The young stellar population of Lynds 1340. An infrared view

We present results of an infrared study of the molecular cloud Lynds 1340, forming three groups of low and intermediate-mass stars. Our goals are to identify and characterise the young stellar population of the cloud, study the relationships between the properties of the cloud and the emergent stellar groups, and integrate L1340 into the picture of the star-forming activity of our Galactic environment. We selected candidate young stellar objects from the Spitzer and WISE data bases using various published color criteria, and classified them based on the slope of the spectral energy distribution. We identified 170 Class II, 27 Flat SED, and Class 0/I sources. High angular resolution near-infrared observations of the RNO 7 cluster, embedded in L1340, revealed eight new young stars of near-infrared excess. The surface density distribution of young stellar objects shows three groups, associated with the three major molecular clumps of L1340, each consisting of less than 100 members, including both pre-main sequence stars and embedded protostars. New Herbig--Haro objects were identified in the Spitzer images. Our results demonstrate that L1340 is a prolific star-forming region of our Galactic environment in which several specific properties of the intermediate-mass mode of star formation can be studied in detail.Comment: 73 pages, 33 figures, 15 tables. Accepted for publication in ApJ

High resolution observations of the L1551 bipolar outflow

The nearby dark cloud Lynds 1551 contains one of the closest examples of a well-collimated bipolar molecular outflow. This source has the largest angular size of any known outflow and was the first bipolar outflow to be detected. The outflow originates from a low-luminosity young stellar object, IRS-5. Optical and radio continuum observations show the presence of a highly collimated, ionized stellar wind orginating from close to IRS-5 and aligned with the molecular outflow. However, we have little information on the actual mechanism that generates the stellar wind and collimates it into opposed jets. The Very Large Array (VLA) observations indicate that the winds originate within 10(15) cm of IRS-5, unfortunately at a size scale difficult to resolve. For these reasons, observations of the structure and dynamics of the hypersonic molecular gas may provide valuable information on the origin and evolution of these outflows. In addition, the study of the impact of the outflowing gas on the surrounding molecular material is essential to understand the consequence these outflows have on the evolution and star formation history of the entire cloud. Moriarty-Schieven et al. (1986) obtained a oversampled map of the CO emission of a portion of both the blueshifted and redshifted outflows in LI551 using Five College Radio Astronomy Observatory 14 m telescope. The oversampled maps have been reconstructed to an effective angular resolution of 20 arcsec using a maximum entropy algorithm. A continuation of the study of Moriarty-Schieven et al. is presented. The entire L1551 outflow has now been mapped at 12 arcsec sampling requiring roughly 4000 spectra. This data has been constructed to 20 arcsec resolution to provide the first high resolution picture of the entire L1551 outflow. This new data has shown that the blueshifted lobe is more extended than previously thought and has expanded downstream sufficiently to break out of the dense molecular cloud, but the redshifted outflow is still confined within the molecular cloud. Details of the structure and kinematics of the high velocity gas are used to test the various models of the origin and evolution of outflows

Gold-katalysierte Mehrkomponentenreaktionen zur Darstellung spirocyclischer Pyrazolidine

Ein einfacher Zugang zu komplexen Molekülen ist nicht nur für die Organische Chemie, sondern auch für die Wirkstoffentwicklung der pharmazeutischen Industrie von großem Interesse. In diesem Zusammenhang stellen Mehrkomponentenreaktionen ein nützliches Werkzeug für die Synthese diverser hochsubstituierter Verbindungen dar. Diese Arbeit beschäftigt sich mit der Synthese von funktionalisierten heterocyclischen Spiroverbindungen. Diese werden mittels Gold-Katalyse in einer Mehrkomponentenreaktion ausgehend von einem Hydrazin-Derivat, einem Aldehyd und einem Alkinol bzw. Alkinamin oder Alkinthiol dargestellt. Da die nachhaltige Chemie heutzutage immer mehr an Bedeutung gewinnt, wurde ein Reaktionsweg entwickelt, bei dem der Gebrauch an organischen Lösungsmitteln vermieden wird und die Reaktion alternativ dazu im wässrigen Medium durchgeführt werden kann. Hierbei konnten unter Verwendung der mizellaren Katalyse gute Ausbeuten erzielt werden und das mizellare System über mehrere Recyclingzyklen wiederverwendet werden. Da die oben gezeigte Spirocyclisierung bis jetzt auf die Synthese von [N,O]-Spirocyclen beschränkt ist, wurden Experimente durchgeführt, um die Reaktion auf die Synthese von [N,N]- und [N,S]-Spirocyclen zu erweitern. Hierbei konnten Ausbeuten von bis zu 93% erzielt werden. Darüber hinaus wurden Studien zur diastereoselektiven Synthese durchgeführt. Hierbei konnten unter Verwendung von Prolin-Derivaten die Diastereomerenverhältnisse beeinflusst und so erste Erfolge in der diastereoselektiven Spirocyclisierung verzeichnet werden

