67 research outputs found
Dielectric and Transport Properties of Thin Films Deposited from Sols with Silicon Nanoparticles
Local quasioptical resonator diagnostics of semiconductor wafers
The method of measurement of reflection coefficient behind an orifice in one of reflectors of the quasioptical open resonator is considered. According to the applied mathematical model, the method has the restriction which is consist in use of a short-wave approximation for the orifice size (it dimension is much more than a wavelength). For evaluation of limits of applicability of this method the experimental setup in the threecentimetric range of wavelengths consist of the quasioptical open resonator and the system of positioning of the measuring probe is created. By the experimental study of distribution of fields behind an orifice in the reflector of the open resonator it is found that the method, except restriction of mathematical model, has also restrictions, due to the wave’s interference, reflected from edges of this orifice. It causes a deviation from the uniform amplitude distribution of the field in an opening that can lead to increase in an error of a reflection coefficient measuring. It is also shown that by decrease of the sizes of an orifice formation of a bunch with small divergence, but with significantly more expressed distribution of the field localized about a bunch axis in an aperture is possible. It can be used for diagnostics of inhomogeneity of samples with higher locality
Scattering of quasi-optical THz beams on spherical MWCNTs aerogels
Results of research of lateral scattering of electromagnetic radiation by aerogel of MWCNTs are presented. Frequency dependences of lateral scattering of THz radiation of spherical MWCNTs aerogels with diameter of 4.5 and 6 mm at frequency range 43-970 GHz are given
Diffusion doping route to plasmonic Si/SiOx nanoparticles
International audienceSemiconductor nanoparticles (SNPs) are a valuable building block for functional materials. Capabilities for engineering of electronic structure of SNPs can be further improved with development of techniques of doping by diffusion, as post-synthetic introduction of impurities does not affect the nucleation and growth of SNPs. Diffusion of dopants from an external source also potentially allows for temporal control of radial distribution of impurities. In this paper we report on the doping of Si/SiOx SNPs by annealing particles in gaseous phosphorus. The technique can provide efficient incorporation of impurities, controllable with precursor vapor pressure. HRTEM and X-ray diffraction studies confirmed that obtained particles retain their nanocrystallinity. Elemental analysis revealed doping levels up to 10%. Electrical activity of the impurity was confirmed through thermopower measurements and observation of localized surface plasmon resonance in IR spectra. The plasmonic behavior of etched particles and EDX elemental mapping suggest uniform distribution of phosphorus in the crystalline silicon cores. Impurity activation efficiencies up to 34% were achieved, which indicate high electrical activity of thermodynamically soluble phosphorus in oxide-terminated nanosilicon
Optical AR coatings of the Mid-IR band for ZnGeP2 single crystals based on ZnS and oxide aluminum
In this work, the parameters of antireflection interference coatings based on alternating layers of ZnS/Al2O3 on the laser-induced damage threshold (LIDT) of ZGP crystals under the action of Ho:YAG laser radiation at a wavelength of 2.097 μm were determined. The coating deposition was carried out using the ion-beam sputtering method. The LIDT of the sample with a coating based on alternating layers ZnS and Al2O3 was equal to WEo = 3.45 J/cm2, and the LIDT of the uncoated sample was equal to WEo = 2.23 J/cm2. An increase in the optical breakdown threshold by ~55% was observed after the deposition of an AR coating based on ZnS and Al2O3 materials. An assumption was made about the absence of local fluctuations in the composition and mechanical stresses in the case of the coated sample, namely that this leads to good adhesion of the multilayer coating to the polished surface of the crystal, and as a result to an increase in the optical breakdown threshold as compared to the uncoated sample due to closure of the dangling chemical bonds and bulk defects emerging on the polished surface
Prioritisation of Research and Development for modelling the safe production, storage, delivery and use of hydrogen.
Hydrogen is expected to play an important role in the energy mix of a future low carbon society, (the European Strategic Energy Technology Plan of the European Commission (COM 2007 - 723) and in the Hydrogen, Fuel Cells & Infrastructure Technologies Program-Multi-Year Research, Development, and Demonstration Plan of the USA Department of Energy (DoE 2007).
Hydrogen safety issues must be addressed in order to ensure that the wide spread deployment and use of hydrogen and fuel cell technologies can occur with the same or lower level of hazards and associated risk compared to the conventional fossil fuel technologies. Hydrogen safety is a EU Policy relevant issue as it is stated in the priority 3 Action 2 (Continuous improvement in safety and security) of the EU “Energy 2020 A strategy for competitive, sustainable and secure energy”: “The same security and safety considerations will also be upheld in the development and deployment of new energy technologies (hydrogen safety, safety of CO2 transportation network, CO2 storage, etc…)”
Computational Fluid Dynamics (CFD) is one of the tools to investigate safety issues related to the production, storage, delivery and use of hydrogen. CFD techniques can provide a wealthy amount of information on the dynamics of hypothetical hydrogen accident and its consequences. The CFD-based consequence analysis is then used in risk assessments. This report describes the output of a workshop organised at the Institute for Energy and Transport (JRC) in Petten, Netherlands to identify the gaps and issues in CFD modelling of hydrogen release and combustion.
