The pseudomorphic to bulk fcc phase transition of thin Ni films on Pd(100)

We have measured the transformation of pseudomorphic Ni films on Pd(100) into their bulk fcc phase as a function of the film thickness. We made use of x-ray diffraction and x-ray induced photoemission to study the evolution of the Ni film and its interface with the substrate. The growth of a pseudomorphic film with tetragonally strained face centered symmetry (fct) has been observed by out-of-plane x-ray diffraction up to a maximum thickness of 10 Ni layers (two of them intermixed with the substrate), where a new fcc bulk-like phase is formed. After the formation of the bulk-like Ni domains, we observed the pseudomorphic fct domains to disappear preserving the number of layers and their spacing. The phase transition thus proceeds via lateral growth of the bulk-like phase within the pseudomorphic one, i.e. the bulk-like fcc domains penetrate down to the substrate when formed. This large depth of the walls separating the domains of different phases is also indicated by the strong increase of the intermixing at the substrate-film interface, which starts at the onset of the transition and continues at even larger thickness. The bulk-like fcc phase is also slightly strained; its relaxation towards the orthomorphic lattice structure proceeds slowly with the film thickness, being not yet completed at the maximum thickness presently studied of 30 Angstrom (i.e. about 17 layers).Comment: 8 pages, 7 figure

The costs of accessible quality assured syphilis diagnostics: informing quality systems for rapid syphilis tests in a Tanzanian setting.

OBJECTIVES: To determine the costs of Rapid Syphilis Test (RSTs) as compared with rapid plasma reagin (RPR) when implemented in a Tanzanian setting, and to determine the relative impact of a quality assurance (QA) system on the cost of RST implementation. METHODS: The incremental costs for RPR and RST screening programmes in existing antenatal care settings in Geita District, Tanzania were collected for 9 months in subsequent years from nine health facilities that varied in size, remoteness and scope of antenatal services. The costs per woman tested and treated were estimated for each facility. A sensitivity analysis was constructed to determine the impact of parameter and model uncertainty. FINDINGS: In surveyed facilities, a total of 6362 women were tested with RSTs compared with 224 tested with RPR. The range of unit costs was $1.76-$3.13 per woman screened and $12.88-$32.67 per woman treated. Unit costs for the QA system came to $0.51 per woman tested, of which 50% were attributed to salaries and transport for project personnel. CONCLUSIONS: Our results suggest that rapid syphilis diagnostics are very inexpensive in this setting and can overcome some critical barriers to ensuring universal access to syphilis testing and treatment. The additional costs for implementation of a quality system were found to be relatively small, and could be reduced through alterations to the programme design. Given the potential for a quality system to improve quality of diagnosis and care, we recommend that QA activities be incorporated into RST roll-out

Testing the Recovery of Intrinsic Galaxy Sizes and Masses of z~2 Massive Galaxies Using Cosmological Simulations

Accurate measurements of galaxy masses and sizes are key to tracing galaxy evolution over time. Cosmological zoom-in simulations provide an ideal test bed for assessing the recovery of galaxy properties from observations. Here, we utilize galaxies with $M_*\sim10^{10}-10^{11.5}M_{\odot}$ at z~1.7-2 from the MassiveFIRE cosmological simulation suite, part of the Feedback in Realistic Environments (FIRE) project. Using mock multi-band images, we compare intrinsic galaxy masses and sizes to observational estimates. We find that observations accurately recover stellar masses, with a slight average underestimate of ~0.06 dex and a ~0.15 dex scatter. Recovered half-light radii agree well with intrinsic half-mass radii when averaged over all viewing angles, with a systematic offset of ~0.1 dex (with the half-light radii being larger) and a scatter of ~0.2 dex. When using color gradients to account for mass-to-light variations, recovered half-mass radii also exceed the intrinsic half-mass radii by ~0.1 dex. However, if not properly accounted for, aperture effects can bias size estimates by ~0.1 dex. No differences are found between the mass and size offsets for star-forming and quiescent galaxies. Variations in viewing angle are responsible for ~25% of the scatter in the recovered masses and sizes. Our results thus suggest that the intrinsic scatter in the mass-size relation may have previously been overestimated by ~25%. Moreover, orientation-driven scatter causes the number density of very massive galaxies to be overestimated by ~0.5 dex at $M_*\sim10^{11.5}M_{\odot}$.Comment: Published in the Astrophysical Journal Letters (7 pages, 5 figures; updated to match published version

Rest-Frame Near-Infrared Radial Light Profiles up to z=3 from JWST/NIRCam: Wavelength Dependence of the S\'ersic Index

