Automation of MCDOR at NMT-3 Los Alamos National Laboratory. Final report

The automation of various parts of multiple--cycle direct oxide reduction (MCDOR) at LANL`s NMT-3 was the goal of this research and development activities. In particular, originally the following goals were assigned to the author by the NMT-3 technical staff leaders (Greg Bird, Jim McNeese, Joel Williams): (1) Design and fabricate an automation set up; (2) Step-wise automation is preferred; (3) Step 1 involves automatic metering and mixing of powders; and (4) Step 2-automatic transport of powder to furnace location The initial task assigned in May 91 was to get the appropriate design developed and order equipment and parts to automatically weight powders. In fact the work statement read {open_quotes}Create an experimental automation set up in the ME Department at UNM to automatically weigh powders using an electronic balance. Further, design the set up such that the electronic balance is reprogrammable for specific weight set points. Thus, when a set point in weight is reached by means of a vibratory feeder feeding a container on the balance, the electronic balance will send an electronic signal out to switch off the vibratory feeder{close_quotes}. The automation of the reduction of plutonium oxide to plutonium is described

Solid State Aircraft Concept Overview

Due to recent advances in polymers, photovoltaics, and batteries a unique type of aircraft may be feasible. This is a solid-state aircraft, with no conventional mechanical moving parts. Airfoil, propulsion, energy production, energy storage and control are combined in an integrated structure. The key material of this concept is an ionic polymeric-metal composite (IPMC) that provides source of control and propulsion. This material has the unique capability of deforming in an electric field and returning to its original shape when the field is removed. Combining the IPMC with thin-film batteries and thin-film photovoltaics provides both energy source and storage in the same structure. The characteristics of the materials enables flapping motion of the wing to be utilized to generate the main propulsive force. Analysis shows that a number of design configurations can be produced to enable flight over a range of latitudes on Earth, Venus and possibly Mars

An Energetically-Autonomous Robotic Tadpole with Single Membrane Stomach and Tail

We present an energetically autonomous robotic tadpole that uses a single membrane component for both electrical energy generation and propulsive actuation. The coupling of this small bio-inspired power source to a bio-inspired actuator demonstrates the first generation design for an energetically autonomous swimming robot consisting of a single membrane. An ionic polymer metal composite (IPMC) with a Nafion polymer layer is demonstrated in a novel application as the ion exchange membrane and anode and cathode electrode of a microbial fuel cell (MFC), whilst being used concurrently as an artificial muscle tail. In contrast to previous work using stacked units for increased voltage, a single MFC with novel, 0.88ml anode chamber architecture is used to generate suitable voltages for driving artificial muscle actuation, with minimal step up. This shows the potential of the small forces generated by IPMCs for propulsion of a bio-energy source. The work demonstrates great potential for reducing the mass and complexity of bio-inspired autonomous robots. The performance of the IPMC as an ion exchange membrane is compared to two conventional ion exchange membranes, Nafion and cation exchange membrane (CEM). The MFC anode and cathode show increased resistance following inclusion within the MFC environment

Compaction of Rods: Relaxation and Ordering in Vibrated, Anisotropic Granular Material

We report on experiments to measure the temporal and spatial evolution of packing arrangements of anisotropic, cylindrical granular material, using high-resolution capacitive monitoring. In these experiments, the particle configurations start from an initially disordered, low-packing-fraction state and under vertical vibrations evolve to a dense, highly ordered, nematic state in which the long particle axes align with the vertical tube walls. We find that the orientational ordering process is reflected in a characteristic, steep rise in the local packing fraction. At any given height inside the packing, the ordering is initiated at the container walls and proceeds inward. We explore the evolution of the local as well as the height-averaged packing fraction as a function of vibration parameters and compare our results to relaxation experiments conducted on spherically shaped granular materials.Comment: 9 pages incl. 7 figure

Ionic liquids at electrified interfaces

Until recently, “room-temperature” (<100–150 °C) liquid-state electrochemistry was mostly electrochemistry of diluted electrolytes(1)–(4) where dissolved salt ions were surrounded by a considerable amount of solvent molecules. Highly concentrated liquid electrolytes were mostly considered in the narrow (albeit important) niche of high-temperature electrochemistry of molten inorganic salts(5-9) and in the even narrower niche of “first-generation” room temperature ionic liquids, RTILs (such as chloro-aluminates and alkylammonium nitrates).(10-14) The situation has changed dramatically in the 2000s after the discovery of new moisture- and temperature-stable RTILs.(15, 16) These days, the “later generation” RTILs attracted wide attention within the electrochemical community.(17-31) Indeed, RTILs, as a class of compounds, possess a unique combination of properties (high charge density, electrochemical stability, low/negligible volatility, tunable polarity, etc.) that make them very attractive substances from fundamental and application points of view.(32-38) Most importantly, they can mix with each other in “cocktails” of one’s choice to acquire the desired properties (e.g., wider temperature range of the liquid phase(39, 40)) and can serve as almost “universal” solvents.(37, 41, 42) It is worth noting here one of the advantages of RTILs as compared to their high-temperature molten salt (HTMS)(43) “sister-systems”.(44) In RTILs the dissolved molecules are not imbedded in a harsh high temperature environment which could be destructive for many classes of fragile (organic) molecules

Energy applications of ionic liquids

Ionic liquids offer a unique suite of properties that make them important candidates for a number of energy related applications. Cation–anion combinations that exhibit low volatility coupled with high electrochemical and thermal stability, as well as ionic conductivity, create the possibility of designing ideal electrolytes for batteries, super-capacitors, actuators, dye sensitised solar cells and thermoelectrochemical cells. In the field of water splitting to produce hydrogen they have been used to synthesize some of the best performing water oxidation catalysts and some members of the protic ionic liquid family co-catalyse an unusual, very high energy efficiency water oxidation process. As fuel cell electrolytes, the high proton conductivity of some of the protic ionic liquid family offers the potential of fuel cells operating in the optimum temperature region above 100 °C. Beyond electrochemical applications, the low vapour pressure of these liquids, along with their ability to offer tuneable functionality, also makes them ideal as CO2 absorbents for post-combustion CO2 capture. Similarly, the tuneable phase properties of the many members of this large family of salts are also allowing the creation of phase-change thermal energy storage materials having melting points tuned to the application. This perspective article provides an overview of these developing energy related applications of ionic liquids and offers some thoughts on the emerging challenges and opportunities

Morphing in nature and beyond: a review of natural and synthetic shape-changing materials and mechanisms

Shape-changing materials open an entirely new solution space for a wide range of disciplines: from architecture that responds to the environment and medical devices that unpack inside the body, to passive sensors and novel robotic actuators. While synthetic shape-changing materials are still in their infancy, studies of biological morphing materials have revealed key paradigms and features which underlie efficient natural shape-change. Here, we review some of these insights and how they have been, or may be, translated to artificial solutions. We focus on soft matter due to its prevalence in nature, compatibility with users and potential for novel design. Initially, we review examples of natural shape-changing materials—skeletal muscle, tendons and plant tissues—and compare with synthetic examples with similar methods of operation. Stimuli to motion are outlined in general principle, with examples of their use and potential in manufactured systems. Anisotropy is identified as a crucial element in directing shape-change to fulfil designed tasks, and some manufacturing routes to its achievement are highlighted. We conclude with potential directions for future work, including the simultaneous development of materials and manufacturing techniques and the hierarchical combination of effects at multiple length scales.</p