A hydrogen accident usually follows a typical sequence of events: an unintended release, the mixing of hydrogen with air to form a flammable mixture, the ignition of the flammable cloud and depending on the conditions, and a fire or an explosion (deflagration or/and detonation). For each stage of the accident, the critical CFD issues have been identified and prioritised. Beyond the specific issues of CFD modelling that are described for each accident stage in the report, some general modelling issues can be found in all stages:
• lack of an extensive validation of CFD codes/models that covers all the relevant range of conditions that can be found in hypothetical accident scenarios e.g. in terms of geometrical lay-out, leak flow rates.
• lack of a CFD validation protocol for hydrogen like it exists for Liquefied Natural Gas (LNG): the Model Evaluation Protocols (MEP) for assessment of models for accident consequences, with guidance on evaluating models in terms of scientific assessment, verification and validation.
• lack of a database of experiments for validation of hydrogen models.
• in some cases, lack of complete and accurate experimental data for the CFD validation.
The goals of this work were to perform a state of the art review in CFD modelling of hypothetical accidents scenarios related to hydrogen technologies and identify and prioritise the gaps in the field.
The report is based on a dedicated workshop organised in Petten with the participation of external experts an extensive literature review performed by experts in the field and the direct expertise and experience of the experts. The experts were carefully selected according to their experience/expertise, number of scientific publications and participations to International Conferences, seminars, workshops and to international and/or European co-funded projects such as HySafe (Hydrogen Safety), HyApproval (Approval of Hydrogen Re-fuelling Stations), European Integrated Hydrogen Projects.
By performing a state of the art review of CFD modelling for hydrogen safety issues, a consensus was reached among the scientific experts as to the main gaps in the field and on the priority of the research needs.JRC.F.2-Cleaner energ
Gap Analysis of CFD Modelling of Accidental Hydrogen Release and Combustion
The report describes the findings of a workshop that was held at the Institute for Energy (JRC) in Petten Netherlands, on the topic "Gap analysis of CFD modelling of hydrogen release and combustion". The main topic was divided in 6 sub-topics: release and dispersion, auto-ignition, fires, deflagrations, detonations and DDT, and accident consequences. For each sub-topic, the main gaps in CFD modelling were identified and prioritised.JRC.DDG.F.2-Cleaner energ
Nanoscale Real-Time Detection of Quantum Vortices at Millikelvin Temperatures
Since we still lack a theory of classical turbulence, attention has focused on the conceptually simpler turbulence in quantum fluids. Reaching a better understanding of the quantum case may provide additional insight into the classical counterpart. That said, we have hitherto lacked detectors capable of the real-time, non-invasive probing of the wide range of length scales involved in quantum turbulence. Here we demonstrate the real-time detection of quantum vortices by a nanoscale resonant beam in superfluid 4He at 10mK. Essentially, we trap a single vortex along the length of a nanobeam and observe the transitions as a vortex is either trapped or released, detected through the shift in the beam resonant frequency. By exciting a tuning fork, we control the ambient vortex density and follow its influence on the vortex capture and release rates demonstrating that these devices are capable of probing turbulence on the micron scale
Механический резонанс в кремниевом нанопроводе с высокой добротностью
Resonance properties of nanomechanical resonators based on doubly clamped silicon nanowires, fabricated from silicon-on-insulator and coated with a thin layer of aluminum, were experimentally investigated. Resonance frequencies of the fundamental mode were measured at a temperature of for nanowires of various sizes using the magnetomotive scheme. The measured values of the resonance frequency agree with the estimates obtained from the Euler-Bernoulli theory. The measured internal quality factor of the -long resonator, , exceeds the corresponding values of similar resonators investigated at higher temperatures. The structures presented can be used as mass sensors with an expected sensitivity
About the Motion Influence on a Signal with Hyperbolic Frequency Modulation
В данной статье рассмотрено влияние эффекта Доплера на сигнал с гиперболической частотной модуляцией. Проведен анализ эхо-сигнала на приемнике после отражения от цели, движущейся с постоянной скоростью под некоторым произвольным курсовым углом относительно гидроакустической станцииThis article discusses the Doppler effect influence on a signal with hyperbolic frequency modulation. An echo signal analysis at the receiver after reflection from a target moving at a constant speed at some arbitrary heading angle relative to the hydroacoustic station was carried ou
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