The Enigmatic Radio Afterglow of GRB 991216

We present wide-band radio observations spanning from 1.4 GHz to 350 GHz of the afterglow of GRB 991216, taken from 1 to 80 days after the burst. The optical and X-ray afterglow of this burst were fairly typical and are explained by a jet fireball. In contrast, the radio light curve is unusual in two respects: (a) the radio light curve does not show the usual rise to maximum flux on timescales of weeks and instead appears to be declining already on day 1 and (b) the power law indices show significant steepening from the radio through the X-ray bands. We show that the standard fireball model, in which the afterglow is from a forward shock, is unable to account for (b) and we conclude that the bulk of the radio emission must arise from a different source. We consider two models, neither of which can be ruled out with the existing data. In the first (conventional) model, the early radio emission is attributed to emission from the reverse shock as in the case of GRB 990123. We predict that the prompt optical emission would have been as bright (or brighter) than 8th magnitude. In the second (exotic) model, the radio emission originates from the forward shock of an isotropically energetic fireball (10^54 erg) expanding into a tenuous medium (10^-4 cm^-3). The resulting fireball would remain relativistic for months and is potentially resolvable with VLBI techniques. Finally, we note that the near-IR bump of the afterglow is similar to that seen in GRB 971214 and no fireball model can explain this bump.Comment: ApJ, submitte

L1551NE - Discovery of a Binary Companion

L1551NE is a very young (class 0 or I) low-mass protostar located close to the well-studied L1551 IRS5. We present here evidence, from 1.3mm continuum interferometric observations at ~1'' resolution, for a binary companion to L1551NE. The companion, whose 1.3mm flux density is ~1/3 that of the primary component, is located 1.43'' (~230 A.U. at 160pc) to the southeast. The millimeterwave emission from the primary component may have been just barely resolved, with deconvolved size ~0.82"x0.70" (~131x112 A.U.). The companion emission was unresolved (<100 A.U.). The pair is embedded within a flattened circum-binary envelope of size ~5.4'' x 2.3'' (~860 x 370 A.U.). The masses of the three components (i.e. from the cicumstellar material of the primary star and its companion, and the envelope) are approximately 0.044, 0.014 and 0.023 Mo respectively.Comment: 8 pages, 1 figur

A Keplerian Circumbinary Disk around the Protobinary System L1551 NE

We present SubMillimeter-Array observations of a Keplerian disk around the Class I protobinary system L1551 NE in 335 GHz continuum emission and submillimeter line emission in 13CO (J=3-2) and C18O (J=3-2) at a resolution of ~120 x 80 AU. The 335-GHz dust-continuum image shows a strong central peak closely coincident with the binary protostars and likely corresponding to circumstellar disks, surrounded by a ~600 x 300 AU feature elongated approximately perpendicular to the [Fe II] jet from the southern protostellar component suggestive of a circumbinary disk. The 13CO and C18O images confirm that the circumbinary continuum feature is indeed a rotating disk; furthermore, the C18O channel maps can be well modeled by a geometrically-thin disk exhibiting Keplerian rotation. We estimate a mass for the circumbinary disk of ~0.03-0.12 Msun, compared with an enclosed mass of ~0.8 Msun that is dominated by the protobinary system. Compared with several other Class I protostars known to exhibit Keplerian disks, L1551 NE has the lowest bolometric temperature (~91 K), highest envelope mass (~0.39 Msun), and the lowest ratio in stellar mass to envelope + disk + stellar mass (~0.65). L1551 NE may therefore be the youngest protostellar object so far found to exhibit a Keplerian disk. Our observations present firm evidence that Keplerian disks around binary protostellar systems, ``Keplerian circumbinary disks', can exist. We speculate that tidal effects from binary companions could transport angular momenta toward the inner edge of the circumbinary disk and create the Keplerian circumbinary disk.Comment: 27 pages, 8 figure