We examine the wavelength dependence of radial light profiles based on S\'ersic index $n$ measurements of 1067 galaxies with M$_*\geq$ 10$^{9.5}$M$_\odot$ and in the redshift range $0.5 < z < 3$. The sample and rest-frame optical light profiles are drawn from CANDELS$+$3D-HST; rest-frame near-infrared light profiles are inferred from CEERS JWST/NIRCam imaging. $n$ shows only weak dependence on wavelength, regardless of redshift, galaxy mass and type: on average, star-forming galaxies have $n = 1-1.5$ and quiescent galaxies have $n = 3-4$ in the rest-frame optical and near-infrared. The strong correlation at all wavelengths between $n$ and star-formation activity implies a physical connection between the radial stellar mass profile and star-formation activity. The main caveat is that the current sample is too small to discern trends for the most massive galaxies (M$_* > 10^{11}M_\odot$).Comment: 15 pages, 7 figures, Submitted to ApJ. Comments welcom

Point-of-Care Tests to Strengthen Health Systems and Save Newborn Lives: The Case of Syphilis

Rosanna Peeling and colleagues describe their experience of introducing point-of-care testing to screen for syphilis in pregnant women living in low- and middle-income countries

The impact of HIV/SRH service integration on workload: analysis from the Integra Initiative in two African settings.

BACKGROUND: There is growing interest in integration of HIV and sexual and reproductive health (SRH) services as a way to improve the efficiency of human resources (HR) for health in low- and middle-income countries. Although this is supported by a wealth of evidence on the acceptability and clinical effectiveness of service integration, there is little evidence on whether staff in general health services can easily absorb HIV services. METHODS: We conducted a descriptive analysis of HR integration through task shifting/sharing and staff workload in the context of the Integra Initiative - a large-scale five-year evaluation of HIV/SRH integration. We describe the level, characteristics and changes in HR integration in the context of wider efforts to integrate HIV/SRH, and explore the impact of HR integration on staff workload. RESULTS: Improvements in the range of services provided by staff (HR integration) were more likely to be achieved in facilities which also improved other elements of integration. While there was no overall relationship between integration and workload at the facility level, HIV/SRH integration may be most influential on staff workload for provider-initiated HIV testing and counselling (PITC) and postnatal care (PNC) services, particularly where HIV care and treatment services are being supported with extra SRH/HIV staffing. Our findings therefore suggest that there may be potential for further efficiency gains through integration, but overall the pace of improvement is slow. CONCLUSIONS: This descriptive analysis explores the effect of HIV/SRH integration on staff workload through economies of scale and scope in high- and medium-HIV prevalence settings. We find some evidence to suggest that there is potential to improve productivity through integration, but, at the same time, significant challenges are being faced, with the pace of productivity gain slow. We recommend that efforts to implement integration are assessed in the broader context of HR planning to ensure that neither staff nor patients are negatively impacted by integration policy

The MOSDEF survey:AGN multi-wavelength identification, selection biases and host galaxy properties

We present results from the MOSFIRE Deep Evolution Field (MOSDEF) survey on the identification, selection biases, and host galaxy properties of 55 X-ray, IR and optically-selected active galactic nuclei (AGN) at $1.4 < z < 3.8$. We obtain rest-frame optical spectra of galaxies and AGN and use the BPT diagram to identify optical AGN. We examine the uniqueness and overlap of the AGN identified at different wavelengths. There is a strong bias against identifying AGN at any wavelength in low mass galaxies, and an additional bias against identifying IR AGN in the most massive galaxies. AGN hosts span a wide range of star formation rate (SFR), similar to inactive galaxies once stellar mass selection effects are accounted for. However, we find (at $\sim 2-3\sigma$ significance) that IR AGN are in less dusty galaxies with relatively higher SFR and optical AGN in dusty galaxies with relatively lower SFR. X-ray AGN selection does not display a bias with host galaxy SFR. These results are consistent with those from larger studies at lower redshifts. Within star-forming galaxies, once selection biases are accounted for, we find AGN in galaxies with similar physical properties as inactive galaxies, with no evidence for AGN activity in particular types of galaxies. This is consistent with AGN being fueled stochastically in any star-forming host galaxy. We do not detect a significant correlation between SFR and AGN luminosity for individual AGN hosts, which may indicate the timescale difference between the growth of galaxies and their supermassive black holes

The 3D-HST Survey: <i>Hubble Space Telescope</i> WFC3/G141 Grism Spectra, Redshifts, and Emission Line Measurements for ~ 100,000 Galaxies

