Local roughness exponent in the nonlinear molecular-beam-epitaxy universality class in one-dimension
We report local roughness exponents, , for three
interface growth models in one dimension which are believed to belong the
non-linear molecular-beam-epitaxy (nMBE) universality class represented by the
Villain-Lais-Das Sarma (VLDS) stochastic equation. We applied an optimum
detrended fluctuation analysis (ODFA) [Luis et al., Phys. Rev. E 95, 042801
(2017)] and compared the outcomes with standard detrending methods. We observe
in all investigated models that ODFA outperforms the standard methods providing
exponents in the narrow interval consistent
with renormalization group predictions for the VLDS equation. In particular,
these exponent values are calculated for the Clarke-Vvdensky and Das
Sarma-Tamborenea models characterized by very strong corrections to the
scaling, for which large deviations of these values had been reported. Our
results strongly support the absence of anomalous scaling in the nMBE
universality class and the existence of corrections in the form
of the one-loop renormalization group analysis
of the VLDS equation
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