We present reduced data and data products from the 3D-HST survey, a 248-orbit $HST$ Treasury program. The survey obtained WFC3 G141 grism spectroscopy in four of the five CANDELS fields: AEGIS, COSMOS, GOODS-S, and UDS, along with WFC3 $H_{140}$ imaging, parallel ACS G800L spectroscopy, and parallel $I_{814}$ imaging. In a previous paper, we presented photometric catalogs in these four fields and in GOODS-N, the fifth CANDELS field. Here we describe and present the WFC3 G141 spectroscopic data, again augmented with data from GO-1600 in GOODS-N (PI: B. Weiner). We developed software to automatically and optimally extract interlaced two-dimensional (2D) and one-dimensional (1D) spectra for all objects in the Skelton et al. (2014) photometric catalogs. The 2D spectra and the multi-band photometry were fit simultaneously to determine redshifts and emission line strengths, taking the morphology of the galaxies explicitly into account. The resulting catalog has redshifts and line strengths (where available) for 22,548 unique objects down to ${{JH}}_{\mathrm{IR}}\leq 24$ (79,609 unique objects down to ${{JH}}_{\mathrm{IR}}\leq 26$). Of these, 5459 galaxies are at $z > 1.5$ and 9621 are at $0.7< z< 1.5$, where Hα falls in the G141 wavelength coverage. The typical redshift error for ${{JH}}_{\mathrm{IR}}\leq 24$ galaxies is ${\sigma }_{z}\approx 0.003\times (1+z)$, i.e., one native WFC3 pixel. The $3\sigma$ limit for emission line fluxes of point sources is $2.1\times {10}^{-17}$ erg $s^{-1} cm^{-2}$. All 2D and 1D spectra, as well as redshifts, line fluxes, and other derived parameters, are publicly available

Micrometre-long covalent organic fibres by photoinitiated chain-growth radical polymerization on an alkali-halide surface

On-surface polymerization is a promising technique to prepare organic functional nanomaterials that are challenging to synthesize in solution, but it is typically used on metal substrates, which play a catalytic role. Previous examples on insulating surfaces have involved intermediate self-assembled structures, which face high barriers to diffusion, or annealing to higher temperatures, which generally causes rapid dewetting and desorption of the monomers. Here we report the photoinitiated radical polymerization, initiated from a two-dimensional gas phase, of a dimaleimide monomer on an insulating KCl surface. Polymer fibres up to 1 μm long are formed through chain-like rather than step-like growth. Interactions between potassium cations and the dimaleimide’s oxygen atoms facilitate the propagation of the polymer fibres along a preferred axis of the substrate over long distances. Density functional theory calculations, non-contact atomic force microscopy imaging and manipulations at room temperature were used to explore the initiation and propagation processes, as well as the structure and stability of the resulting one-dimensional polymer fibres

Interplay between local structure and supramolecular order in the reactivity of surface-supported molecular aggregates

SPM tools have been extensively used in recent years to prepare, characterize and test the structural and functional properties of self-assembled molecular networks on surfaces. In many cases the molecular positional and conformational degrees of freedom determine a complex interfacial energy landscape, where subtle equilibria lead to the formation of various 2D ordered phases, often related to each other by phase transitions able to trigger the molecular reactivity, which therefore depends on subtle interrelations between local adsorption sites, intramolecular structure and long range supramolecular order. This talk will address some aspects of the structure-reactivity relationships in several surface-supported molecular networks, studied by means of STM complemented by other surface science and computational tools: e.g. the dependence of the catalytic activity toward oxygen reduction and of the magnetic properties of an Ag-supported iron phthalocyanine monolayer on the supramolecular arrangement of the molecules [1]; the requirements for either thermal [2] or photo-excited [3] covalent stabilization of single- and bicomponent supramolecular networks containing functionalized porphyrins on Ag low-index surfaces; the bottom up synthesis of long range ordered 1D poly-para-phenylene nanowires and 2D graphene nanoribbons on gold substrates [4]. [1] Casarin et al., J. Phys. Chem. C, 2010 ,114, 2144; Sedona, F. et al. Nat. Mater, 2012, 11, 970, Bartolom\ue9 et al. J. Phys. Chem. C, 2015 ,119, 12488. [2] Di Marino et al., Langmuir, 2010, 26, 2466; Sedona et al., ACS Nano, 2010, 4, 5147; Sedona et al. J. Phys. Chem. C, 2014 ,118, 1587. [3] Basagni et al., Chem. Eur. J. 2014, 20, 14296. [4] Basagni et al., J. Am. Chem. Soc. 2015, 137, 1802; Basagni et al., ACS Nano 2016, 10